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Vol. 31 No. 7 (2019): Vol 31 Issue 7

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Triton-B Catalyzed, Green and Efficient Method for the Synthesis of Dithiocarbazates

https://doi.org/10.14233/ajchem.2019.21973
Sadaf Zaidi
Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Uttar Pradesh, Lucknow Campus, Lucknow-226028, India
Mridula Saxena
Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Uttar Pradesh, Lucknow Campus, Lucknow-226028, India

Corresponding Author(s) : Sadaf Zaidi

sadaf.zaidi00@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 7 (2019): Vol 31 Issue 7

Abstract

A novel, solvent free and high yielding method was accomplished for one-pot synthesis of dithiocarbazates by the reaction of various alkyl halides (primary, secondary and tertiary) with variety of substituted hydrazines using Triton-B (benzyl-trimethylammonium hydroxide) and carbon di sulphide. This new method of synthesizing dithiocarbazates involves mild conditions, simple procedures and high yields of the products as compared to previously used methods.

Keywords

Primary alkyl halides Secondary alkyl halides Tertiary alkyl halides Triton-B Carbon disulfide Dithiocarbazates
Zaidi, S., & Saxena, M. (2019). Triton-B Catalyzed, Green and Efficient Method for the Synthesis of Dithiocarbazates. Asian Journal of Chemistry, 31(7), 1581–1584. https://doi.org/10.14233/ajchem.2019.21973
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References
  1. U. Ragnarsson, Chem. Soc. Rev., 30, 205 (2001); https://doi.org/10.1039/b010091a.
  2. B. Mishra, S. Reiling, D. Zarena and G. Wang, Curr. Opin. Chem. Biol., 38, 87 (2017); https://doi.org/10.1016/j.cbpa.2017.03.014.
  3. F.R. Pavan, P.L. da S. Maia, S.R. Leite, V.M. Deflon, A.A. Batista, D.N. Sato, S.G. Franzblau and C.Q. Leite, Eur. J. Med. Chem., 45, 1898 (2010); https://doi.org/10.1016/j.ejmech.2010.01.028.
  4. H. van der Goot, Eur. J. Chem., 35, 5 (2000); https://doi.org/10.1016/S0223-5234(00)00101-X.
  5. E.U. Schmidt, Hydrazine and its Derivatives Preparation, Properties, Applications, Wiley-Interscience: New York, edn 2 (2001).
  6. S. Kubota, M. Uda, Y. Mori, F. Kametani and H. Terada, J. Med. Chem., 21, 591 (1978); https://doi.org/10.1021/jm00204a018.
  7. M.S.C. Pedras and M. Jha, Bioorg. Med. Chem., 14, 4958 (2006); https://doi.org/10.1016/j.bmc.2006.03.014.
  8. N. Bharti, M.R. Maurya, F. Naqvi and A. Azam, Bioorg. Med. Chem. Lett., 10, 2243 (2000); https://doi.org/10.1016/S0960-894X(00)00446-7.
  9. B. Neelam, M. Mannar R, N. Fehmida, B. Alok, B. Sudha and A. Amir, Eur. J. Med. Chem., 35, 481 (2000); https://doi.org/10.1016/S0223-5234(00)00145-8.
  10. H.S. Chen, Z.H. Li, Y.H. Han and Z.W. Wang, Chin. Chem. Lett., 10, 365 (1999).
  11. T.J. Connolly, A.J. Crittall, A.S. Ebrahim and G. Ji, Org. Process Res. Dev., 4, 526 (2000); https://doi.org/10.1021/op0002904.
  12. M.J. Hauser, J. Org. Chem., 31, 968 (1966); https://doi.org/10.1021/jo01341a514.
  13. V. del Amo, A.P. McGlone, C. Foster and A.P. Davis, J. Comb. Chem., 7, 1 (2005); https://doi.org/10.1021/cc049875q.
  14. M.T.H. Tarafder, M.A. Ali, N. Saravanan, W.Y. Weng, S. Kumar, N. Umar-Tsafe and K.A. Crouse, Transition Met. Chem., 25, 3 (2000); https://doi.org/10.1023/A:1007044910814.
  15. S.-N. Li, Q.-G. Zhai, M.-C. Hu and Y.-C. Jiang, J. Chem. Crystallogr., 41, 12 (2011); https://doi.org/10.1007/s10870-010-9825-4.
  16. F.N.-F. How, K.A. Crouse, M.I.M. Tahir, M.T.H. Tarafder and A.R. Cowley, Polyhedron, 27, 3325 (2008); https://doi.org/10.1016/j.poly.2008.07.022.
  17. M. Quibell, W.G. Turnell and T. Johnson, J. Chem. Soc. Perkin Trans. I, 22, 2843 (1993); https://doi.org/10.1039/p19930002843.
  18. C.J. Gray, M. Quibell, N. Baggett and T. Hammerle, Int. J. Pept. Protein Res., 40, 351 (1992); https://doi.org/10.1111/j.1399-3011.1992.tb00311.x.
  19. X. Huang, E. Tang, W.-M. Xu and J. Cao, J. Comb. Chem., 7, 802 (2005); https://doi.org/10.1021/cc0498231.
  20. J.Y. Hwang, H.S. Choi, D.H. Lee and Y.D. Gong, J. Comb. Chem., 7, 816 (2005); https://doi.org/10.1021/cc0500957.
  21. A. Monaci and F. Trali, J. Chem. Soc. Dalton Trans., 499 (1980); https://doi.org/10.1039/DT9800000499.
  22. S.B. Kalia, V. Sharma, K. Lumba, G. Kaushal and A. Sharma, Indian J. Pharm. Sci., 69, 438 (2007); https://doi.org/10.4103/0250-474X.34558.
  23. M.A. Ali and S.E. Livingstone, Coord. Chem. Rev., 13, 101 (1974); https://doi.org/10.1016/S0010-8545(00)80253-2.
  24. M.R. Maurya, S.S. Khurana, A. Azam, W. Zhang and D. Rheder, Eur. J. Inorg. Chem., 2003, 1966 (2003); https://doi.org/10.1002/ejic.200200642.
  25. A. Saxena, J.K. Koacher and J.P.J. Tandon, Antibact. Antifung. Agent, 9, 435 (1981).
  26. C. Bolzati, E. Benini, M. Cavazza-Ceccato, E. Cazzola, E. Malagò, S. Agostini, F. Tisato, F. Refosco and G. Bandoli, Bioconjug. Chem., 17, 419 (2006); https://doi.org/10.1021/bc050358q.
  27. M.A. Ali, A.H. Mirza, R.J. Butcher and K.A. Crouse, Transition Met. Chem., 31, 79 (2006); https://doi.org/10.1007/s11243-005-6305-3.
  28. H. Dyker, J. Scherkenbeck, D. Gondol, A. Goehrt and A. Harder, J. Org. Chem., 66, 3760 (2001); https://doi.org/10.1021/jo001749v.
  29. S. Nara, T. Sakamoto, E. Miyazawa and Y. Kikugawa, Synth. Commun., 33, 87 (2003); https://doi.org/10.1081/SCC-120015563.
  30. D.L. Fox, J.T. Ruxer, J.M. Oliver, K.L. Alford and R.N. Salvatore, Tetrahedron Lett., 45, 401 (2004); https://doi.org/10.1016/j.tetlet.2003.10.144.
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