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Utilization of Mixed Naphthol Green B and Janus Green B Dyes as Photosensitier in Photogalvanic Cell for Solar Energy Conversion and Storage
Corresponding Author(s) : Chhagan Lal
Asian Journal of Chemistry,
Vol. 32 No. 8 (2020): Vol 32 Issue 8, 2020
Abstract
In this work, a new dye-sensitized solar cell (DSSC) was prepared using naphthol green B and Janus green B as photosensitizers and EDTA as reductant. A 210 μA of photocurrent and 1018 mV of photo-potential were generated using these dyes. The fill factor of 0.40, a conversion efficiency was observed to be 1.0028% and the power or maximum output of cell was calculated to be 213.78 μW. Because of the storage capacity in a cell, a DSSC can be used for a total of 180 min in dark. The properties of mixed photosensitize system EDTA-NGB-JGB were characterized a and evaluated by UV-visible, fluorosencemeter, FESEM and XRD analysis. The photocurrent generation mechanism in photogalvanic cell was also discussed.
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- K.K. Rohatgi-Mukherjee, Fundamentals of Photochemistry, New Age International: Delhi, India, pp. 292-293 (2002).
- P. Koli, Appl. Energy, 118, 231 (2014);https://doi.org/10.1016/j.apenergy.2013.12.035
- P. Koli, U. Sharma and K.M. Gangotri, Renew. Energy, 37, 250 (2012); https://doi.org/10.1016/j.renene.2011.06.022
- P. Koli and U. Sharma, Energy Source A, 39, 555 (2017);https://doi.org/10.1080/15567036.2016.1243171
- M.Z. Hoffman and N.N. Lichtin, eds., R.R. Hantala, R.B. King and C.C. Kutal, Solar Energy, N.N. Publisher: New Jersey, p. 153 (1979).
- W.J. Albery and M.D. Archer, Nature, 270, 399 (1977);https://doi.org/10.1038/270399a0
- T. Sakata, Y. Suda, J. Tanaka and H. Tsubomura, J. Phys. Chem., 81, 537 (1977);https://doi.org/10.1021/j100521a009
- M.Z. Hoffman and N.N. Litchin, Sol. Energy, 21, 153 (1979).
- H. Tsubomura, Y. Shimoura and S. Fujiwara, J. Phys. Chem., 83, 2103 (1979);https://doi.org/10.1021/j100479a010
- M.A. Fox and Kabir-Ud-Din, J. Phys. Chem., 83, 1800 (1980);https://doi.org/10.1021/j100476a022
- P. Koli, RSC Adv., 4, 46194 (2014);https://doi.org/10.1039/C4RA08373C
- S. Yadav amd C. Lal, Int. J. Green Energy, 8, 265 (2011);https://doi.org/10.1002/er.4440170408
- S. Dube, Int. J. Energy Res., 17, 311 (1993);https://doi.org/10.1002/er.4440170408
- C. Lal, J. Power Sources, 164, 926 (2007);https://doi.org/10.1016/j.jpowsour.2006.11.020
- M.K. Bhimwal and K.M. Gangotri, Energy, 36, 1324 (2011);https://doi.org/10.1016/j.energy.2010.11.007
- K.M. Gangotri and K.R. Genwa, J. Indian Chem. Soc., 81, 592 (2004).
- S.A. Mahmoud, B.S. Mohamed, A.S. El-Tabei, M.A. Hegazy, M.A. Betiha, H.M. Killa, E.K. Heikal, S.A.K. Halil, M. Dohium and S.B. Hosney, Energy Procedia, 46, 227 (2014);https://doi.org/10.1016/j.egypro.2014.01.177
- S.A. Mahmoud and B.S. Mohamed, Int. J. Electrochem. Sci., 10, 3340 (2015).
- P. Gangotri and P. Koli, Sustain. Energy Fuels, 1, 882 (2017);https://doi.org/10.1039/C7SE00083A
- P. Koli, Int. J. Ambient Energy, 40, 868 (2019);https://doi.org/10.1080/01430750.2018.1437565
- K.R. Genwa and N.C. Khatri, Energy Fuels, 23, 1024 (2009);https://doi.org/10.1021/ef800747w
- A.A. McConnell, R.H. Nuttall and D.M. Stalker, Talanta, 25, 425 (1978);https://doi.org/10.1016/0039-9140(78)80019-8
- J.E. Beecher, T. Durst, J.M.J. Frechet, A. Godt, A. Pangborn, D.R. Robello, C.S. William and D.J. Williams, Adv. Mater., 5, 632 (1993).https://doi.org/10.1002/adma.19930050906
- S.C. Ameta, S. Khamesra, A.K. Chittora and K.M. Gangotri, Int. J. Energy Res., 13, 643 (1989);https://doi.org/10.1002/er.4440130604
- C. Lal and K.M. Gangotri, Environ. Prog. Sustain. Energy, 30, 754 (2011);https://doi.org/10.1002/ep.10524
- M. Kaneko and A. Yamada, J. Phys. Chem., 81, 1213 (1977);https://doi.org/10.1021/j100527a020
References
K.K. Rohatgi-Mukherjee, Fundamentals of Photochemistry, New Age International: Delhi, India, pp. 292-293 (2002).
P. Koli, Appl. Energy, 118, 231 (2014);https://doi.org/10.1016/j.apenergy.2013.12.035
P. Koli, U. Sharma and K.M. Gangotri, Renew. Energy, 37, 250 (2012); https://doi.org/10.1016/j.renene.2011.06.022
P. Koli and U. Sharma, Energy Source A, 39, 555 (2017);https://doi.org/10.1080/15567036.2016.1243171
M.Z. Hoffman and N.N. Lichtin, eds., R.R. Hantala, R.B. King and C.C. Kutal, Solar Energy, N.N. Publisher: New Jersey, p. 153 (1979).
W.J. Albery and M.D. Archer, Nature, 270, 399 (1977);https://doi.org/10.1038/270399a0
T. Sakata, Y. Suda, J. Tanaka and H. Tsubomura, J. Phys. Chem., 81, 537 (1977);https://doi.org/10.1021/j100521a009
M.Z. Hoffman and N.N. Litchin, Sol. Energy, 21, 153 (1979).
H. Tsubomura, Y. Shimoura and S. Fujiwara, J. Phys. Chem., 83, 2103 (1979);https://doi.org/10.1021/j100479a010
M.A. Fox and Kabir-Ud-Din, J. Phys. Chem., 83, 1800 (1980);https://doi.org/10.1021/j100476a022
P. Koli, RSC Adv., 4, 46194 (2014);https://doi.org/10.1039/C4RA08373C
S. Yadav amd C. Lal, Int. J. Green Energy, 8, 265 (2011);https://doi.org/10.1002/er.4440170408
S. Dube, Int. J. Energy Res., 17, 311 (1993);https://doi.org/10.1002/er.4440170408
C. Lal, J. Power Sources, 164, 926 (2007);https://doi.org/10.1016/j.jpowsour.2006.11.020
M.K. Bhimwal and K.M. Gangotri, Energy, 36, 1324 (2011);https://doi.org/10.1016/j.energy.2010.11.007
K.M. Gangotri and K.R. Genwa, J. Indian Chem. Soc., 81, 592 (2004).
S.A. Mahmoud, B.S. Mohamed, A.S. El-Tabei, M.A. Hegazy, M.A. Betiha, H.M. Killa, E.K. Heikal, S.A.K. Halil, M. Dohium and S.B. Hosney, Energy Procedia, 46, 227 (2014);https://doi.org/10.1016/j.egypro.2014.01.177
S.A. Mahmoud and B.S. Mohamed, Int. J. Electrochem. Sci., 10, 3340 (2015).
P. Gangotri and P. Koli, Sustain. Energy Fuels, 1, 882 (2017);https://doi.org/10.1039/C7SE00083A
P. Koli, Int. J. Ambient Energy, 40, 868 (2019);https://doi.org/10.1080/01430750.2018.1437565
K.R. Genwa and N.C. Khatri, Energy Fuels, 23, 1024 (2009);https://doi.org/10.1021/ef800747w
A.A. McConnell, R.H. Nuttall and D.M. Stalker, Talanta, 25, 425 (1978);https://doi.org/10.1016/0039-9140(78)80019-8
J.E. Beecher, T. Durst, J.M.J. Frechet, A. Godt, A. Pangborn, D.R. Robello, C.S. William and D.J. Williams, Adv. Mater., 5, 632 (1993).https://doi.org/10.1002/adma.19930050906
S.C. Ameta, S. Khamesra, A.K. Chittora and K.M. Gangotri, Int. J. Energy Res., 13, 643 (1989);https://doi.org/10.1002/er.4440130604
C. Lal and K.M. Gangotri, Environ. Prog. Sustain. Energy, 30, 754 (2011);https://doi.org/10.1002/ep.10524
M. Kaneko and A. Yamada, J. Phys. Chem., 81, 1213 (1977);https://doi.org/10.1021/j100527a020