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Vol. 32 No. 6 (2020): Vol 32 Issue 6

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Improved Capacity of LiNi0.8Mn0.1Co0.1O2 Cathode upon Sn(IV) Doping by Facile Co-Precipitation Method

https://doi.org/10.14233/ajchem.2020.22543
D. Deivamani
P.G. and Research Department of Physics, Alagappa Government Arts College, Karaikudi-630003, India
P. Perumal
P.G. and Research Department of Physics, Alagappa Government Arts College, Karaikudi-630003, India

Corresponding Author(s) : P. Perumal

perumal59@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 6 (2020): Vol 32 Issue 6

Abstract

Nickel rich lithium nickel manganese cobalt oxide is one of the prominent cathode materials in the field of lithium ion battery. The cathode was prepared upon doping with Sn4+ by simple co-precipitation method to develop its discharge capacity. The structural and morphological studies on the cathode material were done by X-ray diffraction and scanning electron microscopy to confirm any structural changes upon doping of Sn4+. The higher discharge capacity of 210 mAh g-1 with 89% capacity retention was achieved even after 100 cycles at C/3 rate for 0.8 mol % Sn4+ doped lithium nickel manganese cobalt oxide. The structural phase change upon cycling for Sn4+ doped and un-doped cathode was illustrated by differential plot. The ionic radius and high bond stability of Sn4+ that compares Ni2+ might be the reason to prevent structural collapse during Li+ intercalation and de-intercalation process.

Keywords

Cathode material Co-precipitation method Tin(IV) Doping Lithium ion battery
Deivamani, D., & Perumal, P. (2020). Improved Capacity of LiNi0.8Mn0.1Co0.1O2 Cathode upon Sn(IV) Doping by Facile Co-Precipitation Method. Asian Journal of Chemistry, 32(6), 1303–1308. https://doi.org/10.14233/ajchem.2020.22543
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