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Vol. 31 No. 7 (2019): Vol 31 Issue 7

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Olea europaea Subsp. Cuspidata Wood Tar Oil as Anticorrosion for Mild steel in Acidic Media

https://doi.org/10.14233/ajchem.2019.21977
Aisha M. Turkustani
Department of Chemistry Science, Faculty of Science, King Abdulaziz University, Jeddah, Kingdom of Saudi Arabia; Faculty of Science for Girl′s College, Jeddah University, Jeddah, Kingdom of Saudi Arabia
Nehad M. Gumgumji
Faculty of Science for Girl′s College, Jeddah University, Jeddah, Kingdom of Saudi Arabia; Department of Biological Sciences s, Faculty of Science, King Abdulaziz University, Jeddah, Kingdom of Saudi Arabia
Abdulrahman S. Al Hajar
Department of Biological Sciences s, Faculty of Science, King Abdulaziz University, Jeddah, Kingdom of Saudi Arabia

Corresponding Author(s) : Aisha M. Turkustani

a.m.turkustani@hotmail.com; amalturkestani@kau.edu.sa

Asian Journal of Chemistry, Vol. 31 No. 7 (2019): Vol 31 Issue 7

Abstract

Corrosion is one of the serious problems in industry, specially acidic corrosion which is caused by acidic solutions which are widely used in acid cleaning, acid pickling and acid descaling. Mild steel (MS) is widely used in the the industrial field is vulnerable to be corroded by the acidic solution. In the industrial media, corrosion processes are responsible for the loss of metals. There are various methods to mitigation the degradation or destruction of metal surface. Using inhibitors is one of the most potent methods in control of corrosion is due to its low cost and eases of application and practice. As the concern is focused on the safety of any industrial process in health and environment, the use of organic plants as corrosion inhibitors is in the forefront in the current trend of corrosion inhibition studies. In the last decades the need of novel corrosion inhibitor compounds has become more and more stringent. In this study, the efficiency of the bark of Olea europaea subsp. Cuspidata as corrosion inhibitor for mild steel in 1.0 M sulphuric acid was studied by electrochemical measurements [potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS)]. The results showed that Olea europaea subsp. Cuspidate wood tar oil acts as a potent corrosion inhibitor and the performance of the inhibitor varied with concentrations for mild steel in 1.0 M H2SO4 + 10 % EtOH. The maximum inhibition (%) was 94.97 %, the results were supported by different techniques used. Electrochemical analysis indicated that Olea europaea subsp. Cuspidata wood oil tar extract acts as mixed mainly cathodic inhibitor. Also, surface analysis the scanning electron microscope (SEM) was carried out to determine the corrosion inhibition property of Olea europaea subsp. Cuspidata wood tar oil in (1.0 M H2SO4 + 10 % EtOH) solution. The adsorption of the wood tar extract on mild steel surface followed Langmuir isotherm.

Keywords

Mild steel Corrosion Olea europaea subsp. Cuspidate wood tar oil Electrochemical techniques Adsorption
Turkustani, A. M., Gumgumji, N. M., & Al Hajar, A. S. (2019). Olea europaea Subsp. Cuspidata Wood Tar Oil as Anticorrosion for Mild steel in Acidic Media. Asian Journal of Chemistry, 31(7), 1558–1564. https://doi.org/10.14233/ajchem.2019.21977
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