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Vol. 27 No. 11 (2015): Vol 27 Issue 11

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Synthesis, Optical Properties and Morphology of Film of Novel Bridged Double Benzimidazole Perylene Derivative

https://doi.org/10.14233/ajchem.2015.19050
Jing Xu
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P.R. China; Northeast Petroleum University, Qinhuangdao 066004, P.R. China
Jia Wang
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P.R. China
Zhe-Min He
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P.R. China
Xiao-Di Guo
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P.R. China
Ying-Ying Zhang
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P.R. China
Hai-Quan Zhang
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P.R. China

Corresponding Author(s) : Hai-Quan Zhang

hqzhang@ysu.edu.cn; 373003762@qq.com

Asian Journal of Chemistry, Vol. 27 No. 11 (2015): Vol 27 Issue 11

Abstract

A bridged double benzimidazole perylene derivative (BIDP) was synthesized from 3,4,9,10-perylenetetracarboxylic dianhydride. UV-visible spectrum and fluorescence spectrum of BIDP were studied in DMF, which showed that the maximum absorption peak was at 525 nm and the other characteristic absorption peaks were at 498 and 566 nm and the emission peak was at 540 and 580 nm. Then the film of BIDP was made by the electrodeposition. The optical physical properties, morphology and aggregation structure were investigated by UV-visible and fluorescence spectra. The characterization were investigated by UV-visible, fluorescence spectrum, SEM and XRD. Finally, the electrodeposition films that had ordered morphology were got by DMF vapour annealing.

Keywords

Bridged double benzimidazole perylene derivative Electrodeposition Film Optical physical properties Aggregation structure
Xu, J., Wang, J., He, Z.-M., Guo, X.-D., Zhang, Y.-Y., & Zhang, H.-Q. (2015). Synthesis, Optical Properties and Morphology of Film of Novel Bridged Double Benzimidazole Perylene Derivative. Asian Journal of Chemistry, 27(11), 4013–4016. https://doi.org/10.14233/ajchem.2015.19050
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