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Vol. 27 No. 10 (2015): Vol 27 Issue 10

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Synthesis, Crystal Structures and Magnetic Property of Manganese(III) Schiff-Base Enantiomers

https://doi.org/10.14233/ajchem.2015.19042
Ping Wang
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China
Lingqian Kong
Dongchang College, Liaocheng University, Liaocheng 252059, P.R. China
Hongyan Zhang
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China
Daopeng Zhang
College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P.R. China

Corresponding Author(s) : Daopeng Zhang

dpzhang73@126.com

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10

Abstract

A pair of manganese(III) Schiff-base enantiomers with the formula {[Mn(R,R-3-MeOSalcy)(H2O)(DMF)]ClO4}2 (1) and {[Mn(S,S-3-MeOSalcy)(H2O)(DMF)]ClO4}2 (2) (3-MeOSalcy = N,N'-(1,2-cyclohexanediylethylene)bis(3-methoxy salicylideneiminato)dianion) have been prepared and characterized by elemental analysis and X-ray structure determination. X-ray diffraction reveals the Mn(III) ion is involved in an elongated octahedron formed by a N4O2 unit. Furthermore, two mononuclear manganese(III) Schiff-base compounds are self-complementary through coordinated aqua ligand from one complex and the free O4 compartment from the neighboring complex, giving supramolecular dimer structure. Investigation over magnetic susceptibilities of these two complexes reveals the overall weak antiferromagnetic interactions between the adjacent Mn(III) ions.

Keywords

Manganese(III) Schiff-base Enantiomer Crystal structure Magnetic property
Wang, P., Kong, L., Zhang, H., & Zhang, D. (2015). Synthesis, Crystal Structures and Magnetic Property of Manganese(III) Schiff-Base Enantiomers. Asian Journal of Chemistry, 27(10), 3883–3886. https://doi.org/10.14233/ajchem.2015.19042
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