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Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

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Purification and Characterization of Phenolic Antioxidant from Corncob Liquid Smoke

https://doi.org/10.14233/ajchem.2020.22486
Edi Suryanto
Department of Chemistry, Faculty of Mathematics and Natural Science, Sam Ratulangi University, Manado, Indonesia
Mercy R.I. Taroreh
Departement of Food and Science Technology, Faculty of Agricultural, Sam Ratulangi University, Manado, Indonesia
Lydia Irma Momuat
Department of Chemistry, Faculty of Mathematics and Natural Science, Sam Ratulangi University, Manado, Indonesia

Corresponding Author(s) : Edi Suryanto

edi7suryanto@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

Abstract

This study aimed to purify and characterize the antioxidant activity of liquid smoke acquired from corncobs. The smoke of crude liquids was generated through pyrolysis and was purified through fractional and simple distillation. The liquid smoke was analyzed using crude fibres, cellulose, hemicellulose, lignin, antioxidant activity and total phenolic compounds. Gas chromatography-mass spectrometry (GC-MS) was employed to analyze the volatile compounds of liquid smoke. Fractional distillation exhibited the higher carbonyl and phenol content than simple distillation, and the overall acid content of fractional distillation was relatively lower. Moreover, the liquid smoke obtained from fractional distillation exhibited the higher total antioxidant and free radical scavenging activity than simple distillation. The GC-MS results showed different derivatives and phenolic compounds as the most dominant components of the liquid smoke of corncobs. The major antioxidant components of fractional distillation include 2-methoxyphenol, phenol, 2,5-dimethylphenol, 2-methylphenol, 2-methoxy-4-methylphenol, 4-ethyl-2-methoxyphenol and 4-ethylphenol, and those of simple distillation include phenol, 2-methylphenol, 2-methoxy- phenol, 2,6-dimethoxyphenol and 3-ethylphenol.

Keywords

Corn cobs Liquid smoke Distillation GC-MS Antioxidants
Suryanto, E., R.I. Taroreh, M., & Irma Momuat, L. (2020). Purification and Characterization of Phenolic Antioxidant from Corncob Liquid Smoke. Asian Journal of Chemistry, 32(12), 2985–2990. https://doi.org/10.14233/ajchem.2020.22486
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