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Vol. 26 No. 17 (2014): Vol 26 Issue 17

Copyright (c) 2014 Xiao-Min Hao, Gang Chen, Chang-Sheng Gu

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Synthesis, Structure, Luminescence and Thermal Stable Properties of Zn(II) Coordination Polymer Constructed from 2-Hydroxyphenylacetic Acid and 4,4'-Trimethylenendipyridine

https://doi.org/10.14233/ajchem.2014.18194
Xiao-Min Hao
Department of Chemistry, Harbin Institute of Technology, Harbin, P.R. China Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, P.R. China
Gang Chen
Department of Chemistry, Harbin Institute of Technology, Harbin, P.R. China
Chang-Sheng Gu
Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, P.R. China

Corresponding Author(s) : Chang-Sheng Gu

gcsheng1968@126.com

Asian Journal of Chemistry, Vol. 26 No. 17 (2014): Vol 26 Issue 17

Abstract

A novel complex 1 of [Zn(tdp)(dpa)2]n (Hdpa: 2-hydroxyphenylacetic acid; tdp: 4,4'-trimethylenendipyridine) was prepared and characterized by elemental analysis, IR, TGA, X-rey single crystal diffraction. The carboxylate oxygens of the 2-hydroxyphenylacetic acid (Hdpa) ligands connect one Zn(II) ion in monodentate coordinated modes to form mononuclear zinc(II) building blocks, which are further linked into a 1D infinite chain through trans-tdp igands. Furthermore, the luminescent properties of 1 was also investigated.

Keywords

Zn(II) coordinated polymer Crystal structure Luminesce
Hao, X.-M., Chen, G., & Gu, C.-S. (2014). Synthesis, Structure, Luminescence and Thermal Stable Properties of Zn(II) Coordination Polymer Constructed from 2-Hydroxyphenylacetic Acid and 4,4’-Trimethylenendipyridine. Asian Journal of Chemistry, 26(17), 5735–5738. https://doi.org/10.14233/ajchem.2014.18194
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