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Design, Synthesis, Spectral and Theoretical Studies of Some Picrates

https://doi.org/10.14233/ajchem.2020.22385
S. Amala
Department of Chemistry, Annamalai University, Annamalainagar-608002, India
G. Rajarajan
Department of Chemistry, Annamalai University, Annamalainagar-608002, India
E. Dhineshkumar
Department of Chemistry, Annamalai University, Annamalainagar-608002, India
https://orcid.org/0000-0001-9033-5311
M. Arockia doss
Department of Chemistry, St. Joseph University, Nagaland-797115, India
V. Thanikachalam
Department of Chemistry, Annamalai University, Annamalainagar-608002, India
https://orcid.org/0000-0003-1076-6272

Corresponding Author(s) : G. Rajarajan

rajarajang70@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 1 (2020): Vol 32 Issue 1

Abstract

The structures of newly synthesized compounds (1-3) viz. 3-ethyl-5-methyl-2,6-bis(4- chlorophenyl)piperidin-1-ium picrate (1), 3-ethyl-5-methyl-2,6-bis(4-methylphenyl)piperidin-1-ium picrate (2) and 3-ethyl-5-methyl-2,6-bis(3,4-dimethoxyphenyl)piperidin-1-ium picrate (3) were confirmed by elemental analysis, FT-IR, 1H and 13C NMR. The UV-visible spectra, fluoresence, emission properties of synthesized 1-3 in different solvents were studied. Compounds 1-3 solvatochromic displays a slight effect of the emission and absorption spectrum, indicating a small change in the dipole moment upon excitation of compounds 1-3. All the compounds were investigated by DFT. The theoretical geometrical parameters are in good agreement with experimental values.

Keywords

Piperidin-1-ium picrate Fluorescence Density functional theory Molecular electrostatic potential
Amala, S., Rajarajan, G., Dhineshkumar, E., doss, M. A., & Thanikachalam, V. (2019). Design, Synthesis, Spectral and Theoretical Studies of Some Picrates. Asian Journal of Chemistry, 32(1), 174–182. https://doi.org/10.14233/ajchem.2020.22385
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