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Vol. 31 No. 11 (2019): Vol 31 Issue 11

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Efficient Catalytic Performance of Calcined Tungstophosphoric Acid for the Claisen-Schmidt Condensation under Solvent-Free Reaction

https://doi.org/10.14233/ajchem.2019.22219
Abdulrahman I. Alharthi
Department of Chemistry, College of Science and Humanities in Al-Kharj, Prince Sattam Bin Abdulaziz University, P.O. Box- 83, Al-Kharj 11942, Saudi Arabia
https://orcid.org/0000-0003-3772-6342

Corresponding Author(s) : Abdulrahman I. Alharthi

a.alharthi@psau.edu.sa

Asian Journal of Chemistry, Vol. 31 No. 11 (2019): Vol 31 Issue 11

Abstract

Effect of calcination of tungstophosphoric acid catalyst was evaluated in terms of the synthesis of chalcone derivatives via Claisen-Schmidt condensation using the reaction of acetophenone and several substituted aldehydes. The catalyst was characterized before and after calcination by FT-IR to assess the effectiveness of the synthesis of the desired products. The calcined tungstophosphoric acid catalyst (HPW-CL) showed a better performance and high yield of Claisen-Schmidt products in a short period of time. It was also found out that the calcined tungstophosphoric acid provides a chemo selective, efficient and environmentally benign synthesis of chalcone in an excellent yield in a solvent-free system.

Keywords

Calcination Tungstophosphoric acid Claisen-Schmidt condensation Chalcone derivatives
Alharthi, A. I. (2019). Efficient Catalytic Performance of Calcined Tungstophosphoric Acid for the Claisen-Schmidt Condensation under Solvent-Free Reaction. Asian Journal of Chemistry, 31(11), 2579–2584. https://doi.org/10.14233/ajchem.2019.22219
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