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Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

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Electrochemical and Theoretical Studies of 2-Acetyl Pyridine and Acetophenone Derivatives as Corrosion Inhibitors for Mild Steel in HCl Solution

https://doi.org/10.14233/ajchem.2020.22897
Dharmendra Kumar Singh
Department of Chemistry, B.B.M.K. University, Dhanbad-828130, India
Mantu Kr. Singh
Department of Chemistry, Raja Shiv Prasad College, Jharia-828111, India

Corresponding Author(s) : Dharmendra Kumar Singh

dksslnt@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 12 (2020): Vol 32 Issue 12, 2020

Abstract

2-Acetyl pyridine nicotinic hydrazone and acetophenone nicotinic hydrazone have prepared and their corrosion inhibition properties for mild steel in 1 M HCl were studied using weight loss, electrochemical and density functional theory (DFT) methods. Both inhibitors showed good inhibition ability and their adsorption on mild obeyed Langmuir adsorption isotherm. Polarization measurements show that they can be classified as inhibitors of mixed type. The inhibition efficiencies of 2-acetyl pyridine nicotinic hydrazone and acetophenone nicotinic hydrazone at 2 mM optimum concentration are 96.5% and 87.7% respectively.

Keywords

2-Acetyl pyridine nicotinic hydrazone Acetophenone nicotinic hydrazone Mild steel Acid corrosion Adsorption
Kumar Singh, D., & Kr. Singh, M. (2020). Electrochemical and Theoretical Studies of 2-Acetyl Pyridine and Acetophenone Derivatives as Corrosion Inhibitors for Mild Steel in HCl Solution. Asian Journal of Chemistry, 32(12), 3097–3104. https://doi.org/10.14233/ajchem.2020.22897
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References
  1. F. Bentiss, M. Lebrini, M. Traisnel and M. Lagrenée, J. Appl. Electrochem., 39, 1399 (2009); https://doi.org/10.1007/s10800-009-9810-9
  2. B. El-Mehdi, B. Mernari, M. Traisnel, F. Bentiss and M. Lagrenée, Mater. Chem. Phys., 77, 489 (2003); https://doi.org/10.1016/S0254-0584(02)00085-8
  3. K.M. Govindaraju, D. Gopi and L. Kavitha, J. Appl. Electrochem., 39, 2345 (2009); https://doi.org/10.1007/s10800-009-9920-4
  4. M. Behpour, S.M. Ghoreishi, A. Gandomi-Niasar, N. Soltani and M. Salavati-Niasari, J. Mater. Sci., 44, 2444 (2009); https://doi.org/10.1007/s10853-009-3309-y
  5. E.S. Ferreira, C. Giacomelli, F.C. Giacomelli and A. Spinelli, Mater. Chem. Phys., 83, 129 (2004); https://doi.org/10.1016/j.matchemphys.2003.09.020
  6. C.M. Goulart, A. Esteves-Souza, C.A. Martinez-Huitle, C.J.F. Rodrigues, M.A.M. Maciel and A. Echevarria, Corros. Sci., 67, 281 (2013); https://doi.org/10.1016/j.corsci.2012.10.029
  7. E.E. Ebenso and I.B. Obot, Int. J. Electrochem. Sci., 5, 2012 (2010).
  8. S.K. Shukla and M.A. Quraishi, Corros. Sci., 51, 1007 (2009); https://doi.org/10.1016/j.corsci.2009.02.024
  9. B. Xu, W. Yang, Y. Liu, X. Yin, W. Gong and Y. Chen, Corros. Sci., 78, 260 (2014); https://doi.org/10.1016/j.corsci.2013.10.007
  10. B.D. Mert, M. Erman Mert, G. Kardas and B. Yazici, Corros. Sci., 53, 4265 (2011); https://doi.org/10.1016/j.corsci.2011.08.038
  11. M.R. Maurya, S. Agarwal, M. Abid, A. Azam, C. Bader, M. Ebel, D. Rehder, Dalton. Trans., 21, 937 (2006); https://doi.org/10.1039/B512326G
  12. D.K. Singh, S. Kumar, G. Udayabhanu and R.P. John, J. Mol. Liq., 216, 738 (2016); https://doi.org/10.1016/j.molliq.2016.02.012
  13. D.K. Singh, E.E. Ebenso, M.K. Singh, D. Behera, G. Udayabhanu and R.P. John, J. Mol. Liq., 250, 88 (2018); https://doi.org/10.1016/j.molliq.2017.11.132
  14. R. Yildiz, Corros. Sci., 90, 544 (2015); https://doi.org/10.1016/j.corsci.2014.10.047
  15. Q.B. Zhang and Y.X. Hua, Electrochim. Acta, 54, 1881 (2009); https://doi.org/10.1016/j.electacta.2008.10.025
  16. R. Solmaz, G. Kardas, M. Culha, B. Yazici and M. Erbil, Electrochim. Acta, 53, 5941 (20080); https://doi.org/10.1016/j.electacta.2008.03.055
  17. F. Bentiss, M. Lagrenee, M. Traisnel and J.C. Hornez, Corros. Sci., 41, 789 (1999); https://doi.org/10.1016/S0010-938X(98)00153-X
  18. R. Solmaz, G. Kardas, B. Yazici and M. Erbil, Colloids Surf. A Physicochem. Eng. Asp., 312, 7 (2008); https://doi.org/10.1016/j.colsurfa.2007.06.035
  19. X. Wang, H. Yang and F. Wang, Corros. Sci., 53, 113 (2011); https://doi.org/10.1016/j.corsci.2010.09.029
  20. S.K. Saha, A. Dutta, P. Ghosh, D. Sukul and P. Banerjee, Phys. Chem. Chem. Phys., 18, 17898 (2016); https://doi.org/10.1039/C6CP01993E
  21. A. Doner, R. Solmaz, M. Ozcan and G. Kardas, Corros. Sci., 53, 2902 (2011); https://doi.org/10.1016/j.corsci.2011.05.027
  22. M. Erbil, Chim. Acta Turc., 1, 59 (1988).
  23. G. Avci, Mater. Chem. Phys., 112, 234 (2008); https://doi.org/10.1016/j.matchemphys.2008.05.036
  24. M. Ozcan, I. Dehri and M. Erbil, Appl. Surf. Sci., 236, 155 (2004); https://doi.org/10.1016/j.apsusc.2004.04.017
  25. T. Pajkossy, J. Electroanal. Chem., 364, 111 (1994); https://doi.org/10.1016/0022-0728(93)02949-I
  26. F. Mansfeld, Z. Sun, C.H. Hsu and A. Nagiub, Corros. Sci., 43, 341 (2001); https://doi.org/10.1016/S0010-938X(00)00064-0
  27. A.O. Yüce and G. Kardaº, Corros. Sci., 58, 86 (2012); https://doi.org/10.1016/j.corsci.2012.01.013
  28. A.K. Singh and M.A. Quraishi, Corros. Sci., 51, 2752 (2009); https://doi.org/10.1016/j.corsci.2009.07.011
  29. M. Mahdavian and S. Ashhari, Electrochim. Acta, 55, 1720 (2010); https://doi.org/10.1016/j.electacta.2009.10.055
  30. K.F. Khaled, Electrochim. Acta, 55, 6523 (2010); https://doi.org/10.1016/j.electacta.2010.06.027
  31. Z. El Adnani, M. Mcharfi, M. Sfaira, M. Benzakour, A.T. Benjelloun and M. Ebn Touhami, Corros. Sci., 68, 223 (2013); https://doi.org/10.1016/j.corsci.2012.11.020
  32. I.B. Obot and N.O. Obi-Egbedi, Corros. Sci., 52, 657 (2010); https://doi.org/10.1016/j.corsci.2009.10.017
  33. I. Ahamad, R. Prasad and M.A. Quraishi, Corros. Sci., 52, 933 (2010); https://doi.org/10.1016/j.corsci.2009.11.016
  34. G. Gao and C. Liang, Electrochim. Acta, 52, 4554 (2007); https://doi.org/10.1016/j.electacta.2006.12.058
  35. S.E. Nataraja, T.V. Venkatesha, H.C. Tandon and B.S. Shylesha, Corros. Sci., 53, 4109 (2011); https://doi.org/10.1016/j.corsci.2011.08.019
  36. K.F. Khaled, Corros. Sci., 52, 2905 (2010); https://doi.org/10.1016/j.corsci.2010.05.001
  37. I. Fleming, Frontier Orbitals and Organic Chemical Reactions, John Wiley and Sons: New York (1976).
  38. T. Chakraborty, K. Gazi and D.C. Ghosh, Mol. Phys., 108, 2081 (2010); https://doi.org/10.1080/00268976.2010.505208
  39. L. Li, Q. Qu, W. Bai, F.C. Yang, Y.J. Chen, S.W. Zhang and Z.T. Ding, Corros. Sci., 59, 249 (2012); https://doi.org/10.1016/j.corsci.2012.03.008
  40. X. Ma, X. Jiang, S. Xia, M. Shan, X. Li, L. Yu and Q. Tang, Appl. Surf. Sci., 371, 248 (2016); https://doi.org/10.1016/j.apsusc.2016.02.212
  41. M.J. Bahrami, M.A. Hosseini and P. Pilvar, Corros. Sci., 52, 2793 (2010); https://doi.org/10.1016/j.corsci.2010.04.024
  42. S.K. Shukla and M.A. Quraishi, Corros. Sci., 51, 1990 (2009); https://doi.org/10.1016/j.corsci.2009.05.020
  43. E. Machnikova, K.H. Whitmire and N. Hackerman, Electrochim. Acta, 53, 6024 (2008); https://doi.org/10.1016/j.electacta.2008.03.021
  44. I. Ahamad and M.A. Quraishi, Corros. Sci., 51, 2006 (2009); https://doi.org/10.1016/j.corsci.2009.05.026
  45. B.G. Ateya, B.E. El-Anadouli and F.M.A. El-Nizamy, Corros. Sci., 24, 497 (1984); https://doi.org/10.1016/0010-938X(84)90032-5
  46. L. Vracar and D.M. Drazic, Corros. Sci., 44, 1669 (2002); https://doi.org/10.1016/S0010-938X(01)00166-4
  47. Y. Tang, F. Zhang, S. Hu, Z. Cao, Z. Wu and W. Jing, Corros. Sci., 74, 271 (2013); https://doi.org/10.1016/j.corsci.2013.04.053
  48. F.M. Donahue and K. Nobe, J. Electrochem. Soc., 112, 886 (1965); https://doi.org/10.1149/1.2423723
  49. E. Khamis, F. Bellucci, R.M. Latanision and E.S.H. El-Ashry, Corrosion, 47, 677 (1991); https://doi.org/10.5006/1.3585307
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