Copyright (c) 2020 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Template Assisted Synthesis of Molecularly Imprinted Polymer for the Extraction of p-Coumaric Acid
Corresponding Author(s) : Showkat Ahmad Bhawani
Asian Journal of Chemistry,
Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020
Abstract
In present study, the molecular imprinting polymer (MIP) of p-coumaric acid was synthesized by using p-coumaric acid as a template, acetonitrile as solvent, 1,4-butanediol dimethacrylate as cross-linker, acrylic acid as monomer and 2,2-azobisisobutironitrile (AIBN) as the initiator. The synthesized polymers were characterized by FTIR and SEM. The results from SEM revealed that the polymer was in spherical shape with size in micro-range. The binding efficiency of polymers was analyzed by adsorption study. The highest rebinding efficiency for MIP was ~ 80% while for non-imprinted polymer (NIP) it was only 24%.
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- S. Koc, D.A. Kose, E. Avci and A. Kose, Hittite J. Sci. Eng., 3, 15 (2016); https://doi.org/10.17350/HJSE19030000027
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References
S. Koc, D.A. Kose, E. Avci and A. Kose, Hittite J. Sci. Eng., 3, 15 (2016); https://doi.org/10.17350/HJSE19030000027
N.K. Aguilar-Hernandez, T. Afseth, F.F. Lopez-Luke and J.P. ContrerasTorres, Vib. Spectrosc., 16, 2682 (2017); https://doi.org/10.1016/j.vibspec.2017.02.002
L. Chen, S. Xu and J. Li, Chem. Soc. Rev., 5, 2922 (2011); https://doi.org/10.1039/c0cs00084a
F. Puoci, G. Cirillo, M. Curcio, F. Iemma, O.I. Parisi, U.G. Spizzirri and N.N. Picci, ed.: M. Elnashar, Molecularly Imprinted Polymers (PIMs) in Biomedical Applications, In: Biopolymers, InTech (2010).
S.R. Shafqat, S.A. Bhawani, S. Bakhtiar and M.N.M. Ibrahim, BMC Chem., 14, 27 (2020); https://doi.org/10.1186/s13065-020-00680-8
S.A. Bhawani and A.L.J. Kimura, Pollut. Res., 37, 1126 (2018).
S. Bakhtiar, S.A. Bhawani and S.R. Shafqat, Chem. Biol. Technol. Agric., 6, 15 (2019); https://doi.org/10.1186/s40538-019-0152-5
S. Farooq, J. Nie, Y. Cheng, Z. Yan, J. Li, S.A.S. Bacha, A. Mushtaq and H. Zhang, Analyst, 143, 3971 (2018); https://doi.org/10.1039/C8AN00907D
S.A. Bhawani, S. Bakhtiar and S.R. Shafqat, Open Chem. Eng. J., 13, 122 (2019); https://doi.org/10.2174/1874123101912010122
R.M. Roland, S.A. Bhawani, R. Wahi and M.N.M. Ibrahim, J. Liq. Chromatogr. Rel. Technol., 43, 94 (2020); https://doi.org/10.1080/10826076.2019.1672077
L. Figueiredo, L. Santos and A. Alves, Adv. Polym.Technol., 34, 21506 (2015); https://doi.org/10.1002/adv.21506
S.A. Bhawani, S. Bakhtiar, R.M. Roland, S.R. Shafqat and M.N.M. Ibrahim, J. Appl. Pharm. Sci., 10, 562 (2020); https://doi.org/10.7324/JAPS.2020.104009
S.A. Bhawani, T.S. Sen and M.N.M. Ibrahim, Chem. Cent. J., 12, 19 (2018); https://doi.org/10.1186/s13065-018-0392-7
A.L.J. Chow and S.A. Bhawani, Int. J. Polym. Sci., 2016, 2418915 (2016); https://doi.org/10.1155/2016/2418915
R.M. Roland and S.A. Bhawani, J. Anal. Methods Chem., 2016, 5671507 (2016); https://doi.org/10.1155/2016/5671507
H. Yan and K.H. Row, Int. J. Mol. Sci., 7, 155 (2006); https://doi.org/10.3390/i7050155
C.F. van Nostrum, Drug Deliv. Formul. Nanotechnol., 2, 119 (2005); https://doi.org/10.1016/j.ddtec.2005.05.004
X. Fu, Q. Yang, Q. Zhou, Q. Lin and Q. Wang, Open J. Org. Polym. Mater., 5, 58 (2015); https://doi.org/10.4236/ojopm.2015.52007
B. Sellergren and K.J. Shea, J. Chromatogr. A, 690, 29 (1995); https://doi.org/10.1016/0021-9673(94)00905-O
M.T. Gokmen and F.E. Du Prez, Prog. Polym. Sci., 37, 365 (2012); https://doi.org/10.1016/j.progpolymsci.2011.07.006
T. Renkecz, K. László and V. Horváth, Mol. Impr., 2, 1 (2014); https://doi.org/10.2478/molim-2014-0001
M. Esfandyari-Manesh, M. Javanbakht, F. Atyabi, A. Badiei and R. Dinarvand, J. Appl. Polym. Sci., 121, 1118 (2011); https://doi.org/10.1002/app.33812
P.A.G. Cormack and A.Z. Elorza, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 804, 173 (2004); https://doi.org/10.1016/j.jchromb.2004.02.013.
R. Rampey, R.J. Umpleby, G.T. Rushton, J.C. Iseman, R.N. Shah and K.D. Shimizu, Anal. Chem., 76, 1123 (2004); https://doi.org/10.1021/ac0345345
W. Chen, Y. Ma, J. Pan, Z. Meng, G. Pan and B. Sellergren, Polymers, 7, 1689 (2015); https://doi.org/10.3390/polym7091478
C. Dai, S. Geissen, Y. Zhang, Y. Zhang and X. Zhou, Environ. Pollut., 159, 1660 (2011); https://doi.org/10.1016/j.envpol.2011.02.041