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Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024

Copyright (c) 2024 Arijit Das, Syed Arshad Hussain, Hritinava Banik, Debasish Maiti, Tamanna Aktar, Sandeep Acharya, Paresh Debnath

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Multifunctional Transition Metal Complexes: Design, Synthesis, Luminescent Features, Electrical Behaviour, Nanostructure Morphology and Bioactive Properties with 1,1-Dicyanoethylene-2,2-dithiolate and p-Phenylenediamine Ligands

https://doi.org/10.14233/ajchem.2024.31336
Arijit Das
Department of Chemistry, Bir Bikram Memorial College, Agartala-799004, India
https://orcid.org/0000-0001-7409-7237
Syed Arshad Hussain
Thin Film and Nanoscience Laboratory, Department of Physics, Tripura University, Suryamaninagar-799022, India
https://orcid.org/0000-0002-3298-6260
Hritinava Banik
Thin Film and Nanoscience Laboratory, Department of Physics, Tripura University, Suryamaninagar-799022, India
https://orcid.org/0000-0002-4825-7951
Debasish Maiti
Department of Human Physiology, Tripura University, Agartala-799022, India
https://orcid.org/0000-0002-7228-2794
Tamanna Aktar
Department of Human Physiology, Tripura University, Agartala-799022, India
https://orcid.org/0000-0002-8597-7931
Sandeep Acharya
Department of Botany, R.K. Mahavidyalaya, Kailashahar, Unakoti-799277, India
https://orcid.org/0009-0009-4208-2511
Paresh Debnath
Department of Chemistry, Bir Bikram Memorial College, Agartala-799004, India; Department of Chemistry, National Institute of Technology Agartala, Jirania-799046, India
https://orcid.org/0000-0003-0959-9374

Corresponding Author(s) : Arijit Das

arijitdas78chem@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024

Abstract

Four new transition metal complexes (1-4) were successfully synthesized through the reaction of M(NO3)2·nH2O (M = Ni, Co, Cd or Zn; n = 6 for Ni, Co, Zn; n = 4 for Cd) with 1,1-dicyanoethylene-2,2-dithiolate (i-MNT2–) and p-phenylenediamine (PPD) ligands. The syntheszed metal complexes were characterized by CHN-analysis, electronic, FTIR and 1H NMR spectroscopic techniques. The electronic transition investigations reveals six coordinate octahedral geometry for Ni(II), distorted octahedral for Co(II), four coordinate tetrahedral geometry for Cd(II) and Zn(II) complexes. All the four metal complexes displayed a significant red shift in the absorption maximum, suggesting their successful assembly. The luminescence behaviour exhibited the prominent fluorescence within the visible range. The current-voltage characteristics revealed that complexes 2 and 3 exhibited ohmic behaviour, displaying a linear curve. On the other hand, complexes 1 and 4 initially maintained a low conducting state (OFF state) until a specific voltage threshold (VTh), beyond which the current sharply increased, transitioning to a higher current state (ON state). The FESEM images of the metal complexes strongly indicated a nano-scale aggregated structure. In terms of antibacterial activity, complexes 3 and 4 demonstrated promising efficacy against various bacterial strains, with complex 3 being particularly potent. The fungicidal activity of all four metal complexes was remarkable against Magnaporthe grisea, Cochliobolus miyabeanus and Synchitrium endobioticum, however, no fungicidal activity was found against Trichophyton mentagrophytes and Candida albicans.

Keywords

Metal complexes 1,1-Dithiolates p-Phenylenediamine Antibacterial activity Antifungal activity
Das, A., Hussain, S. A., Banik, H., Maiti, D., Aktar, T., Acharya, S., & Debnath, P. (2024). Multifunctional Transition Metal Complexes: Design, Synthesis, Luminescent Features, Electrical Behaviour, Nanostructure Morphology and Bioactive Properties with 1,1-Dicyanoethylene-2,2-dithiolate and p-Phenylenediamine Ligands. Asian Journal of Chemistry, 36(6), 1348–1358. https://doi.org/10.14233/ajchem.2024.31336
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References
  1. M.K. Singh and A.D. Paul, Transition Met. Chem., 30, 655 (2005); https://doi.org/10.1007/s11243-005-4586-1
  2. M.K. Singh, A. Das and B. Paul, Transition Met. Chem., 32, 732 (2007); https://doi.org/10.1007/s11243-007-0238-y
  3. D.L. Long, Y. Cui, J.T. Chen, W.-D. Cheng and J.-S. Huang, Polyhedron, 17, 3969 (1998); https://doi.org/10.1016/S0277-5387(98)00195-8
  4. D.L. Long, J.T. Chen, Y. Cui and J.S. Huang, Chem. Lett., 27, 171 (1998); https://doi.org/10.1246/cl.1998.171
  5. X.K. Gao, J.M. Dou, D.C. Li, F.-Y. Dong and D.-Q. Wang, J. Chem. Crystallogr., 35, 107 (2005); https://doi.org/10.1007/s10870-005-2798-z
  6. L.Q. Kong, J.M. Dou, D.-C. Li and D.-Q. Wang, J. Mol. Struct., 785, 186 (2006); https://doi.org/10.1016/j.molstruc.2005.10.034
  7. L. Kong, J. Xu, S. Li, D. Li and J. Dou, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 46, 617 (2016); https://doi.org/10.1080/15533174.2014.988803
  8. A.-Q. Zhou and C.-L. Ni, Acta Crystallogr. E Struct. Rep. Online, 63, m3084 (2007); https://doi.org/10.1107/S160053680705814X
  9. Y. Hou, Q. Huang, H. Zuo and C. Ni, Acta Crystallogr. Sect. E Struct. Rep. Online, 63, m2903 (2007); https://doi.org/10.1107/S1600536807053834
  10. X. Chen, D.H. Huang, C.Y. Huang, J.R. Zhou, H.R. Zuo, Q. Huang, Y. Hou, L.L. Yu, L.M. Yang, X.-P. Liu, C.-L. Ni and Q.-J. Meng, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 39, 179 (2009); https://doi.org/10.1080/15533170902857999
  11. S. Perruchas and K. Boubekeur, Dalton Trans., 16, 2394 (2004); https://doi.org/10.1039/B408458F
  12. P.K. Liao, K.G. Liu, C.S. Fang, C.W. Liu, J.P. Fackler Jr. and Y.-Y. Wu, Inorg. Chem., 50, 8410 (2011); https://doi.org/10.1021/ic2009896
  13. N. Kobayashi, T. Naito and T. Inabe, Mol. Cryst. Liq. Cryst., 376, 233 (2010); https://doi.org/10.1080/10587250210784
  14. M.K. Singh, S. Sutradhar, B. Paul, S. Adhikari, F. Laskar, S. Acharya, D. Chakraborty, S. Biswas, A. Das, S. Roy and A. Frontera, J. Mol. Struct., 1164, 334 (2018); https://doi.org/10.1016/j.molstruc.2018.03.073
  15. S.S. Attar, L. Marchiò, L. Pilia, M.F. Casula, D. Espa, A. Serpe, M. Pizzotti, D. Marinotto and P. Deplano, New J. Chem., 43, 12570 (2019); https://doi.org/10.1039/C9NJ02976A
  16. S. Adhikari, T. Bhattacharjee, A. Das, S. Roy, C.G. Daniliuc, J.K. Zarêba, A. Bauzá and A. Frontera, CrystEngComm, 22, 8023 (2020); https://doi.org/10.1039/D0CE01233E
  17. A. Mishra, G.K. Mishra, Anamika, N. Singh, R. Kant and K. Kumar, Dalton Trans., 53, 1680 (2024); https://doi.org/10.1039/D3DT03932C
  18. H. Mehri and Y. Gholiee, Transition Met. Chem., (2024); https://doi.org/10.1007/s11243-024-00579-6
  19. M. Mitra, O. Mrózek, M. Putscher, J. Guhl, B. Hupp, A. Belyaev, C.M. Marian and A. Steffen, Angew. Chem. Int. Ed., 63, e202316300 (2024); https://doi.org/10.1002/anie.202316300
  20. R.P. Tang, K.M. Wong, N. Zhu and V.W. Yam, Dalton Trans., 20, 3911 (2009); https://doi.org/10.1039/b821264c
  21. S. Adhikari, T. Bhattacharjee, S. Bhattacharjee, C.G. Daniliuc, A. Frontera, E.M. Lopato and S. Bernhard, Dalton Trans., 50, 5632 (2021); https://doi.org/10.1039/D1DT00352F
  22. M.K. Singh, S. Sutradhar, B. Paul, S. Adhikari, R.J. Butcher, S. Acharya and A. Das, J. Coord. Chem., 67, 3613 (2014); https://doi.org/10.1080/00958972.2014.972388
  23. M.K. Singh, S. Sutradhar, B. Paul, S. Adhikari, R.J. Butcher, S. Acharya and A. Das, J. Coord. Chem., 68, 1423 (2015); https://doi.org/10.1080/00958972.2015.1013946
  24. M.K. Singh, S. Sutradhar, B. Paul, S. Adhikari, R.J. Butcher, S. Acharya and A. Das, J. Coord. Chem., 69, 168 (2016); https://doi.org/10.1080/00958972.2015.1112004
  25. M.K. Singh, S. Sutradhar, B. Paul, S. Adhikari, F. Laskar, R.J. Butcher, S. Acharya and A. Das, J. Mol. Struct., 1139, 395 (2017); https://doi.org/10.1016/j.molstruc.2017.03.073
  26. S. Adhikari, T. Bhattacharjee, R.J. Butcher, M. Porchia, M. De Franco, C. Marzano, V. Gandin and F. Tisato, Inorg. Chim. Acta, 498, 119098 (2019); https://doi.org/10.1016/j.ica.2019.119098
  27. T. Bhattacharjee, S. Adhikari, S. Bhattacharjee, S. Debnath, A. Das, C.G. Daniliuc, K. Thirumoorthy, S. Malayaperumal, A. Banerjee, S. Pathak and A. Frontera, Inorg. Chim. Acta, 543, 121157 (2022); https://doi.org/10.1016/j.ica.2022.121157
  28. K.A. Jensen, L. Henriksen, O.B. Weeks, U. Schwieter and J. Paasivirta, Acta Chem. Scand., 22, 1107 (1968); https://doi.org/10.3891/acta.chem.scand.22-1107
  29. P. Debnath, P. Debnath M. Roy L. Sieroñ, W. Maniukiewicz, T. Aktar D. Maiti, A.S. Novikov and T.K. Misra, Crystals, 12, 1582 (2022); https://doi.org/10.3390/cryst12111582
  30. A. Barry, in eds.: V. Lorian, Antibiotics in Laboratory Medicine, Williams and Wilkins, Baltimore, MD, p. 116 (1991).
  31. T. Rosu, M. Negoiu, S. Pasculescu, E. Pahontu, D. Poirier and A. Gulea, Eur. J. Med. Chem., 45, 774 (2010); https://doi.org/10.1016/j.ejmech.2009.10.034
  32. F.A. Cotton, G. Wilkinson, C.A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, John Wiley & Sons, Inc., New York, edn. 6, p. 820 (1999).
  33. A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier Publishing Company: New York, p. 318 (1968).
  34. A.M. El-Mahalawy, R.A. Almotiri, M.M. Alkhamisi and A.R. Wassel, Surf. Interfaces, 30, 101953 (2022); https://doi.org/10.1016/j.surfin.2022.101953
  35. P. Debnath, S. Chakraborty, S. Deb, J. Nath, B. Dey, D. Bhattacharjee, H. Soda, M. Tominaga, Y. Suzuki, J. Kawamata and S.A. Hussain, Appl. Clay Sci., 147, 105 (2017); https://doi.org/10.1016/j.clay.2017.07.013
  36. P. Debnath, S. Chakraborty, S. Deb, J. Nath, D. Bhattacharjee and S.A. Hussain, J. Phys. Chem. C, 119, 9429 (2015); https://doi.org/10.1021/acs.jpcc.5b02111
  37. J.P. Fackler Jr. and D. Coucouvanis, J. Am. Chem. Soc., 88, 3913 (1966); https://doi.org/10.1021/ja00969a005
  38. M.A. Bellimam, A. Stambouli, N. El Karni, T. Bouayoun and A. El Bouri, Acta Clin. Belg., 61(sup1), 41 (2006); https://doi.org/10.1179/acb.2006.068
  39. W. Shen, R. Dittmann, U. Breuer and R. Waser, Appl. Phys. Lett., 93, 222102 (2008); https://doi.org/10.1063/1.3039809
  40. B. Dey, S. Sarkar, H. Banik and S. Arshad Hussain, Mater. Today Proc., 46, 6290 (2021); https://doi.org/10.1016/j.matpr.2020.05.192
  41. S. Sarkar, H. Banik, S. Suklabaidya, B. Deb, S. Majumdar, P.K. Paul, D. Bhattacharjee and S.A. Hussain, Langmuir, 37, 4449 (2021); https://doi.org/10.1021/acs.langmuir.0c03629
  42. H. Banik, S. Sarkar, D. Bhattacharjee and S.A. Hussain, ACS Appl. Electron. Mater., 3, 5248 (2021); https://doi.org/10.1021/acsaelm.1c00750
  43. F.Y. Rahman, S. Sarkar, H. Banik, M.J. Uddin, D. Bhattacharjee and S.A. Hussain, Mater. Today Proc., 65, 2693 (2022); https://doi.org/10.1016/j.matpr.2022.05.341
  44. R. Paul, H. Banik, M. Alzaid, D. Bhattacharjee and S.A. Hussain, ACS Omega, 7, 17583 (2022); https://doi.org/10.1021/acsomega.1c07395
  45. A. Das, S.A. Hussain, H. Banik, D. Maiti, T. Aktar, B. Paul, P. Debnath, L. Sieron, A. Bhattacharya, K.L. Bhowmik, W. Maniukiewicz and P. Debnath, Polyhedron, 18, 116747 (2024); https://doi.org/10.1016/j.poly.2023.116747
  46. Y. Anjaneyulu and R.P. Rao, Synth. React. Inorg. Met.-Org. Chem., 16, 257 (1986); https://doi.org/10.1080/00945718608057530
  47. M. Montazerozohori, S. Zahedi, M. Nasr-Esfahani and A. Naghiha, J. Ind. Eng. Chem., 20, 2463 (2014); https://doi.org/10.1016/j.jiec.2013.10.027
  48. N. Dharmaraj, P. Viswanathamurthi and K. Natarajan, Transition Met. Chem., 26, 105 (2001); https://doi.org/10.1023/A:1007132408648
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