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Vol. 30 No. 8 (2018): Vol 30 Issue 8

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Functionalization of Silica Coated on Iron Sand Magnetic Material with Diethylenetriamine

https://doi.org/10.14233/ajchem.2018.21314
Fahmiati
Department of Chemistry, Universitas Halu Oleo Jl. HEA Mokodompit, Kendari 93232, Indonesia; Department of Chemistry, Universitas Gadjah Mada, Jl. Kaliurang Sekip Utara, Bulaksumur 21, Yogyakarta 55283, Indonesia
Nuryono
Department of Chemistry, Universitas Gadjah Mada, Jl. Kaliurang Sekip Utara, Bulaksumur 21, Yogyakarta 55283, Indonesia
Suyanta
Department of Chemistry, Universitas Gadjah Mada, Jl. Kaliurang Sekip Utara, Bulaksumur 21, Yogyakarta 55283, Indonesia

Corresponding Author(s) : Fahmiati

fahmiati05@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 8 (2018): Vol 30 Issue 8

Abstract

Diethylenetriamine (DETA) functionalized silica coated on magnetic material of iron sand (MM@SiO2–DETA) has been synthesized by sol–gel method. Synthesis was carried out by coating magnetic material of iron sand as the core with diethylenetriamine–modified silica using sodium silicate solution and N1–(3–trimethoxysylilpropyl)diethylenetriamine (TMPSDETA) as silica and diethylenetriamine group sources, respectively. Several variations of mole ratio of silica to DETA at a constant weight of magnetic material were examined to evaluate the effect of the coating agent amount on the properties of MM@SiO2–DETA. MM@SiO2–DETA was characterized with Fourier transform infrared spectrophotometer, X-ray diffraction, scanning electron microscope with energy dispersive spectroscope (SEM–EDX), vibrating sample magnetometer and thermal gravimetric analysis. Stability test of product toward acidic solution and the effect of mole ratio of SiO2 and DETA on adsorption of Au(III) also evaluated. The characterization results indicated that SiO2 and DETA groups were
successfully attached to the surface of magnetic material to form MM@SiO2–DETA. Characteristic bands of the vibration of propyl and amino groups derived from DETA; indicating that DETA was successfully reacted with MM@SiO2. Coating of magnetic material with SiO2 exhibits the decrease in Ms up to 38.2 emu/g and 23.5 emu/g after coating with SiO2–DETA. Thermalgravimetric analysis
indicate thermal stability of the resulted product of MM@SiO2–DETA (1:1) up to 350 °C. Dissolution by acid solution can be diminished by coating magnetic material with silica. Gold(III) adsorption capacity of MM@SiO2–DETA (1:0.5), MM@SiO2–DETA (1:1) and MM@SiO2–DETA (1:2) are found to be higher than 92 %.

Keywords

Diethylenetriamine Silica Iron sand
(1)
Fahmiati; Nuryono; Suyanta. Functionalization of Silica Coated on Iron Sand Magnetic Material With Diethylenetriamine. ajc 2018, 30, 1805-1810.
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