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Synthesis of Eco-Friendly Detergent Based on Crude Palm Oil and Titania Nanoparticles
Corresponding Author(s) : Slamet
Asian Journal of Chemistry,
Vol. 31 No. 10 (2019): Vol 31 Issue 10
Abstract
In this work, we report the synthesis of eco-friendly detergent from crude palm oil and titania. Crude palm oil was converted into methyl ester sulfonate through esterification, transesterification and followed by sulfonation process. As-produced methyl ester sulfonate was characterized with Fourier transformed infrared spectroscopy (FTIR), gas chromatography-mass spectroscopy (GC-MS), liquid chromatography mass spectroscopy (LCMS) and surface tension analysis. Detergents were synthesized by dispersing titania nanoparticles into methyl ester sulfonate solution, forming a nanofluid. Stability and detergency of the nanofluidic detergents were then evaluated. The results showed that the nanofluid detergents were stable in the presence of 0.1 wt % titania and the photocatalytic activity of titania nanoparticles improved the ability of nanofluidic detergents to remove dirt as well as degrading the surfactant residues in the laundry waste stream.
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- L.H.T. Tai and V. Nardello-Rataj, OCL-OL Corps Gras Lipid., 8, 141 (2001).
- M.T. Adiwibowo, M. Ibadurrohman and Slamet, Int. J. Technol., 9, 307 (2018); https://doi.org/10.14716/ijtech.v9i2.1065.
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- M. Cruz, C. Gomez, C.J. Duran-Valle, L.M. Pastrana-Martínez, J.L. Faria, A.M. Silva, M. Faraldos and A. Bahamonde, Appl. Surf. Sci., 416, 1013 (2017); https://doi.org/10.1016/j.apsusc.2015.09.268.
- M. Yan, G. Zeng, X. Li, C. Zhao, G. Yang, J. Gong, G. Chen, L. Tang and D. Huang, New J. Chem., 41, 4377 (2017); https://doi.org/10.1039/C6NJ03196J.
- J. Murcia, E. Ávila-Martínez, H. Rojas, J. Navío and M. Hidalgo, Appl. Catal. B, 200, 469 (2017); https://doi.org/10.1016/j.apcatb.2016.07.045.
- Y.-N. Li, Z.-Y. Chen, S.-J. Bao, M.-Q. Wang, C.-L. Song, S. Pu and D. Long, Chem. Eng. J., 331, 383 (2018); https://doi.org/10.1016/j.cej.2017.08.119.
- Slamet, M. Ibadurrohman and P.P. Wulandari, AIP Conf. Proceed., 1904, 020058 (2017); https://doi.org/10.1063/1.5011915.
- R.M. Silverstein, F.X. Webster, D.J. Kiemle and D.L. Bryce, Spectrometric Identification of Organic Compounds, John Wiley & Sons (2014).
- G. Wang, Y. Morikawa, T. Matsumoto and J. Nakamura, J. Phys. Chem. B, 110, 9 (2006); https://doi.org/10.1021/jp055689e.
References
L.H.T. Tai and V. Nardello-Rataj, OCL-OL Corps Gras Lipid., 8, 141 (2001).
M.T. Adiwibowo, M. Ibadurrohman and Slamet, Int. J. Technol., 9, 307 (2018); https://doi.org/10.14716/ijtech.v9i2.1065.
Slamet and A.S. Redjeki, AIP Conf. Proceed., 1904, 020063 (2017); https://doi.org/10.1063/1.5011920.
M. Sheikholeslami and K. Vajravelu, J. Mol. Liq., 233, 203 (2017); https://doi.org/10.1016/j.molliq.2017.03.026.
S. Aberoumand and A. Jafarimoghaddam, J. Taiwan Inst. Chem. Eng., 71, 315 (2017); https://doi.org/10.1016/j.jtice.2016.12.035.
L. Zhang, Y. Ding, M. Povey and D. York, Prog. Nat. Sci., 18, 939 (2008); https://doi.org/10.1016/j.pnsc.2008.01.026.
M. Cruz, C. Gomez, C.J. Duran-Valle, L.M. Pastrana-Martínez, J.L. Faria, A.M. Silva, M. Faraldos and A. Bahamonde, Appl. Surf. Sci., 416, 1013 (2017); https://doi.org/10.1016/j.apsusc.2015.09.268.
M. Yan, G. Zeng, X. Li, C. Zhao, G. Yang, J. Gong, G. Chen, L. Tang and D. Huang, New J. Chem., 41, 4377 (2017); https://doi.org/10.1039/C6NJ03196J.
J. Murcia, E. Ávila-Martínez, H. Rojas, J. Navío and M. Hidalgo, Appl. Catal. B, 200, 469 (2017); https://doi.org/10.1016/j.apcatb.2016.07.045.
Y.-N. Li, Z.-Y. Chen, S.-J. Bao, M.-Q. Wang, C.-L. Song, S. Pu and D. Long, Chem. Eng. J., 331, 383 (2018); https://doi.org/10.1016/j.cej.2017.08.119.
Slamet, M. Ibadurrohman and P.P. Wulandari, AIP Conf. Proceed., 1904, 020058 (2017); https://doi.org/10.1063/1.5011915.
R.M. Silverstein, F.X. Webster, D.J. Kiemle and D.L. Bryce, Spectrometric Identification of Organic Compounds, John Wiley & Sons (2014).
G. Wang, Y. Morikawa, T. Matsumoto and J. Nakamura, J. Phys. Chem. B, 110, 9 (2006); https://doi.org/10.1021/jp055689e.