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Monitoring Seasonal Variation in Important Physio-Chemical Parameters of Arabian Seawater at Karachi Used for Feeding SWRO
Corresponding Author(s) : Rafia Azmat
Asian Journal of Chemistry,
Vol. 32 No. 9 (2020): Vol 32 Issue 9, 2020
Abstract
This study reports the analysis of various parameters of seawater upto 3 years used for feeding to seawater desalination (SWRO) plant at French Beach, Arabian sea, Karachi city, Pakistan. The work highlights the monitoring of essential parameters of seawater intake to reverse osmosis plant for pre-treatment loop designing and optimizing the operational cost. The study was planned as limited data was available internationally from this region, which includes pH, turbidity, temperature, total dissolved solids (TDS) and total suspended solids (TSS) allied with seasonal variations before pretreatment and after getting permeate. The water production capacity of SWRO plant is 100,000 gallon per day having Filmtech polyamide membrane and equipped with energy recovery turbine. It was observed in the period since 2015 to 2017, the monitoring of intake samples i.e. pH, turbidity and temperature showed variation in the range of 7.9-8.1, 8-34 NTU and 21-29 ºC, respectively. The observed value of TDS and TSS of seawater were 38.0-39.5 g/L and 18-48 mg/L, respectively. The concentrations of soft metals in seawater were found to be in order of Na > Mg > Ca > K while major anions were Cl− >SO42−. The TDS and pH of permeate water found to be in the range of 150-500 mg/L and 6.0-7.5 respectively, while other parameters were within WHO limit.
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- S. Manuel, Desalination, 165, 1 (2004); https://doi.org/10.1016/j.desal.2004.06.001
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- C.-H. Wei, S. Laborie, R.B. Aim and G. Amy, J. Membr Sci., 405-406, 212 (2012); https://doi.org/10.1016/j.memsci.2012.03.010
- American Public Health Association (APHA) Method 4500-H Standard Method for Examination of Water and Wastewater, Section 40 CFR 444.12, 1015 Washington DC, edn 18 (1992).
- ASTM D5907, 13 Standard Test Methods for Filterable Matter (Total Dissolved Solids) and Nonfilterable Matter (Total Suspended Solids) in Water.
- J. Chester and T. Roy, Marine Geochemistry, Blackwell Publishing (2012).
- N. Elahi, Q. Ahmed, L. Bat and F. Yousuf, J. Coast. Life Med., 3, 199 (2015).
- S.A. Siddiqui, A. Mahmood and R. Qari, J. Environ. Res. Dev., 5, 928 (2011).
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- K.L. Tu, L.D. Nghiem and A.R. Chivas, Chem. Eng. J., 168, 700 (2011); https://doi.org/10.1016/j.cej.2011.01.101
- S.C. Doney, Sci. Am., 294, 58 (2006); https://doi.org/10.1038/scientificamerican0306-58
- R.A. Feely, S.C. Doney and S.R. Cooley, Oceanography, 22, 36 (2009); https://doi.org/10.5670/oceanog.2009.95
- S. Bouillon, P.C. Mohan, N. Sreenivas and F. Dehairs, Mar. Ecol. Prog. Ser., 208, 79 (2000); https://doi.org/10.3354/meps208079
- W. Yoon and R.A. Rosson, Appl. Environ. Microbiol., 56, 595 (1990); https://doi.org/10.1128/AEM.56.3.595-600.1990
- S. Kumar, S.S. Adham and W.R. Pearce, Environ. Sci. Technol., 40, 2037 (2006); https://doi.org/10.1021/es0512428
- M.A. Hussain, M. Ansari and R. Kamal, Arabian J. Sci. Eng., 35, 103 (2010).
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References
S. Khoso, H. Wagan, H. Tunio and A. Ansari, J. Appl. Eng. Sci., 13, 35 (2015); https://doi.org/10.5937/jaes13-6445
W. Ishaque and S. Shaikh, Grassroots, 51, 90 (2017).
K. Roy, Urban Environmental Challenges and Poverty Alleviation in Pakistan (1994).
Water scarcity; A threat - The Nation; https://nation.com.pk/15-Sep-2017/water-scarcity-a-threat.
A. Maddocks, R.S. Young and P. Reig, Ranking the World’s Most WaterStressed Countries in 2040, World Resources Institute, August (2015).
M.K. Kahlown and A. Majeed, Water-Resources Situation in Pakistan: Challenges and Future Strategies, Water Resources in the South: Present Scenario and Future Prospects, vol. 20 (2003).
M. Miner, G. Patankar, S. Gamkhar and D.J. Eaton, Water Int., 34, 204 (2009); https://doi.org/10.1080/02508060902902193
H. Gleick, Water Int., 25, 127 (2000); https://doi.org/10.1080/02508060008686804
A. Matin, Z. Khan, S.M.J. Zaidi and M.C. Boyce, Desalination, 281, 1 (2011); https://doi.org/10.1016/j.desal.2011.06.063
K. Than, National Geographic News, Published August 7, 2011; https://news.nationalgeographic.com/news/2011/08/110804-freshwater-crisis-desalination-environment-science/.
S. Manuel, Desalination, 165, 1 (2004); https://doi.org/10.1016/j.desal.2004.06.001
P.K. Abdul Azis, I. Al-Tisan and N. Sasikumar, Desalination, 135, 69 (2001); https://doi.org/10.1016/S0011-9164(01)00140-0
N. Voutchkov, Desalination, 261, 354 (2010); https://doi.org/10.1016/j.desal.2010.07.002
H. Cooley, P.H. Gleick & G.H. Wolff, ed.: I. Hart, Desalination with a Grain of Salt: A California Perspective, Pacific Institute for Studies in Development, Environment, and Security: California, USA (2006).
M.S. Ishaq, Z. Afsheen, A. Khan and A. Khan, Disinfection Methods, IntechOpen (2018).
K.P. Lee, T.C. Arnot and D. Mattia, J. Membr Sci., 370, 1 (2011); https://doi.org/10.1016/j.memsci.2010.12.036
A.D. Khawaji, I.K. Kutubkhanah and J.M. Wie, Desalination, 221, 47 (2008); https://doi.org/10.1016/j.desal.2007.01.067
M. Busch, R. Chu and S. Rosenberg, IDA J. Desalin. Water Resuse, 2, 56 (2010); https://doi.org/10.1179/ida.2010.2.1.56
C.-H. Wei, S. Laborie, R.B. Aim and G. Amy, J. Membr Sci., 405-406, 212 (2012); https://doi.org/10.1016/j.memsci.2012.03.010
American Public Health Association (APHA) Method 4500-H Standard Method for Examination of Water and Wastewater, Section 40 CFR 444.12, 1015 Washington DC, edn 18 (1992).
ASTM D5907, 13 Standard Test Methods for Filterable Matter (Total Dissolved Solids) and Nonfilterable Matter (Total Suspended Solids) in Water.
J. Chester and T. Roy, Marine Geochemistry, Blackwell Publishing (2012).
N. Elahi, Q. Ahmed, L. Bat and F. Yousuf, J. Coast. Life Med., 3, 199 (2015).
S.A. Siddiqui, A. Mahmood and R. Qari, J. Environ. Res. Dev., 5, 928 (2011).
A. Shahzad, M.A. Khan, S.S. Shaukat and W. Ahmed, J. Chem. Soc. Pak., 31, 592 (2009).
K.L. Tu, L.D. Nghiem and A.R. Chivas, Chem. Eng. J., 168, 700 (2011); https://doi.org/10.1016/j.cej.2011.01.101
S.C. Doney, Sci. Am., 294, 58 (2006); https://doi.org/10.1038/scientificamerican0306-58
R.A. Feely, S.C. Doney and S.R. Cooley, Oceanography, 22, 36 (2009); https://doi.org/10.5670/oceanog.2009.95
S. Bouillon, P.C. Mohan, N. Sreenivas and F. Dehairs, Mar. Ecol. Prog. Ser., 208, 79 (2000); https://doi.org/10.3354/meps208079
W. Yoon and R.A. Rosson, Appl. Environ. Microbiol., 56, 595 (1990); https://doi.org/10.1128/AEM.56.3.595-600.1990
S. Kumar, S.S. Adham and W.R. Pearce, Environ. Sci. Technol., 40, 2037 (2006); https://doi.org/10.1021/es0512428
M.A. Hussain, M. Ansari and R. Kamal, Arabian J. Sci. Eng., 35, 103 (2010).
A. Cipollina, G. Micale and L. Rizzuti, Seawater Desalination: Conventional and Renewable Energy Processes, Berlin & Heidelberg: SpringerVerlag (2009).
T. Vladkova, Surface Modification Approach to Control Biofouling, In: Marine and Industrial Biofouling, Springer Series on Biofilms, vol. 4, no.1, pp. 135-163 (2009).
Victorian State Government Website Department of Primary Industries /Department of Sustainability and Environment Archived 2012-11-17 at the Wayback Machine Retrieved on September 20, 2012.
J.A. DeMello, C.A. Carmichael, E.E. Peacock, R.K. Nelson, J.S. Arey and C.M. Reddy, Marine Pollut. Bull., 54, 894 (2007); https://doi.org/10.1016/j.marpolbul.2007.02.016
M.E. Torres, R. Bayer, G. Winckler, A. Suckow and P.N. Froelich, Elemental and Isotopic Abundance of Noble Gases in Formation Fluids Recovered in situ from the Chile Triple Juction; In Proceedings of the Ocean Drilling Program. Scientific Results, vol. 141 (1995).