Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Dye-Sensitized Solar Cells Using Carissa carandas Linn. Fruits Extract as Dye Sensitizer
Corresponding Author(s) : Kongsak Pattarith
Asian Journal of Chemistry,
Vol. 27 No. 11 (2015): Vol 27 Issue 11
Abstract
Dye-sensitized solar cells (DSSCs) are a promising light harvesting material. The dye sensitizers using as solar energy absorber play a crucial on the conversion efficiency. There are two types of dye sensitizers; organic dyes and inorganic dyes. The organic dyes, derived from nature, have some advantages over the inorganic metal complex dyes as follow; (1) higher absorption coefficients; (2) wide range of absorption spectrum; (3) low-cost and environmentally friendly. In this study, the natural dyes extract from Carissa carandas Linn. fruits was used as sensitizers to fabricate dye-sensitized solar cells. The UV-visible adsorption characteristics of natural dye solution were shown to absorb in visible region at lmax 537.92 nm. The light conversion efficiency (h) of dye-sensitized solar cells reached 1.19 % with a short-circuit current density (ISC) of 3.08 mA cm-2, an open circuit voltage (VOC) of 0.64 V and a fill factor (ff) of 0.56.
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- D. Wei, Int. J. Mol. Sci., 11, 1103 (2010); doi:10.3390/ijms11031103.
- A.O.T. Patrocínio, S.K. Mizoguchi, L.G. Paterno, C.G. Garcia and N.Y.M. Iha, Synth. Met., 159, 2342 (2009); doi:10.1016/j.synthmet.2009.08.027.
- M. Grätzel, J. Photochem. Photobiol. Chem., 164, 3 (2004); doi:10.1016/j.jphotochem.2004.02.023.
- M.K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Mueller, P. Liska, N. Vlachopoulos and M. Graetzel, J. Am. Chem. Soc., 115, 6382 (1993); doi:10.1021/ja00067a063.
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- S. Hao, J. Wu, Y. Huang and J. Lin, Sol. Energy, 80, 209 (2006); doi:10.1016/j.solener.2005.05.009.
- H. Chang and Y.J. Lo, Sol. Energy, 84, 1833 (2010); doi:10.1016/j.solener.2010.07.009.
- P. Luo, H. Niu, G. Zheng, X. Bai, M. Zhang and W. Wang, Spectrochim. Acta A, 74, 936 (2009); doi:10.1016/j.saa.2009.08.039.
- M. Shahid, Shahid-ul-Islam and F. Mohammad, J. Clean. Prod., 53, 310 (2013); doi:10.1016/j.jclepro.2013.03.031.
- K.H. Park, T.Y. Kim, J.Y. Park, E.M. Jin, S.H. Yim, D.Y. Choi and J.W. Lee, Dyes Pigments, 96, 595 (2013); doi:10.1016/j.dyepig.2012.10.005.
- A.S. Polo and N.Y. Murakami Iha, Sol. Energy Mater. Sol. Cells, 90, 1936 (2006); doi:10.1016/j.solmat.2006.02.006.
- H. Zhou, L. Wu, Y. Gao and T. Ma, J. Photochem. Photobiol. Chem., 219, 188 (2011); doi:10.1016/j.jphotochem.2011.02.008.
- G. Calogero, I. Citro, C. Crupi and G. Di Marco, Spectrochim. Acta A, 132, 477 (2014); doi:10.1016/j.saa.2014.04.196.
- Y. Wang, Y. Sun, B. Song and J. Xi, Sol. Energy Mater. Sol. Cells, 92, 660 (2008); doi:10.1016/j.solmat.2008.01.017.
- G. Calogero and G.D. Marco, Sol. Energy Mater. Sol. Cells, 92, 1341 (2008); doi:10.1016/j.solmat.2008.05.007.
- R. Solarska, J. Augustynski and K. Sayama, Electrochim. Acta, 52, 694 (2006); doi:10.1016/j.electacta.2006.06.008.
- H. Chang and Y.J. Lo, Sol. Energy, 84, 1833 (2010); doi:10.1016/j.solener.2010.07.009.
- S. Anandan, S. Latha and P. Maruthamuthu, J. Photochem. Photobiol. Chem., 150, 167 (2002); doi:10.1016/S1010-6030(02)00094-1.
- K. Hara, H. Sugihara, L.P. Singh, A. Islam, R. Katoh, M. Yanagida, K. Sayama, S. Murata and H. Arakawa, J. Photochem. Photobiol. Chem., 145, 117 (2001); doi:10.1016/S1010-6030(01)00570-6.
- N.A. Ludin, A.M. Al-Alwani Mahmoud, A. Bakar Mohamad, A.A.H. Kadhum, K. Sopian and N.S. Abdul Karim, Renew. Sustain. Energy Rev., 31, 386 (2014); doi:10.1016/j.rser.2013.12.001.
- S. Hao, J. Wu, Y. Huang and J. Lin, Sol. Energy, 80, 209 (2006); doi:10.1016/j.solener.2005.05.009.
References
D. Wei, Int. J. Mol. Sci., 11, 1103 (2010); doi:10.3390/ijms11031103.
A.O.T. Patrocínio, S.K. Mizoguchi, L.G. Paterno, C.G. Garcia and N.Y.M. Iha, Synth. Met., 159, 2342 (2009); doi:10.1016/j.synthmet.2009.08.027.
M. Grätzel, J. Photochem. Photobiol. Chem., 164, 3 (2004); doi:10.1016/j.jphotochem.2004.02.023.
M.K. Nazeeruddin, A. Kay, I. Rodicio, R. Humphry-Baker, E. Mueller, P. Liska, N. Vlachopoulos and M. Graetzel, J. Am. Chem. Soc., 115, 6382 (1993); doi:10.1021/ja00067a063.
K.-H. Park, T.-Y. Kim, S. Han, H.-S. Ko, S.-H. Lee, Y.-M. Song, J.-H. Kim and J.-W. Lee, Spectrochim. Acta A, 128, 868 (2014); doi:10.1016/j.saa.2014.03.016.
S. Hao, J. Wu, Y. Huang and J. Lin, Sol. Energy, 80, 209 (2006); doi:10.1016/j.solener.2005.05.009.
H. Chang and Y.J. Lo, Sol. Energy, 84, 1833 (2010); doi:10.1016/j.solener.2010.07.009.
P. Luo, H. Niu, G. Zheng, X. Bai, M. Zhang and W. Wang, Spectrochim. Acta A, 74, 936 (2009); doi:10.1016/j.saa.2009.08.039.
M. Shahid, Shahid-ul-Islam and F. Mohammad, J. Clean. Prod., 53, 310 (2013); doi:10.1016/j.jclepro.2013.03.031.
K.H. Park, T.Y. Kim, J.Y. Park, E.M. Jin, S.H. Yim, D.Y. Choi and J.W. Lee, Dyes Pigments, 96, 595 (2013); doi:10.1016/j.dyepig.2012.10.005.
A.S. Polo and N.Y. Murakami Iha, Sol. Energy Mater. Sol. Cells, 90, 1936 (2006); doi:10.1016/j.solmat.2006.02.006.
H. Zhou, L. Wu, Y. Gao and T. Ma, J. Photochem. Photobiol. Chem., 219, 188 (2011); doi:10.1016/j.jphotochem.2011.02.008.
G. Calogero, I. Citro, C. Crupi and G. Di Marco, Spectrochim. Acta A, 132, 477 (2014); doi:10.1016/j.saa.2014.04.196.
Y. Wang, Y. Sun, B. Song and J. Xi, Sol. Energy Mater. Sol. Cells, 92, 660 (2008); doi:10.1016/j.solmat.2008.01.017.
G. Calogero and G.D. Marco, Sol. Energy Mater. Sol. Cells, 92, 1341 (2008); doi:10.1016/j.solmat.2008.05.007.
R. Solarska, J. Augustynski and K. Sayama, Electrochim. Acta, 52, 694 (2006); doi:10.1016/j.electacta.2006.06.008.
H. Chang and Y.J. Lo, Sol. Energy, 84, 1833 (2010); doi:10.1016/j.solener.2010.07.009.
S. Anandan, S. Latha and P. Maruthamuthu, J. Photochem. Photobiol. Chem., 150, 167 (2002); doi:10.1016/S1010-6030(02)00094-1.
K. Hara, H. Sugihara, L.P. Singh, A. Islam, R. Katoh, M. Yanagida, K. Sayama, S. Murata and H. Arakawa, J. Photochem. Photobiol. Chem., 145, 117 (2001); doi:10.1016/S1010-6030(01)00570-6.
N.A. Ludin, A.M. Al-Alwani Mahmoud, A. Bakar Mohamad, A.A.H. Kadhum, K. Sopian and N.S. Abdul Karim, Renew. Sustain. Energy Rev., 31, 386 (2014); doi:10.1016/j.rser.2013.12.001.
S. Hao, J. Wu, Y. Huang and J. Lin, Sol. Energy, 80, 209 (2006); doi:10.1016/j.solener.2005.05.009.