Copyright (c) 2024 Manimegalai S
This work is licensed under a Creative Commons Attribution 4.0 International License.
A Comprehensive Corrosion Inhibition Behaviour Studies of Leucophyllum frutescens Leaves Extract for Mild Steel
Corresponding Author(s) : S. Manimegalai
Asian Journal of Chemistry,
Vol. 36 No. 9 (2024): Vol 36 Issue 9, 2024
Abstract
In an effort to address corrosion in an environmentally conscious manner, a current study has investigated the efficacy of an acid extract derived from Leucophyllum frutescens leaves as a green corrosion inhibitor for mild steel in acidic conditions (1.0 M HCl solution). The investigation, conducted at room temperature using standard mass loss and electrochemical techniques, varied the extract concentration, temperature and immersion time. Through these experiments, an adsorption isotherm was established and kinetic and thermodynamic parameters were evaluated. The electrochemical measurements suggested a mixed mode of inhibition. Surface analytical techniques including FT-IR, UV-visible, SEM and 3D optical profilometer were employed to confirm the inhibitor’s effectiveness in preventing corrosion by protecting the mild steel surface and impeding hydrogen evolution and metal dissolution. The findings indicate that L. frutescens leaves extract offers promising corrosion protection while being environmental friendly due to its biodegradability and lack of harmful substances such as heavy metals.
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M. Goyal, S. Kumar, I. Bahadur, C. Verma and E.E. Ebenso, J. Mol. Liq., 256, 565 (2018); https://doi.org/10.1016/j.molliq.2018.02.045
D.S. Chauhan, M. Quraishi, A. Sorour, S.K. Saha and P. Banerjee, RSC Adv., 9, 14990 (2019); https://doi.org/10.1039/C9RA00986H
A.S. Fouda, A. El-Askalany, A. El-Habab and S. Ahmed, J. Bio Tribocorros., 5, 56 (2019); https://doi.org/10.1007/s40735-019-0248-2
R. Yildiz, Corros. Sci., 90, 544 (2015); https://doi.org/10.1016/j.corsci.2014.10.047
C. Verma, M. Quraishi, L.O. Olasunkanmi and E.E. Ebenso, RSC Adv., 5, 85417 (2015); https://doi.org/10.1039/C5RA16982H
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A. Espinoza-Vázquez, F.J. Rodríguez-Gómez, I.K. Martínez-Cruz, D. Ángeles-Beltrán, G.E. Negrón-Silva, M. Palomar-Pardavé, L.L. Romero, D. Pérez-Martínez and A.M. Navarrete-López, R. Soc. Open Sci., 6, 181738 (2019); https://doi.org/10.1098/rsos.181738
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M.F. Lebrini, F. Robert and C. Roos, Int. J. Electrochem. Sci., 5, 1698 (2010); https://doi.org/10.1016/S1452-3981(23)15422-8
P.C. Okafor, M.E. Ikpi, E. Uwah, E.E. Ebenso, U.J. Ekpe and S.A. Umoren, Corros. Sci., 50, 2310 (2008); https://doi.org/10.1016/j.corsci.2008.05.009
H. Wei, B. Heidarshenas, L. Zhou, G. Hussain, Q. Li and K. (Ken) Ostrikov, Mater. Today Sustain., 10, 100044 (2020); https://doi.org/10.1016/j.mtsust.2020.100044
M.A. Quraishi, A. Singh, V.K. Singh, D.K. Yadav and A.K. Singh, Mater. Chem. Phys., 122, 114 (2010); https://doi.org/10.1016/j.matchemphys.2010.02.066
P.R. Vijayalakshmi, R. Rajalakshmi and S. Subhashini, J. Chem., 22, 4537 (2010); https://doi.org/10.1155/2010/453694
E.E. Oguzie, C.K. Enenebeaku, C.O. Akalezi, S.C. Okoro, A.A. Ayuk and E.N. Ejike, J. Colloid Interface Sci., 349, 283 (2010); https://doi.org/10.1016/j.jcis.2010.05.027
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A.J. Harborne, Phytochemical Methods A Guide to Modern Techniques of Plant Analysis, Springer Nature (1998).
O.A. Akinbulumo, O.J. Odejobi and E.L. Odekanle, Results Mater., 5, 100074 (2020); https://doi.org/10.1016/j.rinma.2020.100074
P.S. Neriyana and V.D. Alva, Chem. Afr., 3, 1087 (2020); https://doi.org/10.1007/s42250-020-00190-z
A. Berrissoul, E. Loukili, N. Mechbal, F. Benhiba, A. Guenbour, B. Dikici, A. Zarrouk and A. Dafali, J. Colloid Interface Sci., 580, 740 (2020); https://doi.org/10.1016/j.jcis.2020.07.073
A.O. Yuce, Met. Mater. Int., 26, 456 (2020); https://doi.org/10.1007/s12540-019-00509-7
M. Alimohammadi, M. Ghaderi, A. Ramazani S.A and M. Mahdavian, Sci. Rep., 13, 3737 (2023); https://doi.org/10.1038/s41598-023-30571-6
A.K. Singh, B. Chugh, M. Singh, S. Thakur, B. Pani, L. Guo, S. Kaya and G. Serdaroglu, J. Mol. Liq., 330, 115605 (2021); https://doi.org/10.1016/j.molliq.2021.115605
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A.A. Fadhil, A.A. Khadom, S.K. Ahmed, H. Liu, C. Fu and H.B. Mahood, Surf. Interfaces, 20, 100595 (2020); https://doi.org/10.1016/j.surfin.2020.100595
F. Kaya, R. Solmaz and H.I. Geçibesler, J. Ind. Eng. Chem., 122, 102 (2023); https://doi.org/10.1016/j.jiec.2023.02.013