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Vol. 30 No. 7 (2018): Vol 30 Issue 7

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Synthesis, Characterization and Catalytic Activity of NiO-Mn2O3/ZrO2 Spinel Co-Catalysts

https://doi.org/10.14233/ajchem.2018.21425
Salih Hadi Kadhim
Department of Chemistry, College of Science, University of Babylon, Hilla 51002, Iraq

Corresponding Author(s) : Salih Hadi Kadhim

hadi197019@yahoo.com

Asian Journal of Chemistry, Vol. 30 No. 7 (2018): Vol 30 Issue 7

Abstract

The spinel co-catalyst NiO-Mn2O3/ZnO2 in two different ratios (0.5:0.5:2) and (1:2:1) of the components oxides were prepared using co-precipitation method of their metal hydroxides. This method was performed in basic medium (pH 9), using sodium carbonate as a precipitated agent. The precipitated samples dried at 120 ºC overnight and then calcinated at 650 ºC for three hours. The prepared spinel co-catalyst was investigated using powder X-ray diffraction, Fourier transfer infrared spectroscopy, energy-dispersive X-ray spectroscopy and atomic force microscopy. According to spectroscopic studies and magnetic properties, the obtained co-catalyst was a normal spinel type. The catalytic activity of prepared co-catalysts was conducted by following photocatalytic degradation of Bismarck Brown G dye. From the obtained results, the best ratio of spinel catalyst was (0.5:0.5:2) optimized, which achieved a higher activity for removal percentage (97 %) dye.

Keywords

Spinel catalyst NiO-Mn2O3/ZrO2 catalyst Spinel oxide
Kadhim, S. H. (2018). Synthesis, Characterization and Catalytic Activity of NiO-Mn2O3/ZrO2 Spinel Co-Catalysts. Asian Journal of Chemistry, 30(7), 1650–1654. https://doi.org/10.14233/ajchem.2018.21425
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