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Vol. 31 No. 9 (2019): Vol 31 Issue 9

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Synthesis and Electrochemical Studies of Hexamethyldibenzotetraaza N4-Macrocyclic Complexes of Ni(II) and Cu(II) Metal ions

https://doi.org/10.14233/ajchem.2019.21952
Vinod Kumar Vashistha
Department of Chemistry, G.L.A. University, Mathura-281406, India
Neeraj Sharma
Department of Chemistry, G.L.A. University, Mathura-281406, India
Anuj Kumar
Department of Chemistry, G.L.A. University, Mathura-281406, India
Usha Rani Sharma
Department of Physics, Agra College, Agra-282002, India

Corresponding Author(s) : Vinod Kumar Vashistha

vinod.vashistha@gla.ac.in

Asian Journal of Chemistry, Vol. 31 No. 9 (2019): Vol 31 Issue 9

Abstract

Hexamethyldibenzotetraaza[14]annulene type macrocyclic complexes of Ni(II) and Cu(II) have been synthesized by template method. These macrocyclic complexes were characterized by molar conductance, elemental analysis, IR, UV-visible, mass spectra and cyclic voltammetry. On the basis of electronic studies saddle shape distorted octahedral structure have been assigned to these macrocyclic complexes. The redox behaviour of Ni(II) and Cu(II) macrocyclic complexes showed reversible and quasi-irreversible redox process that supported by the ipc/ipa ratio which is in good agreement with Randles-Sevcik equation. These macrocyclic complexes were also studied for the antimicrobial activity against E. coli, P. aeruginosa, B. subtilis, S. aureus and C. albicans compared with gentamycin as standard drug.

Keywords

Hexamethyldibenzotetraaza[14]annulene Macrocyclic complexes Cyclic voltammetry Antimicrobial activity
Vashistha, V. K., Sharma, N., Kumar, A., & Sharma, U. R. (2019). Synthesis and Electrochemical Studies of Hexamethyldibenzotetraaza N4-Macrocyclic Complexes of Ni(II) and Cu(II) Metal ions. Asian Journal of Chemistry, 31(9), 2116–2120. https://doi.org/10.14233/ajchem.2019.21952
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