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Vol. 30 No. 8 (2018): Vol 30 Issue 8

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Thermodynamic Properties of Binary Mixtures of Methyl Benzoate with Chlorobenzene and Benzaldehyde at 308.15 and 318.15 K

https://doi.org/10.14233/ajchem.2018.21292
P. Prabhu*
Department of Chemistry, St. Joseph's College, Tiruchirappalli-621 002, India *Corresponding author: E-mail: ruban_prabhu@yahoo.com; prabhuruban51@gmail.com
A. Rose Venis
Department of Chemistry, St. Joseph's College, Tiruchirappalli-621 002, India *Corresponding author: E-mail: ruban_prabhu@yahoo.com; prabhuruban51@gmail.com

Asian Journal of Chemistry, Vol. 30 No. 8 (2018): Vol 30 Issue 8

Abstract

Densities, viscosities and ultrasonic velocities of binary liquid mixtures of methyl benzoate with chlorobenzene and benzaldehyde have been measured at 308.15 and 318.15 K. By these experimental data excess volume (VE), deviation in isentropic compressibility (ΔKS), deviation in viscosity (Δη) intermolecular free length (ΔLf), intermolecular free volume (ΔVf) and deviation in acoustic impedance (ΔZ) were calculated. These results have been correlated with the Redlich and Kister type polynomial equation to derive the coefficients and standard errors. Significance of the calculated excess quantities were analyzed for mixtures of methyl benzoate with chlorobenzene and benzaldehyde, through which intermolecular interactions have been investigated.

Keywords

Density Viscosity Ultrasonic velocity Excess properties Binary mixture Molecular interaction.
Prabhu*, P., & Rose Venis, A. (2018). Thermodynamic Properties of Binary Mixtures of Methyl Benzoate with Chlorobenzene and Benzaldehyde at 308.15 and 318.15 K. Asian Journal of Chemistry, 30(8), 1759–1764. https://doi.org/10.14233/ajchem.2018.21292
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