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Vol. 31 No. 5 (2019): Vol 31 Issue 5

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Novel Synthetic Strategy of Cyclic Dithiocarbamates Catalyzed by Triton-B

https://doi.org/10.14233/ajchem.2019.21830
R. Kishore
Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Uttar Pradesh, Lucknow Campus, Lucknow-226028, India
https://orcid.org/0000-0001-8223-1037
M. Kamboj
Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Uttar Pradesh, Lucknow Campus, Lucknow-226028, India
https://orcid.org/0000-0002-9965-7269
M. Shukla
Department of Chemistry, Babu Banarasi Das National Institute of Technology & Management, Lucknow-227105, India
https://orcid.org/0000-0003-0713-1452
N. Srivastava
Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Uttar Pradesh, Lucknow Campus, Lucknow-226028, India
https://orcid.org/0000-0002-4167-0807

Corresponding Author(s) : M. Kamboj

mkamboj@lko.amity.edu

Asian Journal of Chemistry, Vol. 31 No. 5 (2019): Vol 31 Issue 5

Abstract

A simple, rapid and green methodology to synthesize cyclic dithiocarbamates (compounds 1-9) was developed by the reaction of 1° amines, CS2 and ethyl 3-bromo-2-oxopropanoate (ethyl bromopyruvate) facilitated by Triton-B as phase transfer catalyst. These compounds (1-9) were characterized with the help of elemental analysis, IR, NMR and mass spectroscopic methods This efficient green approach requires mild conditions and gives good yield of product. In vitro antimicrobial activities of these compounds are reported against the pathogenic bacteria and fungi.

Keywords

Carbon disulfide Primary amine Dithiocarbamates Triton-B Phase transfer catalyst
Kishore, R., Kamboj, M., Shukla, M., & Srivastava, N. (2019). Novel Synthetic Strategy of Cyclic Dithiocarbamates Catalyzed by Triton-B. Asian Journal of Chemistry, 31(5), 1091–1094. https://doi.org/10.14233/ajchem.2019.21830
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