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Vol. 31 No. 12 (2019): Vol 31 Issue 12

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Template Synthesis, Characterization and Reactivities of Anionic Transition Metal Complexes with Tetraaza Protonated 11,13-Dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-Diol as Cation

https://doi.org/10.14233/ajchem.2019.22310
B. Vimala
Department of Chemistry, Mother Teresa Women’s University, Kodaikanal-624102, India
S.R. Jayapradha
Department of Chemistry, Government Arts College for Women, Nilakottai-624208, India
A. Selvan
Department of Chemistry, Government Arts College for Women, Nilakottai-624208, India
https://orcid.org/0000-0003-4406-9889

Corresponding Author(s) : A. Selvan

selvamithu6970@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 12 (2019): Vol 31 Issue 12

Abstract

Template synthesis, characterization and reactivities of anionic transition metal complexes with tetraazaprotonated 11,13-dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-diol as cation has been achieved. By magnetic and spectral studies, hexachlorometallate(II) anionic complexes have been found to be octahedral. It is envisioned that the cationic macrocycle may be associating with both the complex and chloride anions through hydrogen bonding thereby rendering the molecule as a whole neutral. Deprotonation, protonation analysis and chemosensor behaviour have been showed by pH variation studies and relevant anionic additions, respectively. All of these data supports the newly synthesized anionic complexes in a strange manner.

Keywords

Anionic coordination complexes Schiff-base macrocyclic complexes Protonated polyazamacrocycles
Vimala, B., Jayapradha, S., & Selvan, A. (2019). Template Synthesis, Characterization and Reactivities of Anionic Transition Metal Complexes with Tetraaza Protonated 11,13-Dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-Diol as Cation. Asian Journal of Chemistry, 31(12), 2924–2930. https://doi.org/10.14233/ajchem.2019.22310
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