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Vol. 30 No. 7 (2018): Vol 30 Issue 7

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A Green Method Synthesis and Antimicrobial Activity of 2-Amino-4H-Chromene Derivatives

https://doi.org/10.14233/ajchem.2018.21191
K. Kantharaju
Department of Chemistry, Peptide and Medicinal Chemistry Research Laboratory, Rani Channamma University, Vidyasangama, NH-4, Belagavi-591 156, India
Santosh Y. Khatavi
Department of Chemistry, Peptide and Medicinal Chemistry Research Laboratory, Rani Channamma University, Vidyasangama, NH-4, Belagavi-591 156, India

Corresponding Author(s) : K. Kantharaju

kk@rcub.ac.in

Asian Journal of Chemistry, Vol. 30 No. 7 (2018): Vol 30 Issue 7

Abstract

Agro-waste stuff ash extracted solution have been emerging in recent practicing green reaction catalysis in organic synthesis. The derived media have been demonstrated in reactions like Sonogashira, Dakin, Henry, Suzuki-Miyaura, amide bond formation. Traditionally, these reactions were performed in organic solvents and used expensive catalysts with elevated temperature. These catalytic media showed distinct properties during reaction course such as, in situ base, homogeneous catalysts and reducing agent. The present work reviewed green protocol synthesis of 2-amino-4H-chromene derivatives employing reaction of substituted benzaldehyde, malononitrile and α/β-naphthol or resorcinol; three component reaction catalyzed in the presence of water extract of banana peel ash (WEB) extraction under microwave and grindstone methods is described. The reaction found eco-friendly, simple reaction condition with easy separation of final product in pure form. The final product was characterized for its homogeneity using spectroscopic techniques. Some of the selected chromene derivatives (3b, 3d, 3g) prepared in this method is tested for its in vitro antimicrobial studies. The bioassay revealed that products 3b and 3d showed positive response and comparable antimicrobial activity with the reference compounds.

Keywords

Chromene Green method Water extract of banana peels Microwave irradiation Antimicrobial activity
Kantharaju, K., & Khatavi, S. Y. (2018). A Green Method Synthesis and Antimicrobial Activity of 2-Amino-4H-Chromene Derivatives. Asian Journal of Chemistry, 30(7), 1496–1502. https://doi.org/10.14233/ajchem.2018.21191
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