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Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

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Spectral and Biological Studies: Co(II), Ni(II), Cu(II), Zn(II) and Pd(II) Complexes of 5-Methyl-4-{(3-fluoro-4-methoxybenzylidiene)amino}-3-thiol-1,2,4-triazole

https://doi.org/10.14233/ajchem.2020.22960
Kiran Singh
Department of Chemistry, Kurukshetra University, Kurukshetra-136119, India
Preeti Siwach
Department of Chemistry, Kurukshetra University, Kurukshetra-136119, India
Amit Sharma
Department of Microbiology, Kurukshetra University, Kurukshetra-136119, India

Corresponding Author(s) : Kiran Singh

kiransinghkuk@yahoo.co.in; profkiransingh2017@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

Abstract

A series of metal-complexes of Co2+, Ni2+, Cu2+, Zn2+ and Pd2+ with new Schiff base named 5-methyl-4-((3-fluoro-4-methoxybenzylidiene)-amino)-3-thiol-s-triazole have been synthesized and characterized. Schiff base is formed by the condensation of 3-fluoro-4-methoxy-benzaldehyde and 4-amino-3-mercapto-5-methyl-1,2,4-triazoles (AMMT). After synthesis, Schiff base is characterized by IR and NMR techniques. Metal complexes are characterized by different techniques as IR, NMR, ESR, electronic and fluorescence. Elemental analysis and magnetic measurements of metal complexes have also been carried out. Using different techniques, tentative geometry for newly synthesized complexes have been proposed i.e. square planar for copper and palladium complexes and octahedral for rest of the metal complexes. The biological activities of all the metal complexes of this series are also examined.

Keywords

Biological Triazole Schiff base Metal-complexes NMR
Singh, K., Siwach, P., & Sharma, A. (2020). Spectral and Biological Studies: Co(II), Ni(II), Cu(II), Zn(II) and Pd(II) Complexes of 5-Methyl-4-{(3-fluoro-4-methoxybenzylidiene)amino}-3-thiol-1,2,4-triazole. Asian Journal of Chemistry, 32(12), 3157–3164. https://doi.org/10.14233/ajchem.2020.22960
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