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Effect of Pb2+ Ions on the Mechanical, Structural and Thermal Behaviour of B2O3-CaO Glasses
Corresponding Author(s) : C. Subashini
Asian Journal of Chemistry,
Vol. 32 No. 1 (2020): Vol 32 Issue 1
Abstract
B2O3-CaO-PbO glasses with different concentrations of PbO (5-20 mol % in four steps) were prepared by melt quench technique. The amorphous nature and homogeneities of the prepared glasses were confirmed by XRD and SEM analyses. Ultrasonic velocities and density were measured at 303 K using pulse-echo technique and Archimedes’ principle respectively. Various parameters, viz., molar volume, longitudinal modulus, shear modulus, bulk modulus, Young’s modulus, Poisson’s ratio, micro-hardness and Debye temperature have been evaluated from the measured data. The results of ultrasonic properties indicate that the incorporation of lead ions expand the calcium borate network structure. FTIR spectra revealed that boron exists in both trigonal and tetrahedral structural units and no boroxial ring formation takes place in the glass structure. The transition temperature, melting temperature and crystallization temperature have been identified using DTA measurements.
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- S.M. Kaczmarek, Opt. Mater., 19, 189 (2002); https://doi.org/10.1016/S0925-3467(01)00218-X
- A.S. Rao, J.L. Rao, R.R. Reddy and T.V. Ramakrishna Rao, Opt. Mater., 4, 717 (1995); https://doi.org/10.1016/0925-3467(95)00040-2.
- S. Mohan, K.S. Thind, G. Sharma and L. Gerward, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 70, 1173 (2008); https://doi.org/10.1016/j.saa.2007.10.038.
- K.I. Cho, S.H. Lee, D.W. Shin and Y.K. Sun, Electrochim. Acta, 52, 1576 (2006); https://doi.org/10.1016/j.electacta.2006.02.065.
- A.G. Dias, J.M.S. Skakle, I.R. Gibson, M.A. Lopes and J.D. Santos, J. Non-Cryst. Solids, 351, 810 (2005); https://doi.org/10.1016/j.jnoncrysol.2005.01.060.
- M.N. Rahaman, D.E. Day, B. Sonny Bal, Q. Fu, S.B. Jung, L.F. Bonewald and A.P. Tomsia, Acta Biomater., 7, 2355 (2011); https://doi.org/10.1016/j.actbio.2011.03.016.
- Manupriya, K.S. Thind, G. Sharma, V. Rajendran, K. Singh, A.V. Gayathri Devi and S. Aravindan, Phys. Status Solidi, 203, 2356 (2006); https://doi.org/10.1002/pssa.200622140.
- M. Gabr, K.A.-A. Ali and A.G. El-Din Mostafa, Turkish J. Phys., 31, 31 (2007).
- D.W. Kim, D.G. Lee and K.S. Hong, Mater. Res. Bull., 36, 585 (2001); https://doi.org/10.1016/S0025-5408(01)00551-7.
- R. Palani and G. Srinivasan, Int. J. Recent Sci. Res., 3, 992 (2012).
- J. Krogh-Moe and H. Jürine, Phys. Chem. Glasses, 6, 46 (1965).
- H.A. El-Batal and A.F. Abbas, Trans. Indian Ceram. Soc., 31, 36 (1972); https://doi.org/10.1080/0371750X.1972.10840795.
- S. Kumar, P. Vinatier, A. Levasseur and K.J. Rao, J. Solid State Chem., 177, 1723 (2004); https://doi.org/10.1016/j.jssc.2003.12.034.
- R.K. Brow and D.R. Tallant, J. Non-Cryst. Solids, 222, 396 (1997); https://doi.org/10.1016/S0022-3093(97)00382-7.
- K.A. Matori, M.H.M. Zaid, S.H.A. Aziz, H.M. Kamari and Z.A. Wahab, J. Non-Cryst. Solids, 361, 78 (2013); https://doi.org/10.1016/j.jnoncrysol.2012.10.022.
- V.R. Roma, Elastic Properties of the Lead Containing Bismuthtellurite Glasses, In: Proceedings of 15th World Conference on Non-Destructive Testing, October (2000).
- T.R. Rao, C.V. Rao, C.R. Krishna, C.R. Krishna, U.S.U. Thampy, R.R. Raju, P.S. Rao and R.V.S.S.N. Ravikumar, J. Non-Cryst. Solids, 357, 3373 (2011); https://doi.org/10.1016/j.jnoncrysol.2011.06.004.
- J.L. Kumari, J.S. Kumar and S. Cole, J. Non-Cryst. Solids, 357, 3734 (2011); https://doi.org/10.1016/j.jnoncrysol.2011.07.007.
- G. Sharma, K. Singh, Manupriya, S. Mohan, H. Singh and S. Bindra, Radiat. Phys. Chem., 75, 959 (2006); https://doi.org/10.1016/j.radphyschem.2006.02.008.
- M. Pal, B. Roy and M. Pal, J. Mod. Phys., 2, 1062 (2011); https://doi.org/10.4236/jmp.2011.29129.
- C. Li and Q. Su, Appl. Phys. Lett., 85, 2190 (2004); https://doi.org/10.1063/1.1797562.
References
S.M. Kaczmarek, Opt. Mater., 19, 189 (2002); https://doi.org/10.1016/S0925-3467(01)00218-X
A.S. Rao, J.L. Rao, R.R. Reddy and T.V. Ramakrishna Rao, Opt. Mater., 4, 717 (1995); https://doi.org/10.1016/0925-3467(95)00040-2.
S. Mohan, K.S. Thind, G. Sharma and L. Gerward, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 70, 1173 (2008); https://doi.org/10.1016/j.saa.2007.10.038.
K.I. Cho, S.H. Lee, D.W. Shin and Y.K. Sun, Electrochim. Acta, 52, 1576 (2006); https://doi.org/10.1016/j.electacta.2006.02.065.
A.G. Dias, J.M.S. Skakle, I.R. Gibson, M.A. Lopes and J.D. Santos, J. Non-Cryst. Solids, 351, 810 (2005); https://doi.org/10.1016/j.jnoncrysol.2005.01.060.
M.N. Rahaman, D.E. Day, B. Sonny Bal, Q. Fu, S.B. Jung, L.F. Bonewald and A.P. Tomsia, Acta Biomater., 7, 2355 (2011); https://doi.org/10.1016/j.actbio.2011.03.016.
Manupriya, K.S. Thind, G. Sharma, V. Rajendran, K. Singh, A.V. Gayathri Devi and S. Aravindan, Phys. Status Solidi, 203, 2356 (2006); https://doi.org/10.1002/pssa.200622140.
M. Gabr, K.A.-A. Ali and A.G. El-Din Mostafa, Turkish J. Phys., 31, 31 (2007).
D.W. Kim, D.G. Lee and K.S. Hong, Mater. Res. Bull., 36, 585 (2001); https://doi.org/10.1016/S0025-5408(01)00551-7.
R. Palani and G. Srinivasan, Int. J. Recent Sci. Res., 3, 992 (2012).
J. Krogh-Moe and H. Jürine, Phys. Chem. Glasses, 6, 46 (1965).
H.A. El-Batal and A.F. Abbas, Trans. Indian Ceram. Soc., 31, 36 (1972); https://doi.org/10.1080/0371750X.1972.10840795.
S. Kumar, P. Vinatier, A. Levasseur and K.J. Rao, J. Solid State Chem., 177, 1723 (2004); https://doi.org/10.1016/j.jssc.2003.12.034.
R.K. Brow and D.R. Tallant, J. Non-Cryst. Solids, 222, 396 (1997); https://doi.org/10.1016/S0022-3093(97)00382-7.
K.A. Matori, M.H.M. Zaid, S.H.A. Aziz, H.M. Kamari and Z.A. Wahab, J. Non-Cryst. Solids, 361, 78 (2013); https://doi.org/10.1016/j.jnoncrysol.2012.10.022.
V.R. Roma, Elastic Properties of the Lead Containing Bismuthtellurite Glasses, In: Proceedings of 15th World Conference on Non-Destructive Testing, October (2000).
T.R. Rao, C.V. Rao, C.R. Krishna, C.R. Krishna, U.S.U. Thampy, R.R. Raju, P.S. Rao and R.V.S.S.N. Ravikumar, J. Non-Cryst. Solids, 357, 3373 (2011); https://doi.org/10.1016/j.jnoncrysol.2011.06.004.
J.L. Kumari, J.S. Kumar and S. Cole, J. Non-Cryst. Solids, 357, 3734 (2011); https://doi.org/10.1016/j.jnoncrysol.2011.07.007.
G. Sharma, K. Singh, Manupriya, S. Mohan, H. Singh and S. Bindra, Radiat. Phys. Chem., 75, 959 (2006); https://doi.org/10.1016/j.radphyschem.2006.02.008.
M. Pal, B. Roy and M. Pal, J. Mod. Phys., 2, 1062 (2011); https://doi.org/10.4236/jmp.2011.29129.
C. Li and Q. Su, Appl. Phys. Lett., 85, 2190 (2004); https://doi.org/10.1063/1.1797562.