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Vol. 32 No. 4 (2020): Vol 32 Issue 4, 2020

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Synthesis, Characterization and Photo-Physical Properties of Europium(III) and Terbium(III) Complexes with Thiosemicarbazones

https://doi.org/10.14233/ajchem.2020.22532
Ananya Vishwakarma
Department of Chemistry, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur-273009, India
S.K. Sengupta
Department of Chemistry, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur-273009, India
O.P. Pandey
Department of Chemistry, Deen Dayal Upadhyaya Gorakhpur University, Gorakhpur-273009, India

Corresponding Author(s) : Ananya Vishwakarma

ananyaa.vishwakarma@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 4 (2020): Vol 32 Issue 4, 2020

Abstract

Europium(III) and Terbium(III) complexes of type [Eu(L)Cl(H2O)2] and [Tb(L)OAc(H2O)2] (H2L = thiosemicarbazone ligands derived from substituted thiosemicarbazide and benzil/diacetyl) were synthesized. The ligands and synthesized complexes were characterized on the basis of elemental analysis, FT-IR and 1H NMR and X-ray diffraction studies. Photo-physical properties such as excitation spectra, emission spectra and luminescence curves of complexes were investigated. The most intense peak of Eu3+ ion found at 618 nm attributed to 5D0 → 7F2 transition and peak of Tb3+ ion at 549 nm attributed to 5D4 → 7F5 transition.

Keywords

Thiosemicarbazone Benzil Diacetyl IR 1H NMR Luminescence spectra
Vishwakarma, A., Sengupta, S., & Pandey, O. (2020). Synthesis, Characterization and Photo-Physical Properties of Europium(III) and Terbium(III) Complexes with Thiosemicarbazones. Asian Journal of Chemistry, 32(4), 952–958. https://doi.org/10.14233/ajchem.2020.22532
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