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FTIR Spectra of N,N,N',N'-Tetraoctyl Diglycolamide Complex in Room Temperature Ionic Liquids
Corresponding Author(s) : R. Rama
Asian Journal of Chemistry,
Vol. 31 No. 8 (2019): Vol 31 Issue 8
Abstract
The interaction of an octyl derivative of diglycolamide extractant complex in three different types of room temperature ionic liquids (RTILs) was studied by ATR-FTIR spectroscopic method. The shift in stretching vibrational frequencies for the functional groups (C=O and C-O) in the nitrate ion-extractant complexes and metal ion-extractant complexes in room temperature ionic liquids namely, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C4mim][NTf2], 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([C4mpyr][NTf2]) and 1-butyl-1-methylpiperidinium bis(trifluoromethanesulfonyl)imide ([C4mpip][NTf2]) was compared. These results were also compared with that obtained for molecular diluent system, n-dodecane.
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- A.E. Visser, R.P. Swatloski, S.T. Griffin, D.H. Hartman and R.D. Rogers Sep. Sci. Technol., 36, 785 (2001) https://doi.org/10.1081/SS-100103620.
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- M.L. Dietz and D.C. Stepinski, Talanta, 75, 598 (2008); https://doi.org/10.1016/j.talanta.2007.11.051.
- A.E. Visser, R.P. Swatloski, W.M. Reichert, S.T. Griffin and R.D. Rogers, Ind. Eng. Chem. Res., 39, 3596 (2000); https://doi.org/10.1021/ie000426m.
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- E.A. Mowafy and D. Mohamed, Sep. Purif. Technol., 128, 18 (2014); https://doi.org/10.1016/j.seppur.2014.03.005.
- G. Modolo, H. Asp, C. Schreinemachers and H. Vijgen, Solvent Extr. Ion Exch., 25, 703 (2007); https://doi.org/10.1080/07366290701634578.
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- R. Rama, A. Rout, K.A. Venkatesan, M.P. Antony and P.R. Vasudeva Rao, J. Radioanal. Nucl. Chem., 308, 835 (2016); https://doi.org/10.1007/s10967-015-4568-5.
- J.G. Huddleston, A.E. Visser, W.M. Reichert, H.D. Willauer, G.A. Broker and R.D. Rogers, Green Chem., 3, 156 (2001); https://doi.org/10.1039/b103275p.
- D.R. MacFarlane, P. Meakin, J. Sun, N. Amini and M. Forsyth, J. Phys. Chem. B, 103, 4164 (1999); https://doi.org/10.1021/jp984145s.
- T. Prathibha, K.A. Venkatesan and M.P. Antony, Colloids Surf. A Physicochem. Eng. Asp., 538, 651 (2018); https://doi.org/10.1016/j.colsurfa.2017.11.035.
- K.R. Swami, R. Kumaresan, P.K. Nayak, K.A. Venkatesan and M.P. Antony, Vib. Spectrosc., 93, 1 (2017); https://doi.org/10.1016/j.vibspec.2017.08.006.
References
A.E. Visser, R.P. Swatloski, S.T. Griffin, D.H. Hartman and R.D. Rogers Sep. Sci. Technol., 36, 785 (2001) https://doi.org/10.1081/SS-100103620.
J.P. Hallett and T. Welton, Chem. Rev., 111, 3508 (2011); https://doi.org/10.1021/cr1003248.
D.S. Silvester and R.G. Compton, Z. Phys. Chem., 273, 411 (2015); https://doi.org/10.1524/zpch.2006.220.10.1247.
M.L. Dietz and D.C. Stepinski, Talanta, 75, 598 (2008); https://doi.org/10.1016/j.talanta.2007.11.051.
A.E. Visser, R.P. Swatloski, W.M. Reichert, S.T. Griffin and R.D. Rogers, Ind. Eng. Chem. Res., 39, 3596 (2000); https://doi.org/10.1021/ie000426m.
S.A. Ansari, P.N. Pathak, P.K. Mohapatra and V.K. Manchanda, Chem. Rev., 112, 1751 (2012); https://doi.org/10.1021/cr200002f.
D. Magnusson, B. Christiansen, J.-P. Glatz, R. Malmbeck, G. Modolo, D. Serrano-Purroy and C. Sorel, Solvent Extr. Ion Exch., 27, 26 (2009); https://doi.org/10.1080/07366290802544726.
E.A. Mowafy and D. Mohamed, Sep. Purif. Technol., 128, 18 (2014); https://doi.org/10.1016/j.seppur.2014.03.005.
G. Modolo, H. Asp, C. Schreinemachers and H. Vijgen, Solvent Extr. Ion Exch., 25, 703 (2007); https://doi.org/10.1080/07366290701634578.
J. Ravi, K.A. Venkatesan, M.P. Antony, T.G. Srinivasan and P.R. Vasudeva Rao, Solvent Extr. Ion Exch., 32, 424 (2014); https://doi.org/10.1080/07366299.2013.866857.
J. Ravi, A.S. Suneesh, T. Prathibha, K.A. Venkatesan, M.P. Antony, T.G. Srinivasan and P.R. Vasudeva Rao, Solvent Extr. Ion Exch., 29, 86 (2011); https://doi.org/10.1080/07366299.2011.539421.
R. Rama, A. Rout, K.A. Venkatesan, M.P. Antony and P.R. Vasudeva Rao, J. Radioanal. Nucl. Chem., 308, 835 (2016); https://doi.org/10.1007/s10967-015-4568-5.
J.G. Huddleston, A.E. Visser, W.M. Reichert, H.D. Willauer, G.A. Broker and R.D. Rogers, Green Chem., 3, 156 (2001); https://doi.org/10.1039/b103275p.
D.R. MacFarlane, P. Meakin, J. Sun, N. Amini and M. Forsyth, J. Phys. Chem. B, 103, 4164 (1999); https://doi.org/10.1021/jp984145s.
T. Prathibha, K.A. Venkatesan and M.P. Antony, Colloids Surf. A Physicochem. Eng. Asp., 538, 651 (2018); https://doi.org/10.1016/j.colsurfa.2017.11.035.
K.R. Swami, R. Kumaresan, P.K. Nayak, K.A. Venkatesan and M.P. Antony, Vib. Spectrosc., 93, 1 (2017); https://doi.org/10.1016/j.vibspec.2017.08.006.