Issue

Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024

Copyright (c) 2024 Kanti Ranjan Nath Bhowmik Kanti

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Physico-Chemical Studies of Mixed-Ligand Fluoro Complexes of Some Transition Metals: A Review

https://doi.org/10.14233/ajchem.2024.31378
K.R. Nath Bhowmik
Department of Chemistry, Ramthakur College, Agartala-799002, India
https://orcid.org/0009-0005-0576-5920

Corresponding Author(s) : K.R. Nath Bhowmik

kantinathbhowmik@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024

Abstract

The chemistry of mixed ligand fluoro complexes of transition metals is an intriguing subject that has not yet been thoroughly investigated. Over the past three to four decades, there have been numerous reports of such complexes along with their synthesis, characterization, physico-chemical properties and in some cases crystallographic studies. This review summarizes the progress of some first row transition metal complexes consisting of fluoro as primary ligand and carboxylic, hydroxyl carboxylic, amino acids and nitrogen donor molecules such as pyridine, ethylene diamine, imidazole, 2,2'-bypyridine or 1,10-phenantholine etc. as co-ligands with their synthesis, probable structures and physico-chemical properties.

Keywords

Mixed ligand fluoro complexes Physico-chemical properties Transition metals
Bhowmik, K. N. (2024). Synthesis and Physico-Chemical Studies of Mixed-Ligand Fluoro Complexes of Some Transition Metals: A Review. Asian Journal of Chemistry, 36(6), 1207–1216. https://doi.org/10.14233/ajchem.2024.31378
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. P. Hagenmuller, Inorganic Solid Fluorides. Chemistry and Physics, Academic Press: New York (1985).
  2. R. Hoppe, Angew. Chem. lnt. Ed., 20, 63 (1981); https://doi.org/10.1002/anie.198100631
  3. N.M. Doherty and N.W. Hoffmann, Chem. Rev., 91, 553 (1991); https://doi.org/10.1021/cr00004a005
  4. J.H. Holloway and E.G. Hope, J. Fluor. Chem., 76, 209 (1996); https://doi.org/10.1016/0022-1139(95)03337-8
  5. M.N. Bhattacharjee, M.K. Chaudhuri, H.S. Dasgupta and D.T. Khathing, J. Chem. Soc., Dalton Trans., 2587 (1981); https://doi.org/10.1039/DT9810002587
  6. W. Massa, Inorg. Nucl. Chem. Lett., 13, 253 (1977); https://doi.org/10.1016/0020-1650(77)80103-7
  7. M.N. Bhattacharjee and M.K. Chaudhuri, Polyhedron, 3, 599 (1984); https://doi.org/10.1016/S0277-5387(00)88094-8
  8. M.N. Bhattacharjee and M.K. Chaudhuri, Inorg. Synth., 24, 50 (1986); https://doi.org/10.1002/9780470132555.ch15
  9. M.N. Bhattacharjee and M.K. Chaudhuri, Indian J. Chem., 23A, 424 (1984).
  10. M.N. Bhattacharjee, M.K. Chaudhuri, H.S. Dasgupta and A. Kathipri, Polyhedron, 4, 621 (1985); https://doi.org/10.1016/S0277-5387(00)86672-3
  11. M.N. Bhattacharjee, M.K. Chaudhuri and R.N. Dutta Purkayastha, Inorg. Chem., 24, 447 (1985); https://doi.org/10.1021/ic00197a041
  12. H.A. Goodwin and R.N. Sylva, Aust. J. Chem., 20, 629 (1967); https://doi.org/10.1071/CH9670629
  13. P. Bukovec and V. Kaucic, J. Chem. Soc., Dalton Trans., 1512 (1979); https://doi.org/10.1039/DT9790001512
  14. J.L. Kiplinger, T.G. Richmond and C.E. Osterberg, Chem. Rev., 94, 373 (1994); https://doi.org/10.1021/cr00026a005
  15. M. Hudlicky, J. Fluor. Chem., 44, 345 (1989); https://doi.org/10.1016/S0022-1139(00)82802-X
  16. D.F. Shriver and M.A. Drezdzon, The Manipulation of Air sensitive Compounds, Krieger: Malaber, FL, USA (1982).
  17. J.E. Huheey, Inorganic Chemistry, Harper and Row: New York, edn. 3, p. 268 (1983).
  18. A. Martinsen, J. Songstad, R. Larsson, M. Pouchard, P. Hagenmuller and A.F. Andresen, Acta Chem. Scand., 31, 645 (1977); https://doi.org/10.3891/acta.chem.scand.31a-0645
  19. R.K. Sharma and J.L. Fry, J. Org. Chem., 48, 2112 (1983); https://doi.org/10.1021/jo00160a041
  20. E. Horn, M.R. Snow and P.C. Zeleny, Aust. J. Chem., 33, 1659 (1980); https://doi.org/10.1071/CH9801659
  21. J.P. Collman, L.S. Kegdus, J.R. Norton and R.C. Finke, Principles and Applications of Organotransition Metal Chemistry, University Science Books, Mill Valley, CA, p 68 (1987).
  22. R.M. Catala, D. Cruz-Garritz, A. Hills, D.L. Hughes, R.L. Richards, P. Sosa and H. Torrens, J. Chem. Soc. Chem. Commun., 261 (1987); https://doi.org/10.1039/C39870000261
  23. D. Stalke and K.H. Whitmire, J. Chem. Soc. Chem. Commun., 833 (1990); https://doi.org/10.1039/C39900000833
  24. X. Yang, C.L. Stern and T. Marks, Organometallics, 10, 840 (1991); https://doi.org/10.1021/om00050a008
  25. J. Ruwwe, G. Erker and R. Fro¨hlich, Angew. Chem. Int. Ed. Engl., 35, 80 (1996); https://doi.org/10.1002/anie.199600801
  26. A.R. Siedle, R.A. Newmark, W.M. Lamanna and J.C. Huffman, Organometallics, 12, 1491 (1993); https://doi.org/10.1021/om00029a002
  27. H.W. Roesky, M. Sotoodeh and M. Noltemeyer, Angew. Chem. Int. Ed. Engl., 31, 864 (1992); https://doi.org/10.1002/anie.199208641
  28. K. Sauer, Acc. Chem. Res., 13, 249 (1980); https://doi.org/10.1021/ar50152a001
  29. J.C. De Paula and G.W. Brudvig, J. Am. Chem. Soc., 107, 2643 (1985); https://doi.org/10.1021/ja00295a016
  30. J.E. Larson and V.L. Pecoraro Manganese Redox Enzymes, VCH Publishers, New York, p. 1 (1992).
  31. H. Wariishi, K. Valli and M.H. Gold, Biochemistry, 28, 6017 (1989); https://doi.org/10.1021/bi00440a044
  32. P. Nordlund, B.M. Sjoberg and H. Eklund, Nature, 345, 593 (1990); https://doi.org/10.1038/345593a0
  33. Y. Sugiura, H. Kawabe, H. Tanaka, S. Fujimoto and A. Ohara, J. Biol. Chem., 256, 10664 (1981); https://doi.org/10.1016/S0021-9258(19)68676-X
  34. Y. Sugiura, H. Kawabe, H. Tanaka, S. Fujimoto and A. Ohara, J. Am. Chem. Soc., 103, 963 (1981); https://doi.org/10.1021/ja00394a052
  35. G.C. Dismukes, Photochem. Photobiol., 43, 99 (1986); https://doi.org/10.1111/j.1751-1097.1986.tb05598.x
  36. V.L. Pfxoraro, Photochem. Photobiol., 48, 249 (1988); https://doi.org/10.1111/j.1751-1097.1988.tb02818.x
  37. G. Christou, Acc. Chem. Res., 22, 328 (1989); https://doi.org/10.1021/ar00165a006
  38. F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry-A Comprehensive Text, Wiley-Interscience: New York, edn. 4, p. 741 (1980).
  39. Z. Lü, M. Yuan, F. Pan, S. Gao, D. Zhang and D. Zhu, Inorg. Chem., 45, 3538 (2006); https://doi.org/10.1021/ic051648l
  40. Y. Li, W. Wernsdorfer, R. Clérac, I.J. Hewitt, C.E. Anson and A.K. Powell, Inorg. Chem., 45, 2376 (2006); https://doi.org/10.1021/ic051819m
  41. R.S. Nyholm and A.G. Sharpe, J. Chem. Soc., 3579 (1952); https://doi.org/10.1039/jr9520003579
  42. R.D. Peacock, in eds.: F.A. Cotton, Some Fluorine Compounds of the Transition Metals, In: Progress in Inorganic Chemistry, Wiley, vol. 2, pp. 41 (1960).
  43. A.J. Edwards, J. Chem. Soc. A, 0, 3074 (1971); https://doi.org/10.1039/J19710003074
  44. S. Emori, M. Inoue, M. Kishita and M. Kubo, Inorg. Chem., 8, 1385 (1969); https://doi.org/10.1021/ic50077a002
  45. H. Aghabozorg, G.J. Palenik, R.C. Stoufer and J. Summers, Inorg. Chem., 21, 3903 (1982); https://doi.org/10.1021/ic00141a009
  46. C.J. Milios, A. Presimone, A. Mishra, M. Parsons, W. Wernsdofer, G. Christou, S.P. Perlepes and E.K. Brechin, Chem. Commun., 53, 153 (2007); https://doi.org/10.1039/B611174B
  47. H. Diebler, Z. Phys. Chem. , 68, 64 (1969); https://doi.org/10.1524/zpch.1969.68.1_2.064
  48. D.P. Poe, Inorg. Chem., 27, 1280 (1988); https://doi.org/10.1021/ic00280a038
  49. M.N. Bhattacharjee, M.K. Chaudhuri and R.N.D. Purkayastha, Inorg. Chem., 28, 3747 (1989); https://doi.org/10.1021/ic00318a026
  50. R.N.D. Purkayastha, Indian J. Chem., 37A, 158 (1998).
  51. A.K. De, K.R.N. Bhowmik, P. Paul, S. Roy and R.N.D. Purkayastha, J. Indian Chem. Soc., 88, 1423 (2011).
  52. K.R.N. Bhowmik, A.K. Dey and R.N.D. Purkayastha, J. Indian Chem. Soc., 89, 177 (2012).
  53. K.R.N. Bhowmik, P. Paul, D. Dey, M. Bhattacharjee, N. Das, B. Saha, S.R. Boruah and R.N.D. Purkayastha, J. Indian Chem. Soc., 97, 829 (2020).
  54. J. Darriet, W. Massa, J. Pebler and R. Stief, Solid State Sci., 4, 1499 (2002); https://doi.org/10.1016/S1293-2558(02)00046-8
  55. A.R. Biju and M.V. Rajasekharan, J. Mol. Struct., 875, 456 (2008); https://doi.org/10.1016/j.molstruc.2007.05.028
  56. G. Rother, R. Stief, U. Bentrup and W. Massa, J. Fluor. Chem., 132, 740 (2011); https://doi.org/10.1016/j.jfluchem.2011.05.023
  57. P. Nunez, C. Elias, J. Fuentes, X. Solans, A. Tressaud, M.C.M. de Lucas and F. Rodriguez, J. Chem. Soc., Dalton Trans., 4335 (1997); https://doi.org/10.1039/a704368f
  58. C. Elias, J. Fuentes, P. Nunez, V.D. Rodríguez, U. Jacobs and W. Massa, Z. Anorg. Allg. Chem., 624, 2001 (1998); https://doi.org/10.1002/(SICI)1521-3749(1998120)624:12<2001:: AID-ZAAC2001>3.0.CO;2-4
  59. G. Rother, H. Worzala and U. Bentrup, J. Inorg. Gen. Chem., 624, 1706 (1998); https://doi.org/10.1002/(SICI)1521-3749(199810)624:10<1706::AID-ZAAC1706>3.0.CO;2-C
  60. R.W.M. ten Hoedt, J. Reedijk and G.C. Verschoor, Recl. Trav. Chim. Pays Bas, 100, 400 (1981); https://doi.org/10.1002/recl.19811001103
  61. J. Emsley, N.M. Reza, H.M. Dawes and M.B. Hursthouse, J. Chem. Soc., Dalton Trans., 313 (1986); https://doi.org/10.1039/dt9860000313
  62. N.W. Alcock, M.M. Roberts and M.C. Chakravorti, Acta Crystallogr., B36, 687 (1980); https://doi.org/10.1107/S0567740880004141
  63. M.N. Bhattacharjee, M.K. Chaudhuri, M. Devi and K. Yhome, J. Chem. Soc., Dalton Trans., 1055 (1987); https://doi.org/10.1039/DT9870001055
  64. M.A. Soldatkina, L.B. Serezhkina and V.N. Serezhkin, Russ. J. Inorg. Chem., 30, 1640 (1985).
  65. S.L. Edwards, T.L. Poulos and J. Kraut, J. Biol. Chem., 259, 12984 (1984); https://doi.org/10.1016/S0021-9258(18)90644-7
  66. C.R. Bhattacharjee and P.K. Choudhury, Transition Met. Chem., 23, 561 (1998); https://doi.org/10.1023/A:1006927100348
  67. C.R. Bhattacharjee and P.K. Choudhury, Transition Met. Chem., 26, 730 (2001); https://doi.org/10.1023/A:1012210617378
  68. M.N. Bhattacharjee, M.K. Chaudhuri and M. Devi, Polyhedron, 8, 457 (1989); https://doi.org/10.1016/S0277-5387(00)80741-X
  69. R. Goswami, A. Dutta, P. Mondal and C.R. Bhattacharjee, J. Chem. Chem. Sci., 6, 220 (2016).
  70. F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley Eastern, New Delhi. edn 3, p. 723 (1976).
  71. L. Sacconi and A. Sabatini, J. Inorg. Nucl. Chem., 25, 1389 (1963); https://doi.org/10.1016/0022-1902(63)80408-X
  72. W.R. McWhinnie and J.D. Miller, Adv. Inorg. Chem., 12, 135 (1970); https://doi.org/10.1016/S0065-2792(08)60049-7
  73. M.J. Bagley, D. Nicholls and B.A. Warburton, J. Chem. Soc. A, 2694 (1970); https://doi.org/10.1039/j19700002694
  74. M.N. Bhattacharjee, M.K. Chaudhuri and M. Devi, Polyhedron, 11, 1523 (1992); https://doi.org/10.1016/S0277-5387(00)83147-2
Read More
Author biographies is not available.
Statistic
Read Counter : 0 Download : 0