Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Effect of Surface Modification of Fumed-Silica on Mechanical Properties of Unsaturated Polyester Composites
Corresponding Author(s) : Mustafa Çakir
Asian Journal of Chemistry,
Vol. 27 No. 11 (2015): Vol 27 Issue 11
Abstract
The aim of this study is to investigate the effect of surface modification of fumed silica via vinyltrimethoxysilane on mechanical properties of fumed silica-unsaturated polyester composites. Modified and unmodified fumed silica-unsaturated polyester composites were prepared with the inclusion of vinyltrimethoxysilane in different (0, 0.5, 1, 1.5, 2, 2.5, 3 wt %) contents. SEM images revealed dispersion and agglomeration of inorganic constituents throughout the fracture surface of the composites. FT-IR analysis confirmed succesful conduction of surface modification of fumed silica. Mechanical properties were evaluated via tensile and impact tests. Heat deflection temperature tests were also performed to evaluate thermal behaviour. The most obvious effect of modified fumed silica was seen in impact strength which showed two different trends.
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- M. Zhang and R.P. Singh, Mater. Lett., 58, 408 (2004); doi:10.1016/S0167-577X(03)00512-3.
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- G. Ragosta, M. Abbate, P. Musto, G. Scarinzi and L. Mascia, Polymer, 46, 10506 (2005); doi:10.1016/j.polymer.2005.08.028.
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References
M. Zhang and R.P. Singh, Mater. Lett., 58, 408 (2004); doi:10.1016/S0167-577X(03)00512-3.
S. Sun, C. Li, L. Zhang, H.L. Du and J.S. Burnell-Gray, Eur. Polym. J., 42, 1643 (2006); doi:10.1016/j.eurpolymj.2006.01.012.
I. Klarić, N.S. Vrandečić and U. Roje, J. Appl. Polym. Sci., 78, 166 (2000); doi:10.1002/1097-4628(20001003)78:1<166::AID-APP200>3.0.CO;2-A.
R.D. Deanin and W.-Z.L. Chuang, J. Vinyl Technol., 9, 60 (1987); doi:10.1002/vnl.730090206.
S. Şen and N. Nugay, Eur. Polym. J., 37, 2047 (2001); doi:10.1016/S0014-3057(01)00082-9.
A. Dorigato, M. D’Amato and A. Pegoretti, J. Polym. Res., 19, 9889 (2012); doi:10.1007/s10965-012-9889-2.
L.F. Cai, Z.Y. Lin and H. Qian, Expr. Pol. Lett., 4, 397 (2010); doi:10.3144/expresspolymlett.2010.50.
Y.H. Lai, M.C. Kuo, J.C. Huang and M. Chen, Mater. Sci. Eng. A, 458, 158 (2007); doi:10.1016/j.msea.2007.01.085.
M.Q. Zhang, M.Z. Rong, H.B. Zhang and K. Friedrich, Polym. Eng. Sci., 43, 490 (2003); doi:10.1002/pen.10040.
M.Q. Zhang, M.Z. Rong, H.B. Zhang and K. Friedrich, Polym. Eng. Sci., 43, 490 (2003); doi:10.1002/pen.10040.
F. Bondioli, A. Dorigato, P. Fabbri, M. Messori and A. Pegoretti, Polym. Eng. Sci., 48, 448 (2008); doi:10.1002/pen.20973.
F. Bondioli, A. Dorigato, P. Fabbri, M. Messori and A. Pegoretti, J. Appl. Polym. Sci., 112, 1045 (2009); doi:10.1002/app.29472.
M. Preghenella, A. Pegoretti and C. Migliaresi, Polymer, 46, 12065 (2005); doi:10.1016/j.polymer.2005.10.098.
O. Aso, J.I. Eguiazábal and J. Nazábal, Compos. Sci. Technol., 67, 2854 (2007); doi:10.1016/j.compscitech.2007.01.021.
M. Abdelmouleh, S. Boufi, M.N. Belgacem and A. Dufresne, Compos. Sci. Technol., 67, 1627 (2007); doi:10.1016/j.compscitech.2006.07.003.
A.A. Prabu and M. Alagar, Prog. Org. Coat., 49, 236 (2004); doi:10.1016/j.porgcoat.2003.09.018.
H.-L. Su, J.-M. Hsu, J.-P. Pan and C.-S. Chern, J. Appl. Polym. Sci., 103, 3600 (2007); doi:10.1002/app.25313.
Y. Xie, C.A. Hill, Z. Xiao, H. Militz and C. Mai, Composites Part A, 41, 806 (2010); doi:10.1016/j.compositesa.2010.03.005.
W. Yoshida, R.P. Castro, J.-D. Jou and Y. Cohen, Langmuir, 17, 5882 (2001); doi:10.1021/la001780s.
B. Fiedler, F.H. Gojny, M.H.G. Wichmann, M.C.M. Nolte and K. Schulte, Compos. Sci. Technol., 66, 3115 (2006); doi:10.1016/j.compscitech.2005.01.014.
M. Battistella, M. Cascione, B. Fiedler, M.H.G. Wichmann, M. Quaresimin and K. Schulte, Composites Part A, 39, 1851 (2008); doi:10.1016/j.compositesa.2008.09.010.
B.B. Johnsen, A.J. Kinloch, R.D. Mohammed, A.C. Taylor and S. Sprenger, Polymer, 48, 530 (2007); doi:10.1016/j.polymer.2006.11.038.
G. Ragosta, M. Abbate, P. Musto, G. Scarinzi and L. Mascia, Polymer, 46, 10506 (2005); doi:10.1016/j.polymer.2005.08.028.
M.H.G. Wichmann, M. Cascione, B. Fiedler, M. Quaresimin and K. Schulte, Compos. Interfaces, 13, 699 (2006); doi:10.1163/156855406779366723.
S. Sun, C. Li, L. Zhang, H.L. Du and J.S. Burnell-Gray, Eur. Polym. J., 42, 1643 (2006); doi:10.1016/j.eurpolymj.2006.01.012.
C.L. Wu, M.Q. Zhang, M.Z. Rong and K. Friedrich, Compos. Sci. Technol., 62, 1327 (2002); doi:10.1016/S0266-3538(02)00079-9.