Issue

Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024

Copyright (c) 2024 Annam Renita A, Sunitha Salla, Krishnamoorthy.N.R, Kanakaraju.P, Sangeetha.K, Selvakumar.S, Gokul.D

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation of Polycarbazole and Polyaniline Conducting Thin Films and Coating on Indium Tin Oxide by Spin Coating, Dip Coating and Drop Casting

https://doi.org/10.14233/ajchem.2024.32572
A. Annam Renita
Department of Chemistry, Sathyabama Institute of Science and Technlogy, Chennai-600119, India
Sunitha Salla
Department of Chemistry, Sathyabama Institute of Science and Technlogy, Chennai-600119, India
N.R. Krishnamoorthy
Department of Chemistry, Sathyabama Institute of Science and Technlogy, Chennai-600119, India
P. Kanakaraju
SDSC-SHAR, Indian Space Research Organization, Sriharikota-524124, India
K. Sangeetha
SDSC-SHAR, Indian Space Research Organization, Sriharikota-524124, India
S. Selvakumar
SDSC-SHAR, Indian Space Research Organization, Sriharikota-524124, India
D. Gokul
SDSC-SHAR, Indian Space Research Organization, Sriharikota-524124, India
Ankireddy Giridhar
SDSC-SHAR, Indian Space Research Organization, Sriharikota-524124, India

Corresponding Author(s) : A. Annam Renita

reniriana@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024

Abstract

Conducting polymers such as polyaniline (PANI), polycarbazole (PC) and polythiophene (PT) have gained attraction among researchers owing to their outstanding electrical and optical properties. In present study, polyaniline (PANI), polycarbazole (PC) and polythiophene (PT) were prepared by oxidative chemical polymerization followed by their characterization using techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and Raman spectroscopy. The synthesized polymers were further coated with indium tin oxide (ITO) using three different methods viz. spin coating, dip coating and drop casting. The thickness of the films was measured using a Stylus Profilometer and found to be 400 nm for PC and 500 nm for PANI and PT. Therefore, it can be concluded that using suitable process parameters, thin films can be easily obtained from conducting polymers, thus opening new avenues in their application towards sensors, supercapacitors and optoelectronic devices.

Keywords

Polycarbazole Polyaniline Polythiophene Indium tin oxide Spin coating Drop casting Dip coating
Renita, A. A., Salla, S., Krishnamoorthy, N., Kanakaraju, P., Sangeetha, K., Selvakumar, S., … Giridhar, A. (2024). Preparation of Polycarbazole and Polyaniline Conducting Thin Films and Coating on Indium Tin Oxide by Spin Coating, Dip Coating and Drop Casting. Asian Journal of Chemistry, 36(11), 2569–2574. https://doi.org/10.14233/ajchem.2024.32572
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. T.V. Nguyen, Q.V. Le, S. Peng, Z. Dai, S.H. Ahn and S.Y. Kim, Adv. Mater. Technol., 8, 2300474 (2023); https://doi.org/10.1002/admt.202300474
  2. M.G. Tadesse, A.S. Ahmmed and J.F. Lübben, J. Compos. Sci., 8, 53 (2024); https://doi.org/10.3390/jcs8020053
  3. S. Tajik, H. Beitollahi, F.G. Nejad, I.S. Shoaie, M.A. Khalilzadeh, M.S. Asl, Q. Van Le, K. Zhang, H.W. Jang and M. Shokouhimehr, RSC Adv., 10, 37834 (2020); https://doi.org/10.1039/D0RA06160C
  4. C.S. Park, C. Lee and O.S. Kwon, Polymers, 8, 249 (2016); https://doi.org/10.3390/polym8070249
  5. E.A. Ryan, Z.D. Seibers, J.R. Reynolds and M.L. Shofner, J. Appl. Polym. Sci., 55, 225 (2024); https://doi.org/10.1002/app.55225
  6. A. Rehman and X. Zeng, Curr. Opin. Electrochem., 23, 47 (2020); https://doi.org/10.1016/j.coelec.2020.03.010
  7. E. Eskandari, M. Kosari, M.H. Davood Abadi Farahani, N.D. Khiavi, M. Saeedikhani, R. Katal and M. Zarinejad, Sep. Purif. Technol., 231, 115901 (2020); https://doi.org/10.1016/j.seppur.2019.115901
  8. N. Chandrakanthi and M.A. Careem, Polym. Bull., 44, 101 (2000); https://doi.org/10.1007/s002890050579
  9. S. Shahabuddin, R. Gaur, N. Mukherjee, P. Chandra and R. Khanam, Mater. Today Proc., 62, 6950 (2022); https://doi.org/10.1016/j.matpr.2021.12.335
  10. F. Kazemi, S.M. Naghib, Y. Zare and K.Y. Rhee, Polym. Rev., 61, 553 (2021); https://doi.org/10.1080/15583724.2020.1858871
  11. S.S. Shah, S. Oladepo, M.A. Ehsan, W. Iali, A. Alenaizan, M.N. Siddiqui, M. Oyama, A.-R. Al-Betar and M.A. Aziz, Chem. Rec., 24, e202300105 (2024); https://doi.org/10.1002/tcr.202300105
  12. A. Saraswat and S. Kumar, Eur. Polym. J., 200, 112501 (2023); https://doi.org/10.1016/j.eurpolymj.2023.112501
  13. M. Beygisangchin, S.A. Rashid, S. Shafie, A.R. Sadrolhosseini and H.N. Lim, Polymers, 13, 2003 (2021); https://doi.org/10.3390/polym13122003
  14. X. Liu, W. Zheng, R. Kumar, M. Kumar and J. Zhang, Coord. Chem. Rev., 462, 214517 (2022); https://doi.org/10.1016/j.ccr.2022.214517
  15. A. Et Taouil, S. Lakard, F. Dumur, E. Contal and B. Lakard, Synth. Met., 300, 117491 (2023); https://doi.org/10.1016/j.synthmet.2023.117491
  16. J. Bhadra, A. Alkareem and N. Al-Thani, J. Polym. Res., 27, 122 (2020); https://doi.org/10.1007/s10965-020-02052-1
  17. E. Contal, S. Lakard, F. Dumur and B. Lakard, Prog. Org. Coat., 162, 106563 (2022); https://doi.org/10.1016/j.porgcoat.2021.106563
  18. F. Coban, R. Ayranci and M. Ak, Synth. Met., 296, 117356 (2023); https://doi.org/10.1016/j.synthmet.2023.117356
  19. F. Bekkar, F. Bettahar, I. Moreno, R. Meghabar, M. Hamadouche, E. Hernáez, J.L. Vilas-Vilela and L. Ruiz-Rubio, Polymers, 12, 2227 (2020); https://doi.org/10.3390/polym12102227
  20. S.S. Shindalkar, M. Reddy, R. Singh, M.A.M. Nainar and B. Kandasubramanian, Synth. Met., 299, 117467 (2023); https://doi.org/10.1016/j.synthmet.2023.117467
  21. W. Zhang, C. Zhang, J. Liu, X. Wang and S. Zhu, Sol. Energy Mater. Sol. Cells, 251, 112146 (2023); https://doi.org/10.1016/j.solmat.2022.112146
  22. B. Gangopadhyay, A. Roy, D. Paul, S. Panda, B. Das, S. Karmakar, K. Dutta, S. Chattopadhyay and D. Chattopadhyay, ACS Appl. Bio Mater., 7, 485 (2024); https://doi.org/10.1021/acsabm.3c01126
  23. Z. Yu, J. Hu and H. Meng, Front. Mater., 7, 74 (2020); https://doi.org/10.3389/fmats.2020.00074
  24. R. Hu, X. Su, H. Liu, Y. Liu, M.M. Huo and W. Zhang, J. Mater. Sci., 55, 11403 (2020); https://doi.org/10.1007/s10853-020-04825-x
  25. K. Krukiewicz, D. Czerwiñska-G³ówka, R.M. Turczyn, A. Blacha-Grzechnik, C. Vallejo-Giraldo, K. Erfurt, A. Chrobok, J. Faure-Vincent, S. Pouget, D. Djurado and M.J.P. Biggs, ACS Appl. Mater. Interfaces, 15, 45701 (2023); https://doi.org/10.1021/acsami.3c10861
  26. A. Kumar, E. Contal, S. Lakard, F. Dumur, R. Meunier-Prest, L. Viau, M. Bouvet and B. Lakard, Surf. Interfaces, 35, 102447 (2022); https://doi.org/10.1016/j.surfin.2022.102447
  27. G. Zhu, Q. Tang, M. Huang, J. Yang, R. Xu and J. Liu, Sens. Actuators B Chem., 320, 128593 (2020); https://doi.org/10.1016/j.snb.2020.128593
  28. I. Kang, H.-J. Yun, D.S. Chung, S.-K. Kwon and Y.-H. Kim, J. Am. Chem. Soc., 135, 14896 (2013); https://doi.org/10.1021/ja405112s
  29. Y. Wang, Y. Wang, Y. Tian, L. Ma, C. Wang and X. Gao, ECS J. Solid State Sci. Technol., 8, M103 (2019); https://doi.org/10.1149/2.0231910jss
  30. J. Song, Y. Wei, M. Xu, J. Gao, L. Luo, H. Wu, X. Li, Y. Li and X. Wang, ACS Appl. Polym. Mater., 4, 766 (2022); https://doi.org/10.1021/acsapm.1c01224
  31. M.A.C. Mazzeu, L.K. Faria, A.D.M. Cardoso, A.M. Gama, M.R. Baldan and E.S. Gonçalves, J. Aerosp. Technol. Manag., 9, 39 (2017); https://doi.org/10.5028/jatm.v9i1.726
  32. M. Shakir, Noor-e-Iram, M.S. Khan, S.I. Al-Resayes, A.A. Khan and U. Baig, Ind. Eng. Chem. Res., 53, 8035 (2014); https://doi.org/10.1021/ie404314q
  33. S. Sakthivel and A. Boopathi, Int. J. Sci. Res., 141, 97 (2014).
  34. F. Saouti, S. Belaaouad, A. Cherqaoui and Y. Naimi, Biointerface Res. Appl. Chem., 12, 5523 (2021); https://doi.org/10.33263/BRIAC124.55235533
  35. S. Kim, A. Konar, W.S. Hwang, J.H. Lee, J. Lee, J. Yang, C. Jung, H. Kim, J.-B. Yoo, J.-Y. Choi, Y.W. Jin, S.Y. Lee, D. Jena, W. Choi and K. Kim, Nat. Commun., 3, 1011 (2012); https://doi.org/10.1038/ncomms2018
  36. J.L. Carter, C.A. Kelly, J.E. Marshall, V. Hammond, V. Goodship and M.J. Jenkins, Polymers, 14, 5072 (2022); https://doi.org/10.3390/polym14235072
  37. J.L. Carter, C.A. Kelly, J.E. Marshall and M.J. Jenkins, Polym. J., 56, 107 (2023); https://doi.org/10.1038/s41428-023-00854-w
Read More
Author biographies is not available.
Statistic
Read Counter : 0 Download : 0