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Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024

Copyright (c) 2024 Manish Manish, Suvarcha Chauhan

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Physico-chemical Study of Surface Active Ionic Liquid (SAIL) in Aqueous Inulin Solutions: Density and Speed of Sound Measurements

https://doi.org/10.14233/ajchem.2024.32387
Manish
Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla-171005, India
https://orcid.org/0009-0005-7794-0193
Suvarcha Chauhan
Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla-171005, India
https://orcid.org/0000-0001-6307-4785

Corresponding Author(s) : Manish

manishthakur84579@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024

Abstract

Colloidal formulations of surface active ionic liquid (SAIL) have substantial benefit as efficient carrier mainly for therapeutic/pharmaceutical agents. In this regard, density (ρ) and speed of sound (u) have been employed to evaluate the diverse interactions/association behaviour of greener SAIL tetrabutylammonium dodecylsulphate (TBADS) (0.222 to 2.2 mmol kg-1) in aqueous inulin solutions (0.0, 0.2 and 0.3% w/w) at five different temperatures ranging from 293.15 K to 313.15 K. The volumetric and acoustic parameters viz. isentropic compressibility (κs), apparent molar volume (Vφ) and compressibility (κs,φ), intermolecular free length (Lf), relative association (RA), specific acoustic impedance (Z) and molar sound number ([U]) have been calculated by using density (ρ) and speed of sound (u) values. The existence of hydrophilic/hydrophobic interactions for TBADS in aqueous inulin solution is suggested by the variations in volumetric parameters, which further supported by various calculated acoustic parameters. Thus, the interactional outcomes can offer implications that stabilized inulin in the presence of SAILs and can be utilized for the optimal biotic actions.

Keywords

Inulin Tetrabutylammonium dodecylsulphate Ionic liquids Density Relative association Aggregation
Manish, & Chauhan, S. (2024). Physico-chemical Study of Surface Active Ionic Liquid (SAIL) in Aqueous Inulin Solutions: Density and Speed of Sound Measurements. Asian Journal of Chemistry, 36(11), 2530–2538. https://doi.org/10.14233/ajchem.2024.32387
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