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Synthesis and Characterization of Polyvinyl Alcohol-Gum Arabic Polymer Blend Membranes
Corresponding Author(s) : A. Stephen
Asian Journal of Chemistry,
Vol. 32 No. 1 (2020): Vol 32 Issue 1
Abstract
Membranes of poly(vinyl alcohol) (PVA), gum arabic (GA) homopolymer and their blends of six different compositions (w/w) were prepared using solution casting method. Mixing of synthetic polymer e.g., PVA and natural polymer e.g., gum arabic can give a new class of polymer blend with better mechanical properties and biocompatibility than those of single components. The structural, optical and conductivity studies of these prepared membranes were examined by XRD, FTIR, UV and EIS. The XRD diffraction patterns for the polymer blend samples showed that they are more amorphous in nature as compared to pure PVA and pure gum arabic. The FTIR analysis of the samples gave information about various functional groups present in the samples. The energy band gap of various samples were obtained from UV-visible analysis. The conductivity of polymer membrane was analyzed by electronics impedance spectroscopy (EIS). Addition of natural polymer gum arabic has resulted slight increase in the conductivity of blend polymer.
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References
A.D. Jenkins, Polymer Science, A Materials Science Handbook, North Holland Publishing Company: Amsterdam and London, vol. 2 (1972).
S. Devikala, D. Ajith, P. Kamaraj and M. Arthanareeswari, Mater. Today, 14, 630 (2019); https://doi.org/10.1016/j.matpr.2019.04.186.
R.H. Jones and G.J. Thomas, Materials for the Hydrogen Economy, CRC Press: Boca Raton, FL, p. 147 (2008).
L. Mokhtar, Int. J. Sci. Res., 5, 583 (2013).
S. Damodaran and K.L. Parkin, Fennema′s Food Chemistry, CRC Press: Boca Raton, FL, edn 5, p. 83 (2017).
H. Wang, P.A. Williams and C. Senan, Food Hydrocol., 37, 143 (2014); https://doi.org/10.1016/j.foodhyd.2013.10.033.
B.H. Ali, A. Ziada and G. Bluden, Food Chem. Toxicol., 47, 1 (2009); https://doi.org/10.1016/j.fct.2008.07.001.
D. Verbeken, S. Dierckx and K. Dewettinck, Appl. Microbiol. Biotechnol., 63, 10 (2003); https://doi.org/10.1007/s00253-003-1354-z.
D.M.W. Anderson and J.G.K. Farquhar, Int. Tree Crops J., 2, 15 (2003); https://doi.org/10.1080/01435698.1982.9752736.
E. Dauqan and A. Abdullah, Am. J. Appl. Sci., 10, 1270 (2013); https://doi.org/10.3844/ajassp.2013.1270.1279.
C.C.DeMelis and D.Schonecker, Food Chem. Toxicol., 41, 319 (2003); https://doi.org/10.1023/A:1024230324555.
M.T. Razzak and D. Darwis, Radiat. Phys. Chem., 62, 107 (2001); https://doi.org/10.1016/S0969-806X(01)00427-3.
S.P. Masti and R.B. Chougle, Int. Res. J. Environ. Sci., 3, 11 (2014).
B.S. Mudigoudra, S.P. Masti and R.B. Chougale, Res. J. Recent Sci., 1, 83 (2013).
S.S.Z. Hindi, M.O. Albureikan, A.A. Al-Ghamdi, H. Alhummiany and S.M. Al-Sharabi, Nanosci. Nanotechnol. Res., 4, 32 (2017); https://doi.org/10.12691/nnr-4-2-3.
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K.K. Taha, R.H. Elmahi, E.A. Hassan, S.E. Ahmed and M.H. Shyoub, J. Forest Prod. Ind., 1, 11 (2012).
D. Bhakat, P. Barik and A. Bhattacharjee, J. Phys. Chem. Solids, 112, 73 (2018); https://doi.org/10.1016/j.jpcs.2017.09.002.
H. Mallik and A. Sarkar, J. Non-Crystall. Solids, 352, 795 (2006); https://doi.org/10.1016/j.jnoncrysol.2006.02.032.
M.L.Verma and H.D.Sabu, Ionics, 23, 2339 (2017) https://doi.org/10.1007/s11581-017-2063-4.
H. Adam, M.A. Siddig, A.A. Siddig and N.A. Eltahir, Sudan Med. Monit., 8,174 (2013); https://doi.org/10.4103/1858-5000.133006.
F. Bouaziz, M. Koubaa and S.E. Chaabouni, Antioxidants, 5, 26 (2016) https://doi.org/10.3390/antiox5030026.