Copyright (c) 2018 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Template Engineered Tetraazamacrocyclic Complexes and their Antibacterial Studies
Corresponding Author(s) : Monika Kamboj
Asian Journal of Chemistry,
Vol. 30 No. 7 (2018): Vol 30 Issue 7
Abstract
Template condensation reaction of ethylenediamine and acetonylacetone in the presence of metal ions(III) was implemented to synthesize 16 membered macrocyclic complexes as [M(C16H28N4)X]X2]. The characterization of synthesized complexes was done by means of various physio-chemical techniques. Template synthesis, characterization, molecular modeling and in vitro antibacterial activities have been discussed.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- B. Hariprasath, Deepthi, I.S. Babu, P. Venkatesh, S. Sharfudeen and V. Soumya, J. Chem. Pharm. Res., 2, 496 (2010).
- S. Chandra and M. Pundir, Spectrochim. Acta A, 69, 1 (2008); https://doi.org/10.1016/j.saa.2007.02.019.
- S. Chandra, R. Gupta, N. Gupta and S.S. Bawa, Transition Met. Chem., 31, 147 (2006); https://doi.org/10.1007/s11243-005-6194-5.
- K. Kumar and M.F. Tweedle, Pure Appl. Chem., 65, 515 (1993); https://doi.org/10.1351/pac199365030515. S.C. Jackels, B.R. Kroos, W.H. Hinson, N. Karstaedt and P.R. Moran, Radiology, 159, 525 (1986); https://doi.org/10.1148/radiology.159.2.3961187.
- A.D. Watson, S.M. Rockladge and C.B. Higgins, Magnetic Resonance Imaging of the Body, Raven Press, New York (1992).
- J.R. Morrow and É. Toth, Inorg. Chem., 56, 6029 (2017); https://doi.org/10.1021/acs.inorgchem.7b01277.
- D.P. Singh, R. Kumar, M. Kamboj and K. Jain, Acta Chim. Slov., 56, 780 (2009).
- A.I. Vogel, A Text Book of Quantitative Chemical Analysis, Longman, London (1989).
- I. Ahmad and A.Z. Beg, J. Ethnopharmacol., 74, 113 (2001); https://doi.org/10.1016/S0378-8741(00)00335-4.
- P. Rathi, K. Sharma and D.P. Singh, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 130, 72 (2014); https://doi.org/10.1016/j.saa.2014.03.046.
- R. Kumar and R. Singh, Turk. J. Chem., 30, 77 (2006).
- Q. Zeng, J. Sun, S. Gou, K. Zhou, J. Fang and H. Chen, Transition Met. Chem., 23, 371 (1998); https://doi.org/10.1023/A:1006994300484.
- A.K. Singh, R. Singh and P. Saxena, Transition Met. Chem., 29, 867 (2004); https://doi.org/10.1007/s11243-004-1732-0.
- L.K. Gupta and S. Chandra, Transition Met. Chem., 31, 368 (2006); https://doi.org/10.1007/s11243-005-0002-0.
- A.K. Mohamed, K.S. Islam, S.S. Hasan and M. Shakir, Transition Met. Chem., 24, 198 (1999); https://doi.org/10.1023/A:1006903000739.
- C. Lodeiro, R. Basitida, E. Bertolo, A. Macias and R. Rodriguez, Transition Met. Chem., 28, 388 (2003); https://doi.org/10.1023/A:1023672629805.
- F.M.A.M. Aqra, Transition Met. Chem., 24, 337 (1999); https://doi.org/10.1023/A:1006962812246.
- S. Chandra and R. Kumar, Transition Met. Chem., 29, 269 (2004); https://doi.org/10.1023/B:TMCH.0000020359.84853.72.
- V.B. Rana, D.P. Singh, P. Singh and M.P. Teotia, Transition Met. Chem., 7, 174 (1982); https://doi.org/10.1007/BF01035836.
- V.P. Krzyminiewska, H. Litkowska and W.R. Paryzek, Monatsh. Chem., 130, 243 (1999);https://doi.org/10.1007/PL00010204.
- D.P. Singh, V. Malik, K. Kumar, C. Sharma and K.R. Aneja, Spectrochim. Acta A, 76, 45 (2010); https://doi.org/10.1016/j.saa.2010.02.044.
- Z.A. Siddiqi, S. Kumar, M. Khalid and M. Shahid, Spectrochim. Acta A, 72, 970 (2009); https://doi.org/10.1016/j.saa.2008.12.019.
- D.P. Singh, R. Kumar and J. Singh, Eur. J. Med. Chem., 44, 1731 (2009); https://doi.org/10.1016/j.ejmech.2008.03.007.
- D.P. Singh, R. Kumar and J. Singh, J. Enzyme Inhib. Med. Chem., 24, 883 (2009); https://doi.org/10.1080/14756360802456397.
- J.S. Wood, Prog. Inorg. Chem., 16, 227 (1972).
- D.P. Singh, V. Malik, R. Kumar and J. Singh, J. Enzyme Inhib. Med. Chem., 24, 1201 (2009); https://doi.org/10.1080/14756360902779383.
- D.P. Singh, M. Kamboj, K. Kumar, K. Jain and C. Sharma, J. Coord. Chem., 64, 502 (2011); https://doi.org/10.1080/00958972.2010.545398.
References
B. Hariprasath, Deepthi, I.S. Babu, P. Venkatesh, S. Sharfudeen and V. Soumya, J. Chem. Pharm. Res., 2, 496 (2010).
S. Chandra and M. Pundir, Spectrochim. Acta A, 69, 1 (2008); https://doi.org/10.1016/j.saa.2007.02.019.
S. Chandra, R. Gupta, N. Gupta and S.S. Bawa, Transition Met. Chem., 31, 147 (2006); https://doi.org/10.1007/s11243-005-6194-5.
K. Kumar and M.F. Tweedle, Pure Appl. Chem., 65, 515 (1993); https://doi.org/10.1351/pac199365030515. S.C. Jackels, B.R. Kroos, W.H. Hinson, N. Karstaedt and P.R. Moran, Radiology, 159, 525 (1986); https://doi.org/10.1148/radiology.159.2.3961187.
A.D. Watson, S.M. Rockladge and C.B. Higgins, Magnetic Resonance Imaging of the Body, Raven Press, New York (1992).
J.R. Morrow and É. Toth, Inorg. Chem., 56, 6029 (2017); https://doi.org/10.1021/acs.inorgchem.7b01277.
D.P. Singh, R. Kumar, M. Kamboj and K. Jain, Acta Chim. Slov., 56, 780 (2009).
A.I. Vogel, A Text Book of Quantitative Chemical Analysis, Longman, London (1989).
I. Ahmad and A.Z. Beg, J. Ethnopharmacol., 74, 113 (2001); https://doi.org/10.1016/S0378-8741(00)00335-4.
P. Rathi, K. Sharma and D.P. Singh, Spectrochim. Acta A, Mol. Biomol. Spectrosc., 130, 72 (2014); https://doi.org/10.1016/j.saa.2014.03.046.
R. Kumar and R. Singh, Turk. J. Chem., 30, 77 (2006).
Q. Zeng, J. Sun, S. Gou, K. Zhou, J. Fang and H. Chen, Transition Met. Chem., 23, 371 (1998); https://doi.org/10.1023/A:1006994300484.
A.K. Singh, R. Singh and P. Saxena, Transition Met. Chem., 29, 867 (2004); https://doi.org/10.1007/s11243-004-1732-0.
L.K. Gupta and S. Chandra, Transition Met. Chem., 31, 368 (2006); https://doi.org/10.1007/s11243-005-0002-0.
A.K. Mohamed, K.S. Islam, S.S. Hasan and M. Shakir, Transition Met. Chem., 24, 198 (1999); https://doi.org/10.1023/A:1006903000739.
C. Lodeiro, R. Basitida, E. Bertolo, A. Macias and R. Rodriguez, Transition Met. Chem., 28, 388 (2003); https://doi.org/10.1023/A:1023672629805.
F.M.A.M. Aqra, Transition Met. Chem., 24, 337 (1999); https://doi.org/10.1023/A:1006962812246.
S. Chandra and R. Kumar, Transition Met. Chem., 29, 269 (2004); https://doi.org/10.1023/B:TMCH.0000020359.84853.72.
V.B. Rana, D.P. Singh, P. Singh and M.P. Teotia, Transition Met. Chem., 7, 174 (1982); https://doi.org/10.1007/BF01035836.
V.P. Krzyminiewska, H. Litkowska and W.R. Paryzek, Monatsh. Chem., 130, 243 (1999);https://doi.org/10.1007/PL00010204.
D.P. Singh, V. Malik, K. Kumar, C. Sharma and K.R. Aneja, Spectrochim. Acta A, 76, 45 (2010); https://doi.org/10.1016/j.saa.2010.02.044.
Z.A. Siddiqi, S. Kumar, M. Khalid and M. Shahid, Spectrochim. Acta A, 72, 970 (2009); https://doi.org/10.1016/j.saa.2008.12.019.
D.P. Singh, R. Kumar and J. Singh, Eur. J. Med. Chem., 44, 1731 (2009); https://doi.org/10.1016/j.ejmech.2008.03.007.
D.P. Singh, R. Kumar and J. Singh, J. Enzyme Inhib. Med. Chem., 24, 883 (2009); https://doi.org/10.1080/14756360802456397.
J.S. Wood, Prog. Inorg. Chem., 16, 227 (1972).
D.P. Singh, V. Malik, R. Kumar and J. Singh, J. Enzyme Inhib. Med. Chem., 24, 1201 (2009); https://doi.org/10.1080/14756360902779383.
D.P. Singh, M. Kamboj, K. Kumar, K. Jain and C. Sharma, J. Coord. Chem., 64, 502 (2011); https://doi.org/10.1080/00958972.2010.545398.