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Vol. 36 No. 7 (2024): Vol 36 Issue 7, 2024

Copyright (c) 2024 SHYNI B, REMIYA J P, Sikha T S

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Synthesis, Characterization and Applications of Some Lanthanide(III) Complexes with Schiff Base Derived from L-Valine and Vanillin

https://doi.org/10.14233/ajchem.2024.31646
B. Shyni
Department of Chemistry, Mahatma Gandhi College, University of Kerala, Thiruvananthapuram-695004, India
https://orcid.org/0009-0001-8214-2816
J.P. Remiya
Department of Chemistry, Mahatma Gandhi College, University of Kerala, Thiruvananthapuram-695004, India
https://orcid.org/0000-0002-7932-1805
T.S. Sikha
Department of Chemistry, Mahatma Gandhi College, University of Kerala, Thiruvananthapuram-695004, India
https://orcid.org/0000-0002-0275-9382

Corresponding Author(s) : T.S. Sikha

drsikhadinesh@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 7 (2024): Vol 36 Issue 7, 2024

Abstract

Three lanthanide complexes of Sm(III), Nd(III) and Dy(III) with Schiff base ligand, potassium 2-((4-hydroxy-3-methoxybenzylidene)amino)-3-methylbutanoate derived from the condensation of vanillin and L-valine have been successfully synthesized by solid-state method. The elemental analysis, and spectral studies, such as CHN analysis, FT-IR & FIR, UV-Visible, HR-MS, TG/DTG analysis, photoluminescent spectra and conductivity measurements, were employed for the comprehensive characterization of these compounds. These data indicate that the synthesized Schiff base ligand act as tridentate (ONO) manner towards the metal ions. Additionally, diverse biological activities such as antimicrobial, antioxidant, antidiabetic, anti-inflammatory and larvicidal activities of the ligand and its lanthanide(III) complexes were analyzed.

Keywords

Photoluminescent spectra Thermal decomposition Biological activities Larvicidal activity
Shyni, B., Remiya, J., & Sikha, T. (2024). Synthesis, Characterization and Applications of Some Lanthanide(III) Complexes with Schiff Base Derived from L-Valine and Vanillin. Asian Journal of Chemistry, 36(7), 1549–1558. https://doi.org/10.14233/ajchem.2024.31646
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