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Vol. 30 No. 9 (2018): Vol 30 Issue 9

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On the Homographic Dependence of Activation Energy and Viscosity Arrhenius' Temperature for Some Pure Fluids

https://doi.org/10.14233/ajchem.2018.21319
N.O. Alzamel
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
F. Alakhras
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
A.A. Al-Arfaj
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
M.A. Al-Khaldi
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
N.A. Al-Omair
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
E. Al-Abbad
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
A.A. Wassel
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia
N. Ouerfelli
Imam Abdurrahman Bin Faisal University, Department of Chemistry, College of Science, P.O. Box 1982, Dammam 31441, Saudi Arabia; Université de Tunis El Manar, Laboratoire de Biophysique et Technologies Médicales, LR13ES07, Institut Supérieur des Technologies Médicales de Tunis, 9 Avenue Dr. Zouhaier Essafi 1006 Tunis, Tunisia

Corresponding Author(s) : N.O. Alzamel

nalzamil@iau.edu.sa

Asian Journal of Chemistry, Vol. 30 No. 9 (2018): Vol 30 Issue 9

Abstract

Viscosity is the most important hydraulic fluid characteristic and it is one of the significant quantities which are affected by pressure and temperature. Using of statistical methods for regression and correlation analysis, any eventual causal association between the melting and boiling points and the Arrhenius-type equation parameters of some classical Newtonian fluids is attempted. Empirical validations using 101 data set of viscosity of pure Newtonian fluids studied at atmospheric pressure and at different temperature domains give reliable statistical result. In fact, we found a significant strong causal correlation between the Arrhenius activation energy (Ea), the boiling point (Tb) and the Arrhenius temperature (TA). As a result, an original empirical model modeling this relationship is suggested. The proposed model allows the prediction of the normal boiling temperature through information on viscosity Arrhenius parameters. Moreover, the proposed model is very beneficial for fluid engineering data especially for the study of systems efficiency and hydraulic components. Because of that, the need for more accurately and specific mathematical modeling of the fluid behaviour is required.

Keywords

Viscosity Arrhenius temperature Boiling point Pure fluid
Alzamel, N., Alakhras, F., Al-Arfaj, A., Al-Khaldi, M., Al-Omair, N., Al-Abbad, E., … Ouerfelli, N. (2018). On the Homographic Dependence of Activation Energy and Viscosity Arrhenius’ Temperature for Some Pure Fluids. Asian Journal of Chemistry, 30(9), 1937–1943. https://doi.org/10.14233/ajchem.2018.21319
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