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Vol. 31 No. 3 (2019): Vol 31 Issue 3

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Synthesis, Characterization and Microbial Evaluation of Heterocyclic Azo Dye Ligand Complexes of Some Transition Metal(II) Ions

https://doi.org/10.14233/ajchem.2019.21800
Jinan Mohammed Mahmood Al-Zinkee
Department of Chemistry, College of Sceince, University of Diyala, Diyala, Iraq
Amer J. Jarad
Department of Chemistry, College of Education for Pure Science/Ibn-Al-Haitham, University of Baghdad, Baghdad, Iraq

Corresponding Author(s) : Amer J. Jarad

amerjj2006@yahoo.com

Asian Journal of Chemistry, Vol. 31 No. 3 (2019): Vol 31 Issue 3

Abstract

The snthesis and characterization of cobalt(II), nickel(II), copper(II) and zinc(II) complexes of azo ligand 4-[(5-acetyl-2-aminophenyl)-diazenyl]-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one derived from 4-aminoantipyrine and 4-aminoacetophenone are reported. The nature of the compounds have been studied followed by mole ratio and methods of continuous contrast, Beer′s law followed during a condensation rate (1 × 10-4 – 3 × 10-4 M). The analytical data showed that all the complexes are in 1:2 metal-ligand ratio. An octahedral geometry have been suggested for all the compounds and biological studies of all the complexes were evaluated against different types of antimicrobial strains.

Keywords

Transition metals Azo dyes Microbioal studies Antipyrine derivatives
Mahmood Al-Zinkee, J. M., & Jarad, A. J. (2019). Synthesis, Characterization and Microbial Evaluation of Heterocyclic Azo Dye Ligand Complexes of Some Transition Metal(II) Ions. Asian Journal of Chemistry, 31(3), 727–732. https://doi.org/10.14233/ajchem.2019.21800
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