Issue

Vol. 36 No. 3 (2024): Vol 36 Issue 3, 2024

Copyright (c) 2024 B. Thippeswamy, P.A. Suchetan, G.R. Vijayakumar, B. Somashekara, I. Mallikarjuna

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Structural Characterization and Photophysical Properties of Bis(4′-chloro-2,2′:6′,2″-terpyridyl)nickel(II)chloride Dihydrate

https://doi.org/10.14233/ajchem.2024.30843
B. Thippeswamy
1Department of Chemistry, University College of Science, Tumkur University, Tumakuru-572103, India 2Department of Chemistry, Maharani’s Science College for Women (Autonomous), Mysuru-570005, India
https://orcid.org/0009-0003-5174-4026
P.A. Suchetan
Department of Chemistry, University College of Science, Tumkur University, Tumakuru-572103, India
https://orcid.org/0000-0002-0322-4160
G.R. Vijayakumar
Department of Chemistry, University College of Science, Tumkur University, Tumakuru-572103, India
https://orcid.org/0000-0002-5894-3250
B. Somashekara
Department of Chemistry, Smt. Indira Gandhi Government First Grade Women’s College, Sagar-577401, India
https://orcid.org/0000-0002-0063-6047
I. Mallikarjuna
Department of Chemistry, Maharani’s Science College for Women (Autonomous), Mysuru-570005, India
https://orcid.org/0000-0002-4864-8119

Corresponding Author(s) : G.R. Vijayakumar

vijaykumargr18@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 3 (2024): Vol 36 Issue 3, 2024

Abstract

Nickel(II) complex viz. bis(4′-chloro-2,2′:6′,2″-terpyridyl)nickel(II)chloride dihydrate, [Ni(Cltpy)2]Cl2·2H2O where Cltpy is a tridentate ligand was synthesized under mild conditions by conventional method. The octahedral geometry of nickel(II) complex was revealed by single crystal X-ray diffraction (SCXRD) studies. The synthesized Ni(II) complex was characterized by Fourier transform-infrared (FT-IR), elemental analysis, scanning electron microscope (SEM), thermal analysis (TG-DTA), photoluminescence (PL) and diffuse reflectance (DR) spectra. A prominent peak at 630 nm was recorded in the DR spectrum and the band gap energy of 2.38 eV was resulted in accordance with Kubelka-Munk (K-M) theory. The photoluminescent spectra of the synthesized nickel(II) complex displayed the emission of blue green light. The commission internationale de l’eclairage (CIE) coordinates (0.2641, 0.3722) were obtained from its CIE graph.

Keywords

Terpyridine Photoluminescence Diffuse reflectance Single crystal XRD Thermogravimetry
Thippeswamy, B., Suchetan, P., Vijayakumar, G., Somashekara, B., & Mallikarjuna, I. (2024). Synthesis, Structural Characterization and Photophysical Properties of Bis(4′-chloro-2,2′:6′,2″-terpyridyl)nickel(II)chloride Dihydrate. Asian Journal of Chemistry, 36(3), 571–578. https://doi.org/10.14233/ajchem.2024.30843
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. C.W. Tang and S.A. VanSlyke, Appl. Phys. Lett., 51, 913 (1987); https://doi.org/10.1063/1.98799
  2. M.A. Baldo, D.F. O'Brien, Y. You, A. Shoustikov, S. Sibley, M.E. Thompson and S.R. Forrest, Nature, 395, 151(1998); https://doi.org/10.1038/25954
  3. S.A. Sapp, C.M. Elliott, C. Contado, S. Caramori and C.A. Bignozzi, J. Am. Chem. Soc., 124, 11215 (2002); https://doi.org/10.1021/ja027355y
  4. W. Zhang, P. Liu, A. Sadollahkhani, Y. Li, B. Zhang, F. Zhang, M. Safdari, Y. Hao, Y. Hua and L. Kloo, ACS Omega, 2, 9231 (2017); https://doi.org/10.1021/acsomega.7b01434
  5. G. Li, M.D. Brady and G.J. Meyer, J. Am. Chem. Soc., 140, 5447 (2018); https://doi.org/10.1021/jacs.8b00944
  6. M. Srinivas, T.O.S. Kumar, K.M. Mahadevan, S. Naveen, G.R. Vijayakumar, H. Nagabhushana, M.N. Kumara and N.K. Lokanath, J. Sci. Adv. Mater. Devices, 1, 324 (2016); https://doi.org/10.1016/j.jsamd.2016.07.002
  7. B.Z. Momeni, F. Rahimi, S.M. Jebraeil and J. Janczak, J. Mol. Struct., 1150, 196 (2017); https://doi.org/10.1016/j.molstruc.2017.08.081
  8. K. Das, A. Datta, S. Roy, J.K. Clegg, E. Garribba, C. Sinha and H. Kara, Polyhedron, 78, 62 (2014); https://doi.org/10.1016/j.poly.2014.04.032
  9. A. Donmez, G. Oylumluoglu, M.B. Coban, C. Kocak, M. Aygun and H. Kara, J. Mol. Struct., 1149, 569 (2017); https://doi.org/10.1016/j.molstruc.2017.08.027
  10. E. Gungor, M.B. Coban, H. Kara and Y. Acar, J. Clust. Sci., 29, 967 (2018); https://doi.org/10.1007/s10876-018-1406-2
  11. D.A. Kara, A. Donmez, H. Kara, M.B. Coban, Acta Crystallogr. C, 74, 901 (2018); https://doi.org/10.1107/S2053229618009166
  12. X. Ren, B.D. Alleyne, P.I. Djurovich, C. Adachi, I. Tsyba, R. Bau and M.E. Thompson, Inorg. Chem., 43, 1697 (2004); https://doi.org/10.1021/ic035183f
  13. L. He, X. Wang and L. Duan, ACS Appl. Mater. Interface, 10, 11801 (2018); https://doi.org/10.1021/acsami.8b00466
  14. A. Abedi, E. Saemian and V. Amani, J. Struct. Chem., 56, 1545 (2015); https://doi.org/10.1134/S0022476615080132
  15. C. Bizzarri, E. Spuling, D.M. Knoll, D. Volz and S. Bräse, Coord. Chem. Rev., 373, 49 (2018); https://doi.org/10.1016/j.ccr.2017.09.011
  16. H. Rudmann, S. Shimada and M.F. Rubner, J. Am. Chem. Soc., 124, 4918 (2002); https://doi.org/10.1021/ja012721j
  17. Bruker APEX2, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA (2004).
  18. G.M. Sheldrick, Acta Crystallogr. A, 71, 3 (2015); https://doi.org/10.1107/S2053273314026370
  19. L.J. Farrugia, J. Appl. Cryst., 45, 849 (2012); https://doi.org/10.1107/S0021889812029111
  20. A.L. Spek, Acta Crystallogr. D, 65, 148 (2009); https://doi.org/10.1107/S090744490804362X
  21. C.F. Macrae, I.J. Bruno, J.A. Chisholm, P.R. Edgington, P. McCabe, E. Pidcock, L. Rodriguez-Monge, R. Taylor, J. van de Streek and P.A. Wood, J. Appl. Cryst., 41, 466 (2008); https://doi.org/10.1107/S0021889807067908
  22. S. Arounaguiri, D. Easwaramoorthy, A. Ashokkumar, A. Dattagupta and B.G. Maiya, Proc. Indian Acad. Sci. (Chem. Sci.), 112, 1 (2000); https://doi.org/10.1007/BF02704295
  23. D.C.-Sulikowska, A. Malinowska and J.R.-Doczekalska, Polish J. Chem., 74, 607 (2000).
  24. S.K. Mishra and S.B. Kanungo, J. Therm. Anal.Calorim., 38, 2417 (1992); https://doi.org/10.1007/BF01974621
  25. A.E. Morales, E.S. Mora and U. Pal, Rev. Mex. Fisica, 53, 18 (2007).
  26. L. He, J. Qiao, L. Duan, G.F. Dong, D.Q. Zhang, L.D. Wang and Y. Qiu, Adv. Funct. Mater., 19, 2950 (2009); https://doi.org/10.1002/adfm.200900723
  27. R.D. Costa, F.J. Cespedes-Guirao, E. Ortí, H.J. Bolink, J. Gierschner, F. Fernández-Lazaro and A. Sastre-Santos, Chem. Commun., 26, 3886 (2009); https://doi.org/10.1039/b905367k
  28. Publication CIE no. 17.4, International Lighting Vocabulary, Central Bureau of the Commission Internationale de L 'Eclairage, Vienna, Austria (1987).
  29. Publication CIE no. 15.2, Colorimetry, Central Bureau of the Commission Internationale de L 'Eclairage, Edn. 2, Vienna, Austria (1986).
  30. R. Lakshmanan, N.C. Shivaprakash and S. S. Nair, J. Lumin., 168, 145 (2015); https://doi.org/10.1016/j.jlumin.2015.08.005
  31. V. Kumar, M. Gohain, J.H. Van Tonder, B.C.B. Bezuindenhoudt, S. Ponra, O.M. Ntwaeaborwa and H.C. Swart, Opt. Mater., 50B, 275 (2015); https://doi.org/10.1016/j.optmat.2015.11.009
Read More
Author biographies is not available.
Download
AJC-36-3-5
Statistic
Read Counter : 0 Download : 0