Issue

Vol. 32 No. 8 (2020): Vol 32 Issue 8, 2020

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Efficiency of Organic Corrosion Inhibitors Derived from Thai-Bael Fruit Extract for Preventing Corrosion in Carbon Steels

https://doi.org/10.14233/ajchem.2020.22743
Phattarasuda Manantapong
Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Ladyao, Chatuchak, Bangkok 10900, Thailand
https://orcid.org/0000-0003-3411-7699
Nattanon Chaipunya
Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Ladyao, Chatuchak, Bangkok 10900, Thailand
https://orcid.org/0000-0002-4742-6653
Suttipong Wannapaiboon
Synchrotron Light Research Institute, 111 University Avenue, Suranaree, Muang, Nakhon Ratchasima 30000, Thailand
https://orcid.org/0000-0002-6765-9809
Prae Chirawatkul
Synchrotron Light Research Institute, 111 University Avenue, Suranaree, Muang, Nakhon Ratchasima 30000, Thailand
https://orcid.org/0000-0002-5468-4511
Worawat Wattanathana
Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Ladyao, Chatuchak, Bangkok 10900, Thailand
https://orcid.org/0000-0002-3592-3708
Yuranan Hanlumyuang
Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Ladyao, Chatuchak, Bangkok 10900, Thailand
https://orcid.org/0000-0003-0252-1435

Corresponding Author(s) : Yuranan Hanlumyuang

yuranan.h@ku.th

Asian Journal of Chemistry, Vol. 32 No. 8 (2020): Vol 32 Issue 8, 2020

Abstract

The inhibiting action of Thai-bael fruit extract at room temperature on hot-rolled steel in 1M HCl solution was studied. The chemical functional groups of the green inhibitors were  characterized by Fourier-transformed infrared spectroscopy. The electrochemical activities of steel surface were investigated through linear polarization measurements, electrochemical  impedance spectroscopy, surface assessment techniques based on optical microscopy and X-ray absorption spectroscopy. Electrochemical testing samples have been prepared in the form of square plates with the size 1 × 1 cm2. The organic corrosion inhibitor extract from Thai-bael fruit has shown the smallest corrosion current density (Icorr) of 114.8 μA cm-2 and corrosion  potential (Ecorr) of -424.6 mV, compared with standard Ag/AgCl electrode potential. In comparison, similar tests in the bare HCl solutions yielded Icorr = 882.4 mA cm-2 and Ecorr = -445.8  mV. The mixed-type corrosion inhibiting behaviour was evidenced in the results of the polarization measurements. Electrochemical impedance spectroscopy reveals that the resistance to  charge transfer due to the presence of the extracts has been increased by about four times that of the same test on the bare HCl solution, indicating the formation of a protective layer.  The adsorption of the organic molecules near the steel-electrolyte interface is evident in the decreasing double-layer capacitance with the enhancing concentration levels of the extract.  This latter finding supports the displacement of the water molecules by means of the adsorption of the inhibitors on the steel surface. The optical images of steel surface before and after  being immersed in HCl solution also showed pieces of evidence of corrosion retardation. XANES study as well as the linear combination fitting revealed that the samples immersed in HCl  solutions with Thai-bael fruit extract possess less Fe3+ compositions. All tendencies across the four examinations indicate that Thai-bael fruit extract could potentially inhibit the corrosion  reaction of steel electrodes in the acidic solution. 

Keywords

Corrosion inhibitors Carbon steel Thai-bael fruit
Manantapong, P. ., Chaipunya, N. ., Wannapaiboon, S. ., Chirawatkul, P. ., Wattanathana, W. ., & Hanlumyuang, Y. . (2020). Efficiency of Organic Corrosion Inhibitors Derived from Thai-Bael Fruit Extract for Preventing Corrosion in Carbon Steels. Asian Journal of Chemistry, 32(8), 2043–2050. https://doi.org/10.14233/ajchem.2020.22743
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. C.C. Chama, Int. J. Eng. Res. Africa, 12, 25 (2014); https://doi.org/10.4028/www.scientific.net/JERA.12.25
  2. M. Natesan, S. Selvaraj, T. Manickam and G. Venkatachari, Sci. Technol. Adv. Mater., 9, 045002 (2008); https://doi.org/10.1088/1468-6996/9/4/045002
  3. A.S. Yaro, A.A. Khadom and H.F. Ibraheem, Anti-Corros. Methods Mater., 58, 116 (2011); https://doi.org/10.1108/00035591111130497
  4. S. Lyon, ed.: D. Fron, Overview of Corrosion Engineering, Science and Technology, In: Nuclear Corrosion Science and Engineering, Woodhead Publishing Series in Energy: Number 22, pp. 1-30 (2012).
  5. C.G. Dariva and A.F. Galio, in ed.: E. Hart, Developments in Corrosion Protection, In: Corrosion Inhibitors-Principles, Mechanisms and Appli-cations, Nova Science Publishers Inc., p. 122 (2014).
  6. B.E.A. Rani and B.B.J. Basu, Int. J. Corros., 2012, 1 (2012); https://doi.org/10.1155/2012/380217
  7. C. Verma, M.A. Quraishi, M. Makowska-Janusik, L.O. Olasunkanmi, K. Kluza and E.E. Ebenso, Sci. Rep., 7, 44432 (2017); https://doi.org/10.1038/srep44432
  8. O.K. Abiola and A.O. James, Corros. Sci., 52, 661 (2010); https://doi.org/10.1016/j.corsci.2009.10.026
  9. P.B. Raja and M.G. Sethuraman, Mater. Lett., 62, 113 (2008); https://doi.org/10.1016/j.matlet.2007.04.079
  10. J.C.O.C. Okere, Food Technol., 4, 61 (2013).
  11. M. Mobin, M. Basik and J. Aslam, Measurement, 134, 595 (2019); https://doi.org/10.1016/j.measurement.2018.11.003
  12. A. Singh, I. Ahamad and M.A. Quraishi, Arab. J. Chem., 9, S1584 (2016);https://doi.org/10.1016/j.arabjc.2012.04.029
  13. N. Chaubey, V.K. Singh and M.A. Quraishi, Ain Shams Eng. J., 9, 1131 (2018); https://doi.org/10.1016/j.asej.2016.04.010
  14. M. Benarioua, A. Mihi, N. Bouzeghaia and M. Naoun, Egypt. J. Petrol., 28, 155 (2019); https://doi.org/10.1016/j.ejpe.2019.01.001
  15. H. Hussein, Int. J. Mechan. Eng. Technol., 6, 34 (2015).
  16. A. Fidrusli, Suryanto and M. Mahmood, IOP Conf. Series Mater. Sci. Eng., 290, 012087 (2018);https://doi.org/10.1088/1757-899X/290/1/012087
  17. A.Y. El-Etre, Bull. Electrochem., 22, 75 (2006).
  18. A.E. Okoronkwo, S.J. Olusegun and O. Olaniran, Afr. Corros. J., 1, 30 (2015).
  19. A. Fouda, G.Y. Elewady, K. Shalabi and S. Habouba, Int. J. Adv. Res., 2, 817 (2014).
  20. F. Kurniawan and K.A. Madurani, Prog. Org. Coat., 88, 256 (2015); https://doi.org/10.1016/j.porgcoat.2015.07.010
  21. A. Cojocaru, I. Maior, D.I. Vaireanu, C. Lingvay, I. Lingvay, S. Caprarescu And G.E. Badea, J. Sustainable Energy, 1, 64 (2010).
  22. M.H.O. Ahmed, A.A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum, A.B. Mohamad and T.S. Gaaz, Results in Physics, 8, 728 (2018); https://doi.org/10.1016/j.rinp.2017.12.039
  23. S.A. Charoensiddhi and P. Anprung, Int. Food Res. J., 15, 287 (2008).
  24. S.K. Roy and S. Saran, ed.: E.M. Yahia, Bael (Aegle marmelos (L.) Corr. Serr.), In: Postharvest Biology and Technology of Tropical and Subtropical Fruits, Extension Systems Internationa: USA, pp. 186-215 (2011).
  25. N.K. Gupta, K.K. Misra, O. Singh and R. Rai, Progress. Hortic., 48, 116 (2016); https://doi.org/10.5958/2249-5258.2016.00023.3
  26. R. Pati and M. Muthukumar, eds.: S. Jain and S.D. Gupta, Genetic Transformation of Bael (Aegle marmelos Corr.), In: Biotechnology of Neglected and Underutilized Crops, Springer: Dordrecht, pp. 343-365 (2013).
  27. H. Pynam and S.M. Dharmesh, Biomed. Pharmacother., 106, 98 (2018); https://doi.org/10.1016/j.biopha.2018.06.053
  28. T.F. Fuller and J.N. Harb, Electrochemical Engineering, John Wiley & Sons (2018).
  29. M.E. Orazem and B. Tribollet, Electrochemical Impedance Spectroscopy, John Wiley & Sons, edn 2, vol. 48 (2017).
  30. M.R.S. Abouzari, F. Berkemeier, G. Schmitz and D. Wilmer, Solid State Ion., 180, 922 (2009); https://doi.org/10.1016/j.ssi.2009.04.002
  31. M. Outirite, M. Lagrenée, M. Lebrini, M. Traisnel, C. Jama, H. Vezin and F. Bentiss, Electrochim. Acta, 55, 1670 (2010); https://doi.org/10.1016/j.electacta.2009.10.048
  32. A.J. Bard and L.R. Faulkner, Electrochemical Methods Fundamentals and Applications, John Wiley & Sons, Inc., edn 2, vol. 38, p. 850 (2001).
  33. Sudheer and M.A. Quraishi, Ind. Eng. Chem. Res., 53, 2851 (2014); https://doi.org/10.1021/ie401633y
Read More
Author biographies is not available.
Statistic
Read Counter : 4 Download : 13