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Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024

Copyright (c) 2024 Reshma Sachin Pawar Reshma Sachin Pawar

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Adsorption of ortho-Nitrophenol from Aqueous Solution using Phosphated Biomass of Ailanthus excelsa: Kinetic and Equilibrium Studies

https://doi.org/10.14233/ajchem.2024.32333
Reshma S. Pawar
P.G. Department of Chemistry and Research Centre and Prof. Ramkrishna More College, Akurdi-411044, India
https://orcid.org/0009-0008-0686-2476
Kisan M. Gadave
P.G. Department of Chemistry and Research Centre and Prof. Ramkrishna More College, Akurdi-411044, India; P.G. Department of Chemistry and Research Centre and, Annasaheb Magar Mahavidyalaya, Hadapsar-411028, India
https://orcid.org/0009-0004-7118-7332
Shantanu S. Thakare
P.G. Department of Chemistry and Research Centre and, Annasaheb Awate Arts, Commerce & Hutatma Babu Genu Science College, Manchar-410503, India
https://orcid.org/0009-0000-6921-3635
Anandrao A. Kale
P.G. Department of Chemistry and Research Centre and Prof. Ramkrishna More College, Akurdi-411044, India; P.G. Department of Chemistry and Research Centre and, Annasaheb Awate Arts, Commerce & Hutatma Babu Genu Science College, Manchar-410503, India
https://orcid.org/0000-0002-7099-9468

Corresponding Author(s) : Anandrao A. Kale

anandraoakale@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024

Abstract

This study interprets phosphated biomass of Ailanthus excelsa (PBAE) as a eco-friendly, inexpensive and potential adsorbent for adsorption of ortho-nitrophenol (ONP) from aqueous solution by using batch adsorption method. The prepared biosorbent was characterized using a variety of techniques such as Brunauer Emmett Teller (BET), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscope (SEM). As a function of many process parameters including material dose, contact time, concentration, pH and temperature, batch studies were conducted. It was found that a pH of 6.0, a biosorbent dosage of 0.050 g and an initial phenol concentration of 25 mg/L and temperature 298 K were the best conditions for ONP removal. The maximum sorption was found to be 95.28%. Adsorption data was better fitted to the Langmuir, Freundlich, Temkin and Dubinin Radushkevich isotherms. It was demonstrated that the sorption rate follows the pseudo-second order kinetics and intraparticle diffusion theory and the biosorption process was spontaneous and exothermic in nature.

Keywords

Biosorption Phosphated biomass Ailanthus excelsa ortho-Nitrophenol Adsorption isotherms
Pawar, R. S., Gadave, K. M., Thakare, S. S., & Kale, A. A. (2024). Adsorption of ortho-Nitrophenol from Aqueous Solution using Phosphated Biomass of Ailanthus excelsa: Kinetic and Equilibrium Studies. Asian Journal of Chemistry, 36(11), 2547–2555. https://doi.org/10.14233/ajchem.2024.32333
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