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Vol. 31 No. 11 (2019): Vol 31 Issue 11

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Synthesis and Antibacterial Activity of Novel Molybdenum Complexes with Macrocyclic Schiff Base Derived from Furanylethanedione

https://doi.org/10.14233/ajchem.2019.22242
Ramesh Kumar Gautam
Department of Chemistry, D.A.V. (P.G.) College, Kanpur-208001, India
Chandra Prakash Singh
Department of Chemistry, D.B.S. (P.G.) College, Kanpur-208006, India
Shiv Govind Prasad
Department of Chemistry, Uttar Pradesh Textile Technology Institute, Kanpur-208001, India
https://orcid.org/0000-0002-9416-5994
Rajul Saxena
Department of Chemistry, D.A.V. (P.G.) College, Kanpur-208001, India
Devendra Pratap Rao
Department of Chemistry, D.A.V. (P.G.) College, Kanpur-208001, India
https://orcid.org/0000-0003-4628-9121

Corresponding Author(s) : Devendra Pratap Rao

devendraprataprao@yahoo.com

Asian Journal of Chemistry, Vol. 31 No. 11 (2019): Vol 31 Issue 11

Abstract

A new MoO2(VI) complex of formulation [MoO2(L)](acac)2 prepared by a Schiff base, synthesized via reaction of di-2-furanylethanedione with 5-chloropyridine-2,3-diamine and four new MoO2(VI) complexes having formule [MoO2(ML)](acac)2, derived from cyclization of [MoO2(L)](acac)2 with β-diketones are reported in this work. The synthesized MoO2(VI) complexes were characterized on the basis of various analyses like thermal studies, UV-Vis, elemental analyses, NMR, IR and molar conductance. The coordination number of molybdenum metal is six. All the MoO2(VI) complexes have distorted octahedral structure in which Mo atom is coordinated with two O-atoms and four N-atoms. All the complexes show moderate activity against S. typhi and S. aureus. Advancement in the antibacterial task is thought to be of chelation speculation.

Keywords

MoO2(VI) β-Diketones Thermal study Macrocyclic Schiff base
Gautam, R. K., Singh, C. P., Prasad, S. G., Saxena, R., & Rao, D. P. (2019). Synthesis and Antibacterial Activity of Novel Molybdenum Complexes with Macrocyclic Schiff Base Derived from Furanylethanedione. Asian Journal of Chemistry, 31(11), 2607–2612. https://doi.org/10.14233/ajchem.2019.22242
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