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Vol. 31 No. 6 (2019): Vol 31 Issue 6

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Chemically Modified Hydroxyapatite Nanocrystals by Temperature-Responsive Poly(N-isopropylacrylamide) via Surface Initiated Radical Polymerization

https://doi.org/10.14233/ajchem.2019.21769
Doan Van Thuan
Institute of Applied Materials Science, Vietnam Academy of Science and Technology, Ho Chi Minh City, Vietnam; NTT Hi-Tech Institute, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
Hieu-Vu Quang
Institute of Applied Materials Science, Vietnam Academy of Science and Technology, Ho Chi Minh City, Vietnam; NTT Hi-Tech Institute, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
Bui Le Minh
Institute of Applied Materials Science, Vietnam Academy of Science and Technology, Ho Chi Minh City, Vietnam; NTT Hi-Tech Institute, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam
Pham Van Thinh
Dong Nai Technology University, Bien Hoa City, Dong Nai Province, Vietnam
Md. Rafiqul Islam
Energy and Mineral Resources Division, Ministry of Power, Energy and Mineral Resources, Government of the People′s Republic of Bangladesh, Bangladesh; Department of Imaging System Engineering, Pukyong National University, Busan, 608-737, Republic of Korea
Van Thi Thanh Ho
Hochiminh University of Natural Resources and Environment, Ho Chi Minh City, Vietnam
Duy Trinh Nguyen
Graduate University of Science and Technology, Vietnam Academy of Science and Technology, Hanoi, Vietnam; Institute of Chemistry, Vietnam Academy of Science and Technology, Hanoi, Vietnam; Center of Excellence for Functional Polymers and Nano Engineering, Nguyen Tat Thanh University, Ho Chi Minh City, Vietnam

Corresponding Author(s) : Duy Trinh Nguyen

ndtrinh@ntt.edu.vn

Asian Journal of Chemistry, Vol. 31 No. 6 (2019): Vol 31 Issue 6

Abstract

This article reports on application of surface-initiated thiol-lactam initiated radical polymerization (TLIRP) method to modify hydroxyapatite nanocrystals (HAP) with thermoresponsive poly(N-isopropylacrylamide) (PNIPAm) brushes through grafting from strategy. Initially, 3-mercaptopropyl trimethoxysilane possessing thiol groups was functionalized with the -OH species on the surface of hydroxyapatite through ligand-exchanging response to introduce thiol species on hydroxyapatite (hydroxyapatite-thiol). Subsequently, attaching polymerization of N-isopropylacrylamide from HAP-SH surface was accomplished in the attendance of butyrolactam to produce PNIPAAm-g-HAP. Thermogravimetric analysis, Fourier transform infrared, X-ray photoelectron spectroscopy and their thermal phase transition behaviour were employed to confirm the grafting and to characterize the nanoparticle structure.

Keywords

Hydroxyapatite nanocrystals Poly(N-isopropylacrylamide) Surface initiated radical polymerization
Thuan, D. V., Quang, H.-V., Minh, B. L., Thinh, P. V., Islam, M. R., Thanh Ho, V. T., & Nguyen, D. T. (2019). Chemically Modified Hydroxyapatite Nanocrystals by Temperature-Responsive Poly(N-isopropylacrylamide) via Surface Initiated Radical Polymerization. Asian Journal of Chemistry, 31(6), 1221–1224. https://doi.org/10.14233/ajchem.2019.21769
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References
  1. B. Lebeau and P. Innocenzi, Chem. Soc. Rev., 40, 886 (2011); https://doi.org/10.1039/C0CS00106F.
  2. L.G. Bach, M.R. Islam, X.T. Cao, J.M. Park and K.T. Lim, J. Alloys Compd., 582, 22 (2014); https://doi.org/10.1016/j.jallcom.2013.07.186.
  3. A.K. Nguyen, T.H. Nguyen, B.Q. Bao, L.G. Bach and D.H. Nguyen, Int. J. Biomater., 2018, Article ID 1575438 (2018); https://doi.org/10.1155/2018/1575438.
  4. P.J. Molino and G.G. Wallace, APL Mater., 3, 014913 (2015); https://doi.org/10.1063/1.4905372.
  5. O. Baranov, I. Levchenko, J.M. Bell, J.W.M. Lim, S. Huang, L. Xu, B. Wang, D.U.B. Aussems, S. Xu and K. Bazaka, Mater. Horizons, 5, 765 (2018); https://doi.org/10.1039/C8MH00326B.
  6. B.Q. Bao, N.H. Le, D.H.T. Nguyen, T.V. Tran, L.P.T. Pham, L.G. Bach, H.M. Ho, T.H. Nguyen and D.H. Nguyen, Mater. Sci. Eng. C, 91, 912 (2018); https://doi.org/10.1016/j.msec.2018.07.008.
  7. H. Liu, Y. Wang, J. Huang, Z. Chen, G. Chen and Y. Lai, Adv. Funct. Mater., 28, 1707415 (2018); https://doi.org/10.1002/adfm.201707415.
  8. A. Alam, Y. Zhang, H.C. Kuan, S.H. Lee and J. Ma, Prog. Polym. Sci., 77, 1 (2018); https://doi.org/10.1016/j.progpolymsci.2017.09.001.
  9. L.G. Bach, B.T.P. Quynh, M.R. Islam and K.T. Lim, J. Nanosci. Nanotechnol., 16, 12856 (2016); https://doi.org/10.1166/jnn.2016.13651.
  10. M.S. Bakshi, Adv. Colloid Interface Sci., 256, 101 (2018); https://doi.org/10.1016/j.cis.2018.04.012.
  11. O.N. Ciocoiu, G. Staikos and C. Vasile, Carbohydr. Polym., 184, 118 (2018); https://doi.org/10.1016/j.carbpol.2017.12.059.
  12. L. Tan, B. Liu, K. Siemensmeyer, U. Glebe and A. Böker, J. Colloid Interface Sci., 526, 124 (2018); https://doi.org/10.1016/j.jcis.2018.04.074.
  13. L.J. Luo, C.C. Huang, H.C. Chen, J.Y. Lai and M. Matsusaki, Carbohydr. Polym., 197, 375 (2018); https://doi.org/10.1016/j.carbpol.2018.06.020.
  14. K. Nagase, T. Okano and H. Kanazawa, Nano-Structures & Nano-jects, 16, 9 (2018); https://doi.org/10.1016/j.nanoso.2018.03.010.
  15. M. Rizwan, G. Mujtaba, S.A. Memon, K. Lee and N. Rashid, Renew. Sustain. Energy Rev., 92, 394 (2018); https://doi.org/10.1016/j.rser.2018.04.034.
  16. M. Hagemann and W.R. Hess, Curr. Opin. Biotechnol., 49, 94 (2018); https://doi.org/10.1016/j.copbio.2017.07.008.
  17. V.A. Risso, J.M. Sanchez-Ruiz and S.B. Ozkan, Curr. Opin. Struct. Biol., 51, 106 (2018); https://doi.org/10.1016/j.sbi.2018.02.007.
  18. D. Tsiourvas, A. Tsetsekou, M.I. Kammenou and N. Boukos, Mater. Sci. Eng. C, 58, 1225 (2016); https://doi.org/10.1016/j.msec.2015.09.076.
  19. M. Okada and T. Furuzono, Mater. Sci. Eng. B, 173, 199 (2010); https://doi.org/10.1016/j.mseb.2009.12.009.
  20. L.G. Bach, M.R. Islam and K.T. Lim, Mater. Lett., 93, 64 (2013); https://doi.org/10.1016/j.matlet.2012.11.051.
  21. L.G. Bach, M.R. Islam, T.S. Vo, S.K. Kim and K.T. Lim, J. Colloid Interface Sci., 394, 132 (2013); https://doi.org/10.1016/j.jcis.2012.11.068.
  22. F. Mohandes, M. Salavati-Niasari, M. Fathi and Z. Fereshteh, Mater. Sci. Eng. C, 45, 29 (2014); https://doi.org/10.1016/j.msec.2014.08.058.
  23. P. Wei, B. Wang, X. Lu, R. Xin and F. Ren, Surf. Coat. Technol., 313, 381 (2017); https://doi.org/10.1016/j.surfcoat.2017.01.108.
  24. L.G. Bach, B.T.P. Quynh and V.T.T. Ho, J. Nanosci. Nanotechnol., 17, 4127 (2017); https://doi.org/10.1166/jnn.2017.13381.
  25. L.G. Bach, B.T.P. Quynh, K.K. Kiet, M.R. Islam and K.T. Lim, J. Nanosci. Nanotechnol., 16, 8814 (2016); https://doi.org/10.1166/jnn.2016.12510.
  26. A. Sobczak-Kupiec, K. Pluta, A. Drabczyk, M. W³oœ and B. Tyliszczak, Ceram. Int., 44, 13630 (2018); https://doi.org/10.1016/j.ceramint.2018.04.199.
  27. J. Chen, M. Liu, Q. Huang, R. Jiang, H. Huang, F. Deng, Y. Wen, J. Tian, X. Zhang and Y. Wei, Mater. Sci. Eng. C, 92, 518 (2018); https://doi.org/10.1016/j.msec.2018.06.054.
  28. N. Ballard and J.M. Asua, Prog. Polym. Sci., 79, 40 (2018); https://doi.org/10.1016/j.progpolymsci.2017.11.002.
  29. X. Wang, L. Shen and Z. An, Prog. Polym. Sci., 83, 1 (2018); https://doi.org/10.1016/j.progpolymsci.2018.05.003.
  30. X.T. Cao, L.G. Bach, M.R. Islam and K.T. Lim, Mol. Cryst. Liq. Cryst., 618, 111 (2015); https://doi.org/10.1080/15421406.2015.1076305.
  31. L.G. Bach, X.T. Cao, B.T.P. Quynh, V.T.T. Ho and K.T. Lim, Mol. Cryst. Liq. Cryst., 644, 183 (2017); https://doi.org/10.1080/15421406.2016.1277478.
  32. C.M.Q. Le, X.T. Cao, L.G. Bach, W.K. Lee, I. Kang and K.T. Lim, Mol. Cryst. Liq. Cryst., 660, 143 (2018); https://doi.org/10.1080/15421406.2018.1456136.
  33. M.A. Söylemez, O. Güven and M. Barsbay, Eur. Polym. J., 103, 21 (2018); https://doi.org/10.1016/j.eurpolymj.2018.03.037.
  34. X. Chen, X. Liu, C. Miao, P. Song and Y. Xiong, Eur. Polym. J., 107, 229 (2018); https://doi.org/10.1016/j.eurpolymj.2018.08.016.
  35. L.G. Bach, Q.T.P. Bui, X.T. Cao, V.T.T. Ho and K.T. Lim, Polym. Bull., 73, 2627 (2016); https://doi.org/10.1007/s00289-016-1712-5.
  36. J. Ran, L. Wu, Z. Zhang and T. Xu, Prog. Polym. Sci., 39, 124 (2014); https://doi.org/10.1016/j.progpolymsci.2013.09.001.
  37. P. Polanowski, K. Halagan, J. Pietrasik, J.K. Jeszka and K. Matyjaszewski, Polymer, 130, 267 (2017); https://doi.org/10.1016/j.polymer.2017.10.011.
  38. F. Lorandi, M. Fantin, A.A. Isse and A. Gennaro, Curr. Opin. Electrochem., 8, 1 (2018); https://doi.org/10.1016/j.coelec.2017.11.004.
  39. L.G. Bach, M.R. Islam, J.T. Kim, S.Y. Seo and K.T. Lim, Appl. Surf. Sci., 258, 2959 (2012); https://doi.org/10.1016/j.apsusc.2011.11.016.
  40. L.G. Bach, X.T. Cao, V.T.T. Ho, M.R. Islam and K.T. Lim, Mol. Cryst. Liq. Cryst., 618, 120 (2015); https://doi.org/10.1080/15421406.2015.1076315.
  41. H.S. Hwang, J.H. Bae, H.G. Kim and K.T. Lim, Eur. Polym. J., 46, 1654 (2010); https://doi.org/10.1016/j.eurpolymj.2010.06.008.
  42. M.H. Rashid, J.H. Bae, C. Park and K.T. Lim, Mol. Cryst. Liq. Cryst., 532, 514 (2010); https://doi.org/10.1080/15421406.2010.497039.
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