Issue

Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Copyright (c) 2024 Rakesh Kumar Sahu, Dr.Sanghamitra Pradhan, Prof.Sujata Mishra

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Molecular Interaction in Ternary Systems of Tri-n-octylamine/Tri-n-butyl Phosphate/Octanoic Acid with n-Hexane and 1-Hexanol at Different Temperatures

https://doi.org/10.14233/ajchem.2024.31992
R.K. Sahu
Department of Chemistry, Institute of Technical Education and Research (FET), Siksha 'O' Anusandhan Deemed to be University, Khandagiri square, Bhubaneswar-751030, India
https://orcid.org/0000-0001-5294-1097
S. Pradhan
Department of Chemistry, Institute of Technical Education and Research (FET), Siksha 'O' Anusandhan Deemed to be University, Khandagiri square, Bhubaneswar-751030, India
https://orcid.org/0000-0002-0200-6014
S. Mishra
Department of Chemistry, Institute of Technical Education and Research (FET), Siksha 'O' Anusandhan Deemed to be University, Khandagiri square, Bhubaneswar-751030, India
https://orcid.org/0000-0002-5191-7965

Corresponding Author(s) : S. Mishra

sujatamishra@soa.ac.in

Asian Journal of Chemistry, Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Abstract

Density, dielectric constant and refractive index were measured for three ternary systems viz. tri-n-octylamine/tri-n-butyl phosphate/octanoic acid (TOA/TBP/OA), with n-hexane and 1-hexanol at T = 303.15, 308.15 and 313.15 K. Derived properties like molar volume, molar polarization, molar refraction and excess parameters were calculated from the measured density, dielectric constant and refractive index values, respectively. The excess values were also calculated with the Redlich-Kister polynomial and the fitting coefficients and standard deviations are reported. The density of the ternary mixtures increased with the increase in the mole fraction of the solute and decreased with the rise of temperature. The negative dielectric constant values for all the systems indicate a reduction in effective dipoles due to the dipolar self-association of the polar molecules. The FT-IR spectra of all the systems indicate a feeble interaction among the extractants, diluent and modifier.

Keywords

Density Molar volume Dielectric constant Refractive index Ternary mixture
Sahu, R., Pradhan, S., & Mishra, S. (2024). Molecular Interaction in Ternary Systems of Tri-n-octylamine/Tri-n-butyl Phosphate/Octanoic Acid with n-Hexane and 1-Hexanol at Different Temperatures. Asian Journal of Chemistry, 36(8), 1895–1902. https://doi.org/10.14233/ajchem.2024.31992
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M. Pirdashti, M. Ketabi, P. Mobalegholeslam, S. Curteanu, E.N. Dragoi and A. Barani, Int. J. Thermophys., 40, 84 (2019); https://doi.org/10.1007/s10765-019-2545-x
  2. G. Gonfa, M.A. Bustam, N. Muhammad and S. Ullah, J. Mol. Liq., 211, 734 (2015); https://doi.org/10.1016/j.molliq.2015.07.073
  3. R. Rives, A. Mialdun, V. Yasnou, V. Shevtsova and A. Coronas, J. Chem. Thermodyn., 160, 106484 (2021); https://doi.org/10.1016/j.jct.2021.106484
  4. S. Pradhan and S. Mishra, J. Mol. Liq., 279, 317 (2019); https://doi.org/10.1016/j.molliq.2019.01.138
  5. G.P. Johari and W. Dannhauser, J. Phys. Chem., 72, 3273 (1968); https://doi.org/10.1021/j100855a030
  6. CH.V.V. Ramana, A.B.V. Kiran Kumar, A.S. Kumar, M.A. Kumar and M.K. Moodley, Thermochim. Acta, 566, 130 (2013); https://doi.org/10.1016/j.tca.2013.05.022
  7. R.J. Sengwa, Madhvi and Abhilasha, J. Mol. Liq., 123, 92 (2006); https://doi.org/10.1016/j.molliq.2005.03.005
  8. T. Vishwam and V.R.K. Murthy, J. Mol. Struct., 1035, 46 (2013); https://doi.org/10.1016/j.molstruc.2012.09.025
  9. R.J. Sengwa and S. Sankhla, J. Non-Cryst. Solids, 353, 4570 (2007); https://doi.org/10.1016/j.jnoncrysol.2007.04.049
  10. J.P. Martínez Jiménez, J.M. Forniés-Marquina, D.D. Rodríguez and S.O. Lacarra, J. Mol. Liq., 139, 48 (2008); https://doi.org/10.1016/j.molliq.2007.10.011
  11. Y. Yin, C. Zhu and Y. Ma, J. Chem. Thermodyn., 102, 413 (2016); https://doi.org/10.1016/j.jct.2016.07.041
  12. K. Binnemans and P.T. Jones, J. Sustain. Metall., 3, 570 (2017); https://doi.org/10.1007/s40831-017-0128-2
  13. Z. Ying, S. Liu, G. Li, Q. Wei and X. Ren, J. Mol. Liq., 384, 122205 (2023); https://doi.org/10.1016/j.molliq.2023.122205
  14. H. Matsuda, K. Tochigi, K. Kurihara and T. Funazukuri, J. Solution Chem., 52, 105 (2023); https://doi.org/10.1007/s10953-022-01220-9
  15. F. Aliajj, A. Hernandez, A. Zeqiraj, N. Syla and T. Arbneshi, Int. J. Thermophys., 45, 3 (2024); https://doi.org/10.1007/s10765-023-03300-4
  16. A.E. Andreatta, A. Arce, E. Rodil and A. Soto, J. Solution Chem., 39, 371 (2010); https://doi.org/10.1007/s10953-010-9507-z
  17. U. Domañska, Int. J. Mol. Sci., 11, 1825 (2010); https://doi.org/10.3390/ijms11041825
  18. H. Gupta, S. Malik, M. Chandrasekhar and V.K. Sharma, J. Therm. Anal. Calorim., 131, 1653 (2018); https://doi.org/10.1007/s10973-017-6587-7
  19. N. Swain, V. Chakravortty, S.K. Singh and D. Panda, Indian J. Chem., 38A, 1116 (1999).
  20. M. Mishra, B. Dalai, S.K. Singh, N. Swain and U.N. Dash, Chem. Data Coll., 33, 100708 (2021); https://doi.org/10.1016/j.cdc.2021.100708
  21. N. Swain, S.K. Singh, D. Panda and V. Chakravortty, J. Mol. Liq., 94, 233 (2001); https://doi.org/10.1016/S0167-7322(01)00271-9
  22. F. Yang, B. Wang, A. Baimoldina, Y. Song, P. Altemose, C. Kowall and L. Li, RSC Adv., 11, 40033 (2021); https://doi.org/10.1039/D1RA08623E
  23. A. Mishra, N. Swain, S. Pradhan and S. Mishra, J. Met. Mater. Miner., 31, 44 (2021); https://doi.org/10.55713/jmmm.v31i1.998
  24. S. Satpathy, S. Pradhan and S. Mishra, J. Radioanal. Nucl. Chem., 313, 531 (2017); https://doi.org/10.1007/s10967-017-5311-1
  25. V.V. Belova, Y.V. Tsareva, Y.A. Zakhodyaeva, V.K. Ivanov and A.A. Voshkin, Processes, 9, 2222 (2021); https://doi.org/10.3390/pr9122222
  26. M. Matsumoto, T. Otono and K. Kondo, Sep. Purif. Technol., 24, 337 (2001); https://doi.org/10.1016/S1383-5866(01)00137-X
  27. R.K. Sahu, S. Pradhan and S. Mishra, Russ. J. Phys. Chem. A. Focus Chem., 96, 2809 (2022); https://doi.org/10.1134/S003602442213012X
  28. R.K. Sahu, S. Pradhan and S. Mishra, ChemistrySelect, 7, e202203900 (2022); https://doi.org/10.1002/slct.202203900
  29. S. Fang, X.B. Zuo, X.J. Xu and D.H. Ren, J. Chem. Thermodyn., 68, 281 (2014); https://doi.org/10.1016/j.jct.2013.09.017
  30. M.N. Hossain, M.M.H. Rocky and S. Akhtar, J. Chem. Eng. Data, 61, 124 (2016); https://doi.org/10.1021/acs.jced.5b00343
  31. O.G. Sas, G.R. Ivanis, M.Lj. Kijevcanin, B. Gonzalez, A. Dominguez and I.R. Radovic, J. Chem. Thermodyn., 162, 106578 (2021); https://doi.org/10.1016/j.jct.2021.106578
  32. U.S. Krishnamoorthy, V. Sundarrajan, R. Ambrose and K. Shenbagam, Int. J. Thermodyn., 25, 040 (2022); https://doi.org/10.5541/ijot.1010582
  33. S. Fang, C.X. Zhao and C.H. He, J. Chem. Eng. Data, 53, 2244 (2008); https://doi.org/10.1021/je8003707
  34. R. Kachangoon, J. Vichapong, Y. Santaladchaiyakit and N. Teshima, ACS Omega, 8, 21332 (2023); https://doi.org/10.1021/acsomega.3c02919
Read More
Author biographies is not available.
Statistic
Read Counter : 0 Download : 0