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Vol. 31 No. 7 (2019): Vol 31 Issue 7

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Synthesis, Characterization and Analytical Applications of Novel Potentiometric Sensor Based on Chromium(III)Boratotungstophosphate

https://doi.org/10.14233/ajchem.2019.21919
Pernita Dogra
Department of Chemistry, M.M. University, Mullana, Ambala-133207, India
Harish K. Sharma
Department of Chemistry, M.M. University, Sadhopur, Ambala-134007, India
Anju Parmar
Department of Chemistry, M.M. University, Mullana, Ambala-133207, India

Corresponding Author(s) : Pernita Dogra

pernita.dogra@mmumullana.org

Asian Journal of Chemistry, Vol. 31 No. 7 (2019): Vol 31 Issue 7

Abstract

Ion selective electrode based on chromium(III) boratotungstophosphate was successfully fabricated for the detection of Hg(II) ions. The characterization of electroactive material has been done with FTIR, SEM, EDS and X-Ray diffraction studies. Polymeric membranes containing different composition of electroactive material and epoxy resin as binder were prepared. The best performance was shown by the electrode with composition having 40 % electroactive material and 60 % epoxy resin. A reasonably short response time of 6 s was shown together with a life of six months without any divergence in potential. The sensor possessed a near Nernstian slope of 25 ± 0.8 mV decade-1 over a wide linear range of 1.0 × 10-1 M − 1.0 × 10-6 M Hg(II) ions. The electrode worked satisfactorily in the partially non-aqueous medium also. The working pH range of the sensor was found to be 2.43-8.0. Analytical applicability of membrane sensor was evaluated by using it as an indicator electrode for analysis of Hg(II) ions in different water samples procured from sea and canal waters. The proposed electrode displayed good selectivity for Hg(II) in the presence of some transition metal(II) ions and lanthanide(III) ions.

Keywords

Chromium(III) boratotungstophosphate Mercury(II) Selectivity coefficient Potentiometric sensor
Dogra, P., Sharma, H. K., & Parmar, A. (2019). Synthesis, Characterization and Analytical Applications of Novel Potentiometric Sensor Based on Chromium(III)Boratotungstophosphate. Asian Journal of Chemistry, 31(7), 1481–1488. https://doi.org/10.14233/ajchem.2019.21919
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References
  1. R.A. Bernhoft, J. Environ. Public Health, 2012, Article ID 460508 (2012); https://doi.org/10.1155/2012/460508.
  2. S. Bose-O’Reilly, K.M. McCarty, N. Steckling and B. Lettmeier, Curr. Probl. Pediatr. Adolesc. Health Care, 40, 186 (2010); https://doi.org/10.1016/j.cppeds.2010.07.002.
  3. M.W. Hinds, Spectrochim. Acta B Spectrosc., 53, 1063 (1998); https://doi.org/10.1016/S0584-8547(98)00171-2.
  4. P. Bermejo-Barrera, E.M. Verdura-Constenla, A. Moreda-Piñeiro and A. Bermejo-Barrera, Anal. Chim. Acta, 398, 263 (1999); https://doi.org/10.1016/S0003-2670(99)00453-5.
  5. L. Bennun and J. Gomez, Spectrochim. Acta B Spectrosc., 52, 1195 (1997); https://doi.org/10.1016/S0584-8547(97)00003-7.
  6. B. Rezaei, S. Meghdadi and S. Bagherpour, Sensors, 8, 1469 (2008); https://doi.org/10.1109/JSEN.2008.920719.
  7. A.A. Ismaiel, M.M. Aroua and R. Yusoff, Am. J. Anal. Chem., 3, 859 (2012); https://doi.org/10.4236/ajac.2012.312113.
  8. M. Javanbakht, F. Divsar, A. Badiei, M.R. Ganjali, P. Norouzi, G.M. Ziarani, M. Chaloosi and A. Abdi Jahangir, Anal. Sci., 25, 789 (2009); https://doi.org/10.2116/analsci.25.789.
  9. R.W. Cattrall and C.-P. Pui, Anal. Chem., 48, 552 (1976); https://doi.org/10.1021/ac60367a033.
  10. K.R. Mahajan, R.K. Puri, A. Marwaha, I. Kaur and M.P. Mahajan, J. Hazard. Mater., 167, 237 (2009); https://doi.org/10.1016/j.jhazmat.2008.12.107.
  11. P. Dogra, H.K. Sharma and N. Sharma, Res. J. Chem. Environ., 15, 897 (2011).
  12. P. Dogra, H.K. Sharma and A. Parmar, Res. J. Chem. Environ., 21, 21 (2017).
  13. H.K. Sharma and N. Sharma, E-J. Chem., 6, 1139 (2009); https://doi.org/10.1155/2009/301016.
  14. F. Ahmadi and N. Asaadi, Iran. J. Pharm. Res., 12, 645 (2013).
  15. K.S. Harish, V. Neha and J.K. Kapoor, E-J. Chem., 8, 155 (2011); https://doi.org/10.1155/2011/358039.
  16. S.K. Mittal, R. Kumar, P. Dogra and H.K. Sharma, Res. J. Chem. Environ., 11, 47 (2007).
  17. J.R.S. Brownson, M.I. Tejedor-Tejedor and M.A. Anderson, Chem. Mater., 17, 6304 (2005); https://doi.org/10.1021/cm051568f.
  18. S.A. Nabi, S. Usmani and N. Rehman, Ann. Chim. Fr., 21, 521 (1996).
  19. G.P. Singh, P. Kaur, S. Kaur, D. Arora, P. Singh and P.D. Singh, Mater. Phys. Mech., 14, 31 (2012).
  20. A.I. Tropecelo, M.H. Casimiro, I.M. Fonseca, A.M. Ramos, J. Vital and J.E. Castanheiro, Appl. Catal. A Gen., 390, 183 (2010); https://doi.org/10.1016/j.apcata.2010.10.007.
  21. S. Borghese, A. Blanc, P. Pale and B. Louis, Dalton Trans., 40, 1220 (2011); https://doi.org/10.1039/c0dt01329c.
  22. C. Rocchiccioli-Deltcheff, M. Fournier, R. Franck and R. Thouvenot, Inorg. Chem., 22, 207 (1983); https://doi.org/10.1021/ic00144a006.
  23. Rakesh, S. Ananda and N.M.M. Gowda, Modern Res. Catal., 2, 127 (2013); https://doi.org/10.4236/mrc.2013.24018.
  24. R. Kumar, H.K. Sharma and P. Dogra, Int. J. Environ. Anal. Chem., 91, 280 (2011); https://doi.org/10.1080/03067310903278528.
  25. G. Alberti, P. Cardini-Galli, U. Costantino and E. Torracca, J. Inorg. Nucl. Chem., 29, 571 (1967); https://doi.org/10.1016/0022-1902(67)80063-0.
  26. P. Dogra and J. Sharma, Res. J. Chem. Environ., 12, 35 (2017).
  27. H.K. Sharma, P. Dogra and R. Kumar, Int. J. Pure Appl. Chem., 4, 287 (2009).
  28. H.K. Sharma, P. Dogra, A.K. Gupta and F. Koohyar, Quim. Nova, 37, 1324 (2014); http://dx.doi.org/10.5935/0100-4042.20140198.
  29. H.K. Sharma and P. Dogra, Am. Chem. Sci. J., 4, 457 (2014); https://doi.org/10.9734/ACSJ/2014/5527.
  30. M. Tutulea-Anastasiu, D. Wilson, M. del Valle, C. Schreiner and I. Cretescu, Sensors, 13, 4367 (2013); https://doi.org/10.3390/s130404367.
  31. E. Mahmoud, A. Abdollahain and S. Sahabnasagh, Eur. J. Anal. Chem., 12, 107 (2017).
  32. Y. Umezawa, K. Umezawa and H. Sato, Pure Appl. Chem., 67, 507 (1995); https://doi.org/10.1351/pac199567030507.
  33. Y. Umezawa, P. Bühlmann, K. Umezawa, K. Tohda and S. Amemiya, Pure Appl. Chem., 72, 1851 (2000); https://doi.org/10.1351/pac200072101851.
  34. S.K. Mittal, R. Kumar, P. Dogra and H.K. Sharma, J. Anal. Chem., 65, 1045 (2010); https://doi.org/10.1134/S1061934810100102.
  35. C. Mohan, K. Sharma and S. Chandra, Anal. Bioanal. Electrochem., 9, 35 (2017).
  36. P. Dogra, R. Kumar and H.K. Sharma, Proceedings of International Congress of Chemistry and Environment, Kuwait, p. 500 (2007).
  37. S.K. Mittal and H.K. Sharma, J. Anal. Chem., 60, 1069 (2005); https://doi.org/10.1007/s10809-005-0240-5.
  38. A.M. Radalla, Beni-Suef Univ. J. Basic Appl. Sci., 4, 174 (2015); https://doi.org/10.1016/j.bjbas.2015.05.012.
  39. M.I. Yousry, H. Ibrahim and O.R. Shehab, J. Electroanal. Chem., 666, 11 (2011); https://doi.org/10.1016/j.jelechem.2011.11.024.
  40. X. Yu, Z. Zhou, Y. Wang, Y. Liu, Q. Xie and D. Xiao, Sens. Actuators B: Chemical, 123, 352 (2007); https://doi.org/10.1016/j.snb.2006.08.041.
  41. A.K. Hassan, Mod. Chem. Appl., 1, 111 (2013); https://doi.org/10.4172/2329-6798.1000111.
  42. M. Javanbakht, F. Divsar, A. Badiei, M.R. Ganjali, P. Norouzi, G.M. Ziarani, M. Chaloosi and A.A. Jahangir, J. Anal. Sci., 25, 789 (2009); https://doi.org/10.2116/analsci.25.789.
  43. A.A. Ismaiel, M.M. Aroua and R. Yusoff, Sensors, 14, 13102 (2014); https://doi.org/10.3390/s140713102.
  44. M.N. Abbas and G.A.E. Mostafa, Anal. Chim. Acta, 478, 329 (2003); https://doi.org/10.1016/S0003-2670(02)01520-9.
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