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Synthesis, Characterization and Catalytic Activity of Oxovanadium(IV) Complexes of Heterocyclic Acid Hydrazones
Corresponding Author(s) : P.B. Sreeja
Asian Journal of Chemistry,
Vol. 27 No. 11 (2015): Vol 27 Issue 11
Abstract
Two acid hydrazones, furan-2-carbaldehyde nicotinic hydrazone (L1) and furan-2-carbaldehyde benzhydrazone (L2) have been synthesized and they are characterized by elemental analysis, IR, NMR and UV spectral analysis. Oxovanadium(IV) complexes of these two hydrazones were synthesized and characterized by elemental analysis, IR, UV, EPR, molar conductivity and magnetic susceptibility measurements. Conductivity measurements reveal that the complexes are non-electrolytes. Spectral data indicates the square pyramidal geometry for the monomeric five coordinated oxovanadium(IV) complexes with the general formula [VO(L)(OCH3)]. The complex was studied for its catalytic activity and was found to be a good catalyst in quinoxaline synthesis.
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R. Maccari, R. Ottana and M.G. Vigorita, Bioorg. Med. Chem. Lett., 15, 2509 (2005); doi:10.1016/j.bmcl.2005.03.065.
M.M. Heravi, L. Ranjbar, F. Derikvand, H.A. Oskooie and F.F. Bamoharram, J. Mol. Catal. Chem., 265, 186 (2007); doi:10.1016/j.molcata.2006.10.006.
R.C. Maurya and S. Rajput, J. Mol. Struct., 833, 133 (2007); doi:10.1016/j.molstruc.2006.09.022.
U.O. Ozmen and G. Olgun, Spectrochim. Acta A, 70, 641 (2008); doi:10.1016/j.saa.2007.08.012.
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A. Ray, S. Banerjee, S. Sen, R.J. Butcher, G.M. Rosair, M.T. Garland and S. Mitra, Struct. Chem., 19, 209 (2008); doi:10.1007/s11224-007-9274-7.
C.M. Armstrong, P.V. Bernhardt, P. Chin and D.R. Richardson, Eur. J. Inorg. Chem., 1145 (2003); doi:10.1002/ejic.200390146.
P.B. Sreeja, M.R.P. Kurup, A. Kishore and C. Jasmin, Polyhedron, 23, 575 (2004); doi:10.1016/j.poly.2003.11.005.
S.N. Rao, D.D. Mishra, R.C. Maurya and N.N. Rao, Polyhedron, 16, 1825 (1997); doi:10.1016/S0277-5387(96)00487-1.
N. Mathew, M. Kuriakose, E.B. Seena and M.R.P. Kurup, Acta Cryst., E63, o2190 (2007); doi:10.1107/S1600536807014808.
M. Carcelli, P. Cozzini, T. Maccagni, C. Pelizzi and L. Righi, Inorg. Chim. Acta, 303, 238 (2000); doi:10.1016/S0020-1693(00)00040-2.
N.A. Mangalam and M.R.P. Kurup, Spectrochim. Acta A, 71, 2040 (2009); doi:10.1016/j.saa.2008.07.043.
S.A. Sallam, Transition Met. Chem., 30, 341 (2005); doi:10.1007/s11243-004-5859-9.
M.R. Maurya, Coord. Chem. Rev., 237, 163 (2003); doi:10.1016/S0010-8545(02)00293-X.
R. Bikas, H. Hosseini-Monfared, E. Jeanneau and B. Shaabani, J. Chem., Article ID 546287 (2013); doi:10.1155/2013/546287.
D. Collison, B. Gahan, C.D. Garner and F.E. Mabbs, J. Chem. Soc., Dalton Trans., 1980, 667 (1980); doi:10.1039/dt9800000667.
F.E. Dickson, C.J. Kunesh, E.L. McGinnis and L. Petrakis, Anal. Chem., 44, 978 (1972); doi:10.1021/ac60314a009.
P. Corona, A. Carta, M. Loriga, G. Vitale and G. Paglietti, Eur. J. Med. Chem., 44, 1579 (2009); doi:10.1016/j.ejmech.2008.07.025.
Q. Weng, D. Wang, P. Guo, L. Fang, Y. Hu, Q. He and B. Yang, Eur. J. Pharmacol., 581, 262 (2008); doi:10.1016/j.ejphar.2007.12.006.
S. Wagle, A.V. Adhikari and N.S. Kumari, Eur. J. Med. Chem., 44, 1135 (2009); doi:10.1016/j.ejmech.2008.06.006.