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Vol. 36 No. 7 (2024): Vol 36 Issue 7, 2024

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Selective Sensing and Determination of Cu2+ Ions in Environmental Samples with Newly Prepared Quinoline based Chemosensors and Confirmation of Results using DFT Molecular Modelling

https://doi.org/10.14233/ajchem.2024.31456
G.O. Obaiah
Department of Chemistry, Karnataka State Open University, Mukhtagangotri, Mysuru-570006, India
https://orcid.org/0000-0002-4683-7370
M.A. Abdulzahra
Department of Pharmacy, Al-Amal College for Specialized Medical Sciences, Karbala-56001, Iraq
https://orcid.org/0000-0003-2392-4444
A. Tewari
Department of Basic Science and Humanities, Pranveer Singh Institutue of Technology, Bhauti, Kanpur-209305, India
https://orcid.org/0000-0002-1456-649X
M.S. Patel
Mohammed Al-Mana College for Medical Sciences, Dammam, Kingdom of Saudi Arabia
https://orcid.org/0000-0002-8548-6489
V.S. Talismanov
Department of Chemistry, Moscow Institute of Physics and Technology, Dolgoprudny, Moscow Region, 141701, Russian Federation
https://orcid.org/0000-0003-0511-9943
N.K. Sharma
Department of Chemistry, Government P.G. College, Bundi-323001, India
https://orcid.org/0000-0002-4098-8143
S. Sehlangia
Department of Chemistry, School of Basic Sciences, Indian Institute of Technology Mandi, Kamand-175005, India
https://orcid.org/0000-0001-7857-9583
M.S. Thakare
Department of Chemistry, Pratap College (Autonomous), Amalner-425401, India
https://orcid.org/0000-0002-1231-7668

Corresponding Author(s) : S. Sehlangia

sumanyadav1708@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 7 (2024): Vol 36 Issue 7, 2024

Abstract

An efficient turn-off-fluorescence chemosensing method has been developed to detect Cu2+ ions in a variety of samples. Two new quinoline-based chemosensors (QC1 and QC2) have been prepared under the condensation reaction of 8-quinolinecarboxylic acid with derivatives of L-valine. The synthesized chemosensors were characterized by spectroscopic techniques such as 1H NMR, UV, IR, HRMS and CHNS. The HOMO-LUMO orbitals and energy-minimized structures of the chemosensors were developed. The interaction of metal ions with chemosensors and stable structures of complexes were investigated using DFT. The photoluminescence analysis of both chemosensors (QC1 and QC2) showed the fluorescence emission wavelengths on 495 and 512 nm, respectively, for QC1 and QC2. The change in fluorescence emission wavelengths depends on the electronic effects of the substituents on the quinoline ring. The chemosensors showed a high sensitivity for Cu ions; thus, the detection was exhibited in nanomolar levels. The chemosensing studies were performed in the presence of different metal ions and samples taken from other sources.

Keywords

L-Valine Quinoline derivatives Fluorescent probes Chemosensor Environmental samples
Obaiah, G., Abdulzahra, M., Tewari, A., Patel, M., Talismanov, V., Sharma, N., … Thakare, M. (2024). Selective Sensing and Determination of Cu2+ Ions in Environmental Samples with Newly Prepared Quinoline based Chemosensors and Confirmation of Results using DFT Molecular Modelling. Asian Journal of Chemistry, 36(7), 1571–1578. https://doi.org/10.14233/ajchem.2024.31456
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