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Synthesis and Spectral Studies of Some Zn(II) Complexes with Substituted N,N-Donor Ligands Derived from Pyridine-2-carbaldehyde

https://doi.org/10.14233/ajchem.2020.22348
Shiva Lall Sunar
Department of Chemistry, National Institute of Technology Agartala, Barjala, Jirania-799046, India
Keisham Surjit Singh
Department of Chemistry, National Institute of Technology Agartala, Barjala, Jirania-799046, India
Sajal Kundu
Department of Chemistry, National Institute of Technology Agartala, Barjala, Jirania-799046, India

Corresponding Author(s) : Sajal Kundu

kundu12@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 1 (2020): Vol 32 Issue 1

Abstract

A series of four neutral zinc complexes with substituted N,N-donor ligands viz. Ln = (E)-N-(pyridin-2-ylmethylene)anilines of composition [Zn(NO3)2(L1)] (1), [Zn(NO3)2L2] (2), [Zn(NO3)2L3] (3), [Zn(NO3)2L4] (4) were synthesized and characterized. The spectroscopic properties of the Zn(II) complexes were studied by UV-visible, fluorescence, IR and 1H NMR spectral analysis. All the zinc(II) complexes are water soluble and non-electrolyte in solution. Efforts for getting single crystals suitable for X-ray crystal structure could not be achieved. However, on the basis of spectral studies, compounds 1-4 are proposed to have octahedral geometry. The emission spectra of all the complexes show π-π* (intra-ligand) transition.

Keywords

Water soluble Zinc(II) nitrate complexes (E)-N-(pyridin-2-ylmethylene)aniline
Sunar, S. L., Singh, K. S., & Kundu, S. (2019). Synthesis and Spectral Studies of Some Zn(II) Complexes with Substituted N,N-Donor Ligands Derived from Pyridine-2-carbaldehyde. Asian Journal of Chemistry, 32(1), 122–126. https://doi.org/10.14233/ajchem.2020.22348
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