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Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Copyright (c) 2024 Dr. C.Kavitha Chendurpandi, R. Jeevi Esther Rathnakumari,

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Triton X-100 Mediated Electron Transfer Reactions between Iron(III) Polypyridyl Complexes and Phenylsulfinylacetic Acids

Electron transfer reactions between iron(III) polypyridyl complexes and phenylsulfinylacetic acids
https://doi.org/10.14233/ajchem.2024.31880
R. Jeevi Esther Rathnakumari
Department of Chemistry, Nazareth Margoschis College, Nazareth-628617, India
https://orcid.org/0000-0002-6330-2343
C. Kavitha
Department of Chemistry, Aditanar College of Arts and Science, Virapandianpatnam, Tiruchendur-628216, India
https://orcid.org/0000-0001-8015-9836
J. Janet Sylvia Jaba Rose
Department of Chemistry, Nazareth Margoschis College, Nazareth-628617, India
https://orcid.org/0000-0002-4589-2538
P. Subramaniam
Department of Chemistry, Aditanar College of Arts and Science, Virapandianpatnam, Tiruchendur-628216, India
https://orcid.org/0000-0003-0334-9753
V. Vetriselvi
Department of Chemistry, Nazareth Margoschis College, Nazareth-628617, India
https://orcid.org/0009-0008-7629-7804

Corresponding Author(s) : R. Jeevi Esther Rathnakumari

jeeviesther@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Abstract

Oxidative decarboxylation of phenylsulfinylacetic acids (PSAAs) by iron(III) polypyridyl complexes in non-ionic surfactant Triton X-100 medium has been investigated spectrophotometrically. An initial intermediate formation between PSAA and [Fe(NN)3]3+ is confirmed from the observed Michaelis–Menten kinetics and fractional order dependence on PSAA. Applying the Hammett substituent constants to the overall rate constants obtained in TX-100 medium gives non-linear concave upward Hammett plots. A suitable mechanism involving the formation of diphenyl sulphone as product has been proposed. The observed increase in rate with increase in concentration of TX-100 at low concentration range, clearly shows that the reaction takes place in micellar medium and both the reactants are associated or incorporated into micellar phase.

Keywords

Electron transfer reaction Iron(III) polypyridyl complex Phenylsulfinylacetic acid Non-linear Hammett
Rathnakumari, R. J. E., Kavitha, C., Jaba Rose, J. J. S., Subramaniam, P., & Vetriselvi, V. (2024). Triton X-100 Mediated Electron Transfer Reactions between Iron(III) Polypyridyl Complexes and Phenylsulfinylacetic Acids: Electron transfer reactions between iron(III) polypyridyl complexes and phenylsulfinylacetic acids. Asian Journal of Chemistry, 36(8), 1829–1839. https://doi.org/10.14233/ajchem.2024.31880
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