Synthesis, Spectral, Structural and Antimicrobial Studies of Silver Nanoparticles and Ag(I) Complex of 2-Mercaptobenzothiazole

Alya’a Jabar Ahmed; Abdulkareem Mohammed Ali Alsammarraie

doi:10.14233/ajchem.2018.21291

Issue

Vol. 30 No. 7 (2018): Vol 30 Issue 7

Issue Published : May 31, 2018

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Spectral, Structural and Antimicrobial Studies of Silver Nanoparticles and Ag(I) Complex of 2-Mercaptobenzothiazole

https://doi.org/10.14233/ajchem.2018.21291

Alya’a Jabar Ahmed

Directorate of Scholarships and Cultural Relations, Ministry of Higher Education and Scientific Research, Baghdad, Iraq

Abdulkareem Mohammed Ali Alsammarraie

Department of Chemistry, College of Science, University of Baghdad, Baghdad, Iraq

Corresponding Author(s) : Alya’a Jabar Ahmed

alyaa.jabbar@yahoo.com

Asian Journal of Chemistry, Vol. 30 No. 7 (2018): Vol 30 Issue 7
Article Published : May 31, 2018

Abstract

In the present study, Ag(I) complex is synthesized by reacting silver nitrate with ligand (2-mercaptobenzothiazole) in a 1:2 mole ratio. Furthermore, silver nanoparticles were prepared by the reduction of AgNO₃ using 2-mercaptobenzothiazole in dilute aqueous sodium citrate buffer solution. The Ag(I) complex are characterized by elemental analyses, flame atomic absorption, thermogravimetric analyses, molar conductance and magnetic susceptibility, UV-visible as well as FTIR spectroscopy. Analyses, linear geometry is suggested for the Ag(I) complex. The prepared nanoparticles are characterized using X-ray diffraction, scanning electron microscopy, energy dispersive microscopy, atomic force microscopy, vibrational and electronic spectroscopy. X-ray diffraction analysis revealed that silver nanoparticles with fcc crystal structure. The SEM micrographs indicated that the morphology is nearly rods shaped structure with an average diameter of about 100 nm. Biological activities of the ligand and its Ag(I) complex and silver nanoparticles are tested against Staphylococcus aureus, Escherichia coli bacteria and Candida albicans, Candida tropicalis fungi. It was found that both Ag(I) complex and silver nanoparticles have antimicrobial activities.

Keywords

Silver nanoparticles 2-Mecaptobenzothiazole Biological activities

Ahmed, A. J., & Ali Alsammarraie, A. M. (2018). Synthesis, Spectral, Structural and Antimicrobial Studies of Silver Nanoparticles and Ag(I) Complex of 2-Mercaptobenzothiazole. Asian Journal of Chemistry, 30(7), 1608–1612. https://doi.org/10.14233/ajchem.2018.21291

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A.A. Soayed, Inorg. Chim. Acta, 429, 257 (2015); https://doi.org/10.1016/j.ica.2015.02.012.

P. Jeevan, K. Ramya and A.E. Rena, Indian J. Biotechnol., 11, 72 (2012).

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H. Oka, T. Tomioka, K. Tomita, A. Nishino and S. Ueda, Met. Based Drugs, 1, 511 (1994); https://doi.org/10.1155/MBD.1994.511.

K. Nomiya, A. Yoshizawa, K. Tsukagoshi, N.C. Kasuga, S. Hirakawa and J. Watanabe, J. Inorg. Biochem., 98, 46 (2004); https://doi.org/10.1016/j.jinorgbio.2003.07.002.

M. Hanif, A. Saddiqa, S. Hasnain, S. Ahmad, G. Rabbani and A.A. Isab, J. Spectrosc., 22, 51 (2008); https://doi.org/10.1155/2008/170213.

Sh. Ranghar, P. Sirohi, P. Verma and V. Agarwal, Braz. Arch. Biol. Technol., 57, 209 (2013); https://doi.org/10.1590/S1516-89132013005000011.

J. Pulit, M. Banach, R. Szczyglowska and M. Bryk, Acta Biochim. Pol., 60, 795 (2013).

N. Beyth, Y. H.Haddad, A.Domb, W.Khanand and R. Hazan, Evid. Based Complem. Altern. Med., Article ID 246012 (2015); https://doi.org/10.1155/2015/246012.

P. Pandey and M. Dahiya, J. Crit. Rev., 3, 18 (2016).

M.G. Guzman, J. Dille and S. Godet, Int. J. Chem. Biomol. Eng., 2, 104 (2009).

P. Aslanidis, A.G. Hatzidimitriou, E.G. Andreadou, A.A. Pantazaki and N. Voulgarakis, Mater. Sci. Eng. C, 50, 187 (2015); https://doi.org/10.1016/j.msec.2015.02.014.

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Sh. Sujarania, T. Sironmani and A. Ramu, Dig. J. Nanomater. Biostruct., 7, 1843 (2012).

Issue

Vol. 30 No. 7 (2018): Vol 30 Issue 7

Synthesis, Spectral, Structural and Antimicrobial Studies of Silver Nanoparticles and Ag(I) Complex of 2-Mercaptobenzothiazole

Corresponding Author(s) : Alya’a Jabar Ahmed

Abstract

Keywords

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