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Temperature Effect in Adsorption of Blue HE-3R on Calendula officinalis: Isotherm, Kinetics and Thermodynamics
Corresponding Author(s) : M.K. Raman
Asian Journal of Chemistry,
Vol. 31 No. 6 (2019): Vol 31 Issue 6
Abstract
Adsorption of a textile reactive dye blue HE-3R was carried out with a low-cost adsorbent material i.e., Calendula officinalis. The batch adsorption experiment was done with respect to the effect of pH, concentration of dyes, adsorbent dose and contact time. All the experimental results were analyzed for the suitability of Isotherm models (Freundlich, Langmuir, Redlich-Peterson and Tempkin) and kinetic models (pseudo-first-order, pseudo-second-order, intra-particle diffusion and Elovich). Adsorption process follows Redlich-Peterson isotherm and Pseudo-second order kinetics. The maximum adsorption quantity was found to be 17.85 mg g-1 for the adsorption of blue HE-3R on Calendula officinalis. The low temperature favours the adsorption process. The difference in the SEM image and changes in the group frequencies in FT-IR spectra supports the adsorption of Blue HE-3R on Calendula officinalis effectively.
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References
F.E.F. Rêgo, A.M.S. Solano, I.C. da Costa Soares, D.R. da Silva and C.A.M. Huitle and M. Panizza, J. Environ. Chem. Eng., 2, 875 (2014); https://doi.org/10.1016/j.jece.2014.02.017.
S. Cotillas, J. Llanos, P. Cañizares, D. Clematis, G. Cerisola, M.A. Rodrigo and M. Panizza, Electrochim. Acta, 263, 1 (2018); https://doi.org/10.1016/j.electacta.2018.01.052.
M.H. Farzana and S. Meenakshi, Ind. Eng. Chem. Res., 53, 55 (2014); https://doi.org/10.1021/ie402347g.
J. Shah, M.R. Jan and F. Khitab, Proc. Saf. Environ. Protect., 116, 149 (2018); https://doi.org/10.1016/j.psep.2018.01.008.
M. Liu, Z. Lu, Z. Chen, Z. Yu and C. Gao, Desalination, 281, 372 (2011); https://doi.org/10.1016/j.desal.2011.08.023.
M. Liu, Q. Chen, K. Lu, W. Huang, Z. Lü, C. Zhou, S. Yu and C. Gao, Sep. Purif. Technol., 173, 135 (2017); https://doi.org/10.1016/j.seppur.2016.09.023.
C.S.D. Rodrigues, L.M. Madeira and R.A.R. Boaventura, Ind. Eng. Chem. Res., 52, 13313 (2013); https://doi.org/10.1021/ie401301h.
M. Mohammad, M. Alireza, Process Saf. Environ. Protect., 111, 138 (2017); https://doi.org/10.1016/j.psep.2017.06.008.
M. Wawrzkiewicz, Ind. Eng. Chem. Res., 51, 8069 (2012); https://doi.org/10.1021/ie3003528.
Saruchi, V. Kumar, B.S. Kaith and R. Jindal, Ind. Eng. Chem. Res., 55, 10492 (2016); https://doi.org/10.1021/acs.iecr.6b01690.
H. Li, S. Liu, J. Zhao and N. Feng, Colloids Surfaces A: Physicochem. Eng. Asp., 494, 222 (2016); https://doi.org/10.1016/j.colsurfa.2016.01.048.
R.P.F., Melo, N.E.L. Barros, S.K.S. Nunes, D.T.N. Castro and N.A.A. Dantas, Sep. Purif. Technol., 191, 161 (2018); https://doi.org/10.1016/j.seppur.2017.09.029.
B. Balamurugan, M. Thirumarimurugan and T. Kannadasan, Bioresour. Technol., 102, 6365 (2011); https://doi.org/10.1016/j.biortech.2011.03.017.
B.E.L. Baeta, D.R.S. Lima, S.Q. Silva and S.F. Aquino, Chem. Eng. J., 259, 936 (2015); https://doi.org/10.1016/j.cej.2014.08.050.
S. Sadaf, H.N. Bhatti, S. Ali and K. Rehman, Desalination Water Treat., 52, 184 (2014); https://doi.org/10.1080/19443994.2013.780985.
R. Srivastav and D.C. Rupainwar, Indian J. Chem. Technol., 18, 67 (2011).
M.K. Raman and G. Muthuraman, Int. J. Chemtech Res., 7, 2860 (2015).
M.K. Raman and G. Muthuraman, Iranica J. Energy Environ., 8, 48 (2017); https://doi.org/10.5829/idosi.ijee.2017.08.01.09.
M.K. Raman and G. Muthuraman, Iranian J. Energy Environ., 9, 41 (2018); https://doi.org/10.5829/ijee.2018.09.09.06.